Citation: YU Xue, WANG Liang, FENG Li-juan, LI Chun-hu. Preparation of Au/BiOBr/Graphene composite and its photocatalytic performance in phenol degradation under visible light[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(08): 937-942. shu

Preparation of Au/BiOBr/Graphene composite and its photocatalytic performance in phenol degradation under visible light

  • Corresponding author: WANG Liang, 
  • Received Date: 12 April 2016
    Available Online: 22 June 2016

  • BiOBr, BiOBr/Graphene and Au/BiOBr/Graphene composites were prepared by hydrothermal synthesis and dopamine in-situ reduction method; their morphology, composition, phase structure and optical absorption properties were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), ultraviolet-visible diffuse reflection spectroscopy (DRS) and photoluminescence (PL) emission spectroscopy. The photocatalytic performance of Au/BiOBr/Graphene in phenol degradation under visible light was investigated. The results indicate that the Au/BiOBr/Graphene composite exhibits enhanced absorption in the visible light region as well as superior photocatalytic activity in the degradation of aqueous phenol, in comparison with BiOBr and BiOBr/Graphene, owing to the enhanced quantum efficiency, narrowed band gap (2.25eV) and surface plasmon resonance of Au nano particles. Over Au/BiOBr/Graphene composite, the degradation rate of phenol reaches 64% in 180min under visible light irradiation.
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    1. [1]

      [1] OREGAN B,GRATZAL M.A low-cost,high-efficiency solar-cell based on dye-sensitized colloidal TiO2 films[J].Nature,1991,353:737-740.

    2. [2]

      [2] CHEN X,CHEN L,CHEN Y W.Self-assembly of discotic liquid crystal decorated ZnO nanoparticles for efficient hybrid solar cells[J].Rsc Adv,2014,4(7):3627-3632.

    3. [3]

      [3] 桂明生,王鹏飞,袁东,杨易坤.Bi2WO6/g-C3N4复合型催化剂的制备及其可见光光催化性能[J].无机化学学报,2013,29(10):2057-2064.(GUI Ming-sheng,WANG Peng-fei,YUAN Dong,YANG Yi-kun.Synthesis and visible-light photocatalytic activity of Bi2WO6/g-C3N4 composite photocatalyst[J].Chin J Inorg Chem,2013,29(10):2057-2064.)

    4. [4]

      [4] 章剑,章燕,沈玉华,李村,谢安建,花状结构Bi2WO6多孔微球:组装及光催化性能[J].无机化学学报,2012,28(4):739-744.(ZHANG Jian,ZHANG Yan,SHEN Yu-hua,LI Cun,XIE An-dong.Flower-like Bi2WO6 porous microspheres:Assembly and photocatalytic perforrmance[J].Chin J Inorg Chem,2012,28(4):739-744.)

    5. [5]

      [5] ZHANG X M,CHANG X F,GONDAL M A,ZHANG B,LIU Y S,JI G B.Synthesis and photocatalytic activity of graphene/BiOBr composites under visible light[J].Appl Surf Sci,2012,258(20):7826-7832.

    6. [6]

      [6] CAO Q W,CUI X Z,YI F S,XU C.A novel CdWO4/BiOBr p-n heterojunction as visible light photocatalyst[J].J Alloys Compd,2016,670:12-17.

    7. [7]

      [7] HUANG Y C,FAN W J,LONG B,LI H B,ZHAO F Y,LIU Z L,TONG Y X,JI H B.Visible light Bi2S3/Bi2O3/Bi2O2CO3 photocatalyst for effective degradation of organic pollutions[J].Appl Catal B:Environ,2016,186:68-76.

    8. [8]

      [8] 姜凌霄,李可心,颜流水,戴玉华,黄智敏.Ag (Au)/石墨烯-TiO2复合光催化剂的制备及其模拟太阳光光催化性能[J].催化学报,2012,33(12):1974-1981.(JIANG Ling-xiao,LI Ke-xin,YAN Liu-shui,DAI Yu-hua,HUANG Zhi-min.Preparation of Ag (Au)/Graphene-TiO2 composite photocatalysts and their catalytic performance under simulated sunlight irradiation[J].Chin J Catal,2012,33(12):1974-1981.)

    9. [9]

      [9] 陈建炜,石建稳,王旭,崔浩杰,付明来.半导体/石墨烯复合光催化剂的制备及应用[J].催化学报,2013,34(4):621-624.(CHEN Jian-wei,SHI Jian-wen,WANG Xu,CUI Hao-jie,FU Ming-lai.Recent progress in the preparation and application of semiconductor/graphene composite photocatalysts[J].Chin J Catal,2013,34(4):621-640.)

    10. [10]

      [10] LIU W J,CAI J Y,LI Z H.Self-assembly of semiconductor nanoparticles/Reduced Graphene Oxide (RGO) composite aerogels for enhanced photocatalytic performance and facile recycling in aqueous photocatalysis[J].ACS Sustainable Chem Eng,2015,3(2):277-282.

    11. [11]

      [11] 韩丹,张爱文,高官俊,苏海全.负载型纳米Au催化剂光催化性能的研究进展[J].化工进展,2012,31(2):435-440.(HAN Dan,ZHANG Ai-wen,GAO Guan-jun,SU Hai-quan.Progress in the photocatalysis of supported-gold catalysts[J].Chem Ind Eng Prog,2012,31(2):435-440.)

    12. [12]

      [12] SUN L L,ZHAO D X,SONG Z M,SHAN C X,ZHANG Z Z,LI B H,SHEN D Z.Gold nanoparticles modified ZnO nanorods with improved photocatalytic activity[J].J Colloid Interface Sci,2011,363(1):175-181.

    13. [13]

      [13] BI J H,ZHOU Z Y,CHEN M Y,LIANG S J,HE Y H,ZHANG Z Z,WU L.Plasmonic Au/CdMoO4 photocatalyst:Influence of surface plasmon resonance for selective photocatalytic oxidation of benzylic alcohol[J].Appl Surf Sci,2015,349:292-298.

    14. [14]

      [14] LIU Y,YU H T,WANG H,CHEN S,QUAN X.Efficient H2 production over Au/graphene/TiO2 induced by surface plasmon resonance of Au and band-gap excitation of TiO2[J].Mater Res Bull,2014,59:111-116.

    15. [15]

      [15] YU C F,DONG S Y,ZHAO J,HAN X,WANG J Z,SUN J H.Preparation and characterization of sphere-shaped BiVO4/reduced graphene oxide photocatalyst for an augmented natural sunlight photocatalytic activity[J].J Alloys Compd,2016,677:219-227.

    16. [16]

      [16] DONG S,CUI Y,WANG Y,LI Y K,HU L M,SUN J Y,SUN J H.Designing three-dimensional acicular sheaf shaped BiVO4/reduced graphene oxide composites for efficient sunlight-driven photocatalytic degradation of dye wastewater[J].Chem Eng J,2014,249:102-110.

    17. [17]

      [17] WANG N,ZHOU Y,CHEN C,CHENG L Y,DING H M.Ag-C3N4 supported graphene oxide/Ag3PO4 composite with remarkably enhanced photocatalytic activity under visible light[J].Catal Commun,2016,73:74-79.

    18. [18]

      [18] HUO Y N,ZHANG J,MIAO M,JIN Y,Solvothermal synthesis of flower-like BiOBr microspheres with highly visible-light photocatalytic performances[J].Appl Catal B:Environ,2012,111(3):334-341.

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