Citation:
TIAN Peng-Fei, LIU Wen-Xia. Effect of Sodium Citrate on Magnesium Aluminum Hydroxide Stabilized Emulsion[J]. Chinese Journal of Applied Chemistry,
;2008, 25(11): 1271-1276.
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To explore the role of aggregation of solid particles in stabilizing Pickering emulsions,the emulsi-fying effect of positively charged magnesium aluminum hydroxide(MAH) on paraffin/water system,the influence of sodium citrate on the aggregation of MAH as well as on the formation of MAH stabilized paraffin/water emulsion were investigated.The results show that MAH may stabilize paraffin-in-water emulsion when the initial oil-to-water volume ratio was less than 3:1.The stability of the paraffin-in-water emulsion was improved with increasing paraffin volume fraction,which was accompanied by the increase of emulsion viscosity and droplet size.At the level of less than 10%(w/w based on MAH),sodium citrate induced the aggregation of MAH particles forming open aggregates with high viscosity,which improved the stability of MAH stabilized paraffin/water emulsion.However,the viscosity of the paraffin-in-water emulsion was also increased.When denser MAH aggregates were formed by the charge neutralization of citrate,e.g.,the addition level of sodium citrate was larger than 10%,the stability of MAH stabilized paraffin-in-water emulsion was lowered and the emulsion droplet size rapidly increased.
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