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Citation: ZHAO Hui, LUO Xiao-Jun, LUO Yun-Jun. Carbon Nanotubes Grafted with Hyperbranched Poly(Amine-ester) and Dispersion Properties[J]. Chinese Journal of Applied Chemistry, ;2008, 25(11): 1361-1365. shu

Carbon Nanotubes Grafted with Hyperbranched Poly(Amine-ester) and Dispersion Properties

1.
a Research Center of Functional Materials, Kaifeng University, Kaifeng 475004;
2.
b School of Material Science and Engineering, Beijing Institute of Technology, Beijing

Corresponding author: ZHAO Hui,
Received Date: 6 October 2007
Available Online: 11 January 2008

CNTs were first oxidized in a mixture of c(K₂Cr₂O₇)=0.25 mol/L and an acid with c(H+)=1 mol/L to obtain CNTs with hydroxyl groups on their surfaces,then the oxidized CNTs were grafted with hyperbranched poly(amin-ester) through one-step polycondensation between A₂B monomer and active hydroxyl on CNTs surface in the presence of catalyst.The reaction conditions were studied and optimized with respect to the amount of HPAE coupled with CNTs.Under the conditions:n(CNTs-OH):n(A₂B monomer)=1:6,reaction time=10 h,reaction temperature 120℃,the amount of HPAE coupled with CNTs reached to 0.255.From the results of FTIR,XPS and TEM,it can be found that hyperbranched poly(amin-ester) is successfully grafted onto the surface of CNTs.The results indicate that CNTs grafted with hyperbranched poly(amin-ester) exhibit better dispersion in acetone,ethanol or water than unmodified CNTs.
- carbon nanotube,
- hyperbranched polymer,
- dispersion property
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