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Citation: MU Chun-Ming, SHI Tie-Jun, SHI Xian-Lei. Synthesis of Triglycidyl Isocyanurate via Oxidation of Triallyl Isocyanurate with Hydrogen Peroxide[J]. Chinese Journal of Applied Chemistry, ;2008, 25(9): 1090-1094. shu

Synthesis of Triglycidyl Isocyanurate via Oxidation of Triallyl Isocyanurate with Hydrogen Peroxide

1.
School of Chemical Engineering, Hefei University of Technology, Hefei 230009

Corresponding author: SHI Tie-Jun,
Received Date: 23 October 2007
Available Online: 11 January 2008

TAIC was epoxidized by H₂O₂ to prepare TGIC in the presence of a manganese salt and as the catalyst the chemical structure of TGIC was characterized with FT-IR and ¹H NMR.The influences of the molar ratio of reactants,the amount of the catalyst,pH of the buffer solution and the reaction time on the yield were studied.When the molar ratio of TAIC to H₂O₂ was 1:15,the molar ratio of TAIC to manganese salt was 1:0.1,the buffer was NH₄HCO₃ solution in ethyl alcohol,the reaction time was 25 h and the reaction tem-perature was 25 ℃,the efficiency of H₂O₂ and the selectivity of TGIC were 15% and 69%,respectively.The reaction mechanism was also discussed in detail.Results show that the BAP systerm could provide reactive oxygen species to epoxidize carbon-carbon double bond,and the efficiency of H₂O₂ and selectivity of TGIC could be improved with the addition of Mn²⁺.
- trially isocyanurate(TAIC),
- triglycidyl isocyanurate(TGIC),
- ammonium bicarbonate(NH₄-HCO₃),
- hydrogen peroxide(H₂O₂),
- reaction mechanism
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