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Citation: SHI Wen-Bing. Chemiluminescence Analysis of Xanthinol Nicotinate in Reversed Micelle Media[J]. Chinese Journal of Applied Chemistry, ;2008, 25(9): 1116-1118. shu

Chemiluminescence Analysis of Xanthinol Nicotinate in Reversed Micelle Media

SHI Wen-Bing ^,

1.
Department of Chemisty, Changjiang Normal College, Fuling Chongqing 408003

Corresponding author: SHI Wen-Bing,
Received Date: 7 October 2007
Available Online: 4 April 2008
Fund Project: 重庆市教委资助项目(KJ061306) (KJ061306)

Under acidic condition,the nitrogen in xanthinol nicotinate was protonated followed by its reaction with Cl₄^- anion to form an ion-complex,which was carried into a reversed micelle of cetyltrimethyla-mmonium chlorine containing luminol by chloroform,and the dissociated Cl₄^- reacted with luminol to produce an analytical chemiluminescence signal.In a certain concetration range,the CL intensity was proportional to the concentration of xanthinol nicotinate.Under the optimum conditions,the linear range was 0.01 to 15×10^-6 g/mL,and the limit of detection was 0.4×10^-9 g/mL with a relative standard deviation(n=11) of ca.1.26% for xanthinol nicotinate of 1.0×10^-6 g/mL.The method is simple,sensitive and has been applied to determining the studied drug in injection successfully.
- reversed micelle,
- xanthinol nicotinate,
- chemiluminescence
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