Citation: YU Qi, SONG Hua, SONG Hua-lin, WANG Jian, JIANG Nan, LI Feng, CHEN Yan-guang. Effect of reduction temperature on the performance of Ni₂P/Ti-MCM-41 catalyst in hydrodesulfurization[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(08): 970-976. shu

Effect of reduction temperature on the performance of Ni₂P/Ti-MCM-41 catalyst in hydrodesulfurization

YU Qi ¹ ,
SONG Hua ^1,2,, ,
SONG Hua-lin ^3,, ,
WANG Jian ¹ ,
JIANG Nan ¹ ,
LI Feng ^1,2 ,
CHEN Yan-guang ^1,2

1.
1. College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China;
2.
2. Provincial Key Laboratory of Oil & Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China;
3.
3. Department of Image School, Mudanjiang Medical University, Mudanjiang 157011, China

Corresponding author: SONG Hua, SONG Hua-lin,
Received Date: 6 February 2016
Available Online: 30 April 2016
Fund Project:

The supported Ni₂P/Ti-MCM-41 catalyst is prepared by temperature-programmed reduction method with nickel chloride (NiCl₂·6H₂O) as the nickel precursor, ammonium hypophosphite (NH₄H₂PO₂) as the phosphorus precursor and Ti-MCM-41 as the support. The Ni₂P/Ti-MCM-41 catalyst was characterized by H₂-TPR, XRD, BET, XPS, and TEM; the effect of reduction temperature on its catalytic performance in hydrodesulfurization (HDS) was investigated by using dibenzothiophene (DBT) as a model compound. The results show that the precursors on the catalyst prepared in this way can be reduced at 318℃, which is at least 200℃ lower than that prepared by traditional methods. Pure Ni₂P phase can be obtained by reduction at 350-500℃; the low reduction temperature is in favor of forming small Ni₂ Pcrystallite size. The Ni₂P/Ti-MCM-41 catalyst obtained at a reduction temperature of 400℃ exhibits the highest surface area, the best dispersion of Ni₂P crystallite size, the lowest surface phosphorus content and the highest HDS activity; under 340℃, 3.0MPa, a H₂/oil ratio of 500 (volume ratio) and a weight hourly space velocity (WHSV) of 2.0h^-1, the conversion of DBT for HDS reaches 99.4%.
- hydrodesulfurization,
- nickel phosphide,
- reduction temperature,
- Ti-MCM-41,
- dibenzothiophene
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Effect of reduction temperature on the performance of Ni2P/Ti-MCM-41 catalyst in hydrodesulfurization

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Effect of reduction temperature on the performance of Ni₂P/Ti-MCM-41 catalyst in hydrodesulfurization