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Citation: MA Dong-Mei, PENG Ru-Fang, CAI Yan-Hua, ZHU Gen-Hua, WANG Jin-Gang, YU Hai-Jun, CHU Shi-Jin. Synthesis of N-Methyl-2-(3,4-dihydroxyphenyl)[60] Fullerene Pyrrolidine[J]. Chinese Journal of Applied Chemistry, ;2008, 25(10): 1142-1145. shu

Synthesis of N-Methyl-2-(3,4-dihydroxyphenyl)[60] Fullerene Pyrrolidine

1.
a College of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010;
2.
b China Academy of Engineering Physics, Mianyang

Corresponding author: PENG Ru-Fang,
Received Date: 3 September 2007
Available Online: 20 November 2007
Fund Project: 国家自然科学基金资助项目(10576026) (10576026)四川省科技厅重点项目(05GG009-018-04) (05GG009-018-04)

N-methyl-2-(3,4-dihydroxyphenyl)[60] fullerene pyrrolidine was synthesized by the 1,3-dipolar cycloaddition reaction of fullerene(C₆₀) and azomethine ylide(prepared from N-methylglycine and 3,4-dihydroxybenzaldehyde).The product was characterized by UV-Vis,FI-IR,¹H NMR and MS.The reaction conditions affecting the yield were investigated and the optimum reaction conditions which afforded 66%(based on consumed C₆₀) of the product were:molar ratio of C₆₀:N-methylglycine:3,4-dihydroxybenzaldehyde 1:2:5,reaction temperature 95℃,reaction time 28 h.
- C₆₀ derivatives,
- dihydroxybenzaldehyde,
- synthetic technology,
- characterization
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