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Citation: CHEN Lin, HU Zhi-Yong, ZHU Hai-Lin, XUE Zhuan-Ru. Synthesis and Surface Activity of Cleavable Aryl Sulfonate Anionic Surfactants[J]. Chinese Journal of Applied Chemistry, ;2008, 25(11): 1345-1350. shu

Synthesis and Surface Activity of Cleavable Aryl Sulfonate Anionic Surfactants

1.
School of Chemical Engineering and Environment, North China University, Taiyuan 030051

Corresponding author: HU Zhi-Yong,
Received Date: 12 October 2007
Available Online: 16 January 2008

A series of cleavable aryl sulfonate anionic surfactants with different carbon chains were synthesized from cyanuric chloride,aliphatic amine,and H acid mono sodium salt.Their structures were identified by ¹H NMR,IR,and elemental analysis.Their critical micell concentrations(CMC) in aqueous solutions at 25℃ were determined by steady-state fluorescence probe method and surface-tension method,respectively.With increased length of the carbon chain,the values of their CMC and surface tensions under CMC(γ_CMC) first decreased and reached minima(1.5×10^-5 mol/L and 28.29 mN/m respectively) when the carbon number was 10.Then the CMC and γ_CMC increased when the carbon number was 12.Compared with sodium dodecyl benzene sulfonate(SDBS),such kinds of surfactants have much lower surface adsorption amounts and greater molecular areas on the aqueous surface.Stability test results demonstrate that these surfactants are cleavable.
- cyanuric chloride,
- cleavable surfactant,
- surface tension,
- steady-state fluorescence probe method
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