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Citation: YAN Jing, YAO Zhao-Quan, WU Xiu-Mei, WANG Xiu-Guang, LIU Qing-Xiang. Two Zinc(Ⅱ) and Copper(Ⅱ) 1D Coordination Polymers Based on 1-Butylbenzimidazole and Terephthalate Mixed-ligands: Crystal Structures and Weak Interactions[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2674-2680. shu

Two Zinc(Ⅱ) and Copper(Ⅱ) 1D Coordination Polymers Based on 1-Butylbenzimidazole and Terephthalate Mixed-ligands: Crystal Structures and Weak Interactions

  • 1.

    Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry (Tianjin Normal University) Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China

  • Corresponding author: LIU Qing-Xiang, 
  • Received Date: 6 March 2012
    Available Online: 2 July 2012

    Fund Project: 国家自然科学基金(No.21172172) (No.21172172)天津市自然科学基金(No.11JCZDJC22000)资助项目. (No.11JCZDJC22000)

  • The two 1D coordination polymers [Zn(L)2(TP)]n (1) and [Cu(L)2(TP)]n (2) (L=1-butylbenzimidazole, TP=terephthalate ion) have been prepared via the reaction of 1-butylbenzimidazole, terephthalic acid and Zn(NO3)2·6H2O or Cu(NO3)2·3H2O, respectively. The structures of these complexes were characterized by X-ray diffraction analysis. In the crystal packings of coordination polymers 1 and 2, 2D supramolecular layers are formed through C-H…O or O-H…O hydrogen bonds, respectively. The fluorescence emission spectra of L, 1 and 2 are described. CCDC: 899947, 1; 899948, 2.
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