Citation: WANG Miao, SHEN Xin-Lin, TANG Yan-Feng, JIANG Guo-Qing, SHI Yu-Jun. Glycine-Assisted Hydrothermal Synthesis of CaF₂∶Ln³⁺(Ln=Eu, Tb) Microcrystals with Different Morphologies[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2660-2666. shu

Glycine-Assisted Hydrothermal Synthesis of CaF₂∶Ln³⁺(Ln=Eu, Tb) Microcrystals with Different Morphologies

1.
School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, China

Corresponding author: SHI Yu-Jun,
Received Date: 27 March 2012
Available Online: 25 June 2012
Fund Project: 国家自然科学基金(No.21173122,20906052) (No.21173122,20906052)江苏省自然科学基金(No.BK2010281) (No.BK2010281)南通市应用研究计划项目(BK2011035) (BK2011035)

By employing KBF₄ or K₂SiF₆ as fluoride source, a facile glycine-assisted hydrothermal route has been developed to synthesize a series of well-dispersed CaF₂∶Ln³⁺(Ln=Eu, Tb) microcrystals with a variety of morphologies, such as cubes, hollow polyhedra and hollow spheres. X-ray diffraction (XRD), Fourier transform IR (FTIR), scanning electron microscopy (SEM) and photoluminescence (PL) were used to characterize the purity, crystalline phase, morphologies and the photoluminescence properties of the samples. The XRD results show that all the as-prepared CaF₂ have cubic structure and high crystallinity. The SEM results indicate that, in the presence of glycine, the as-prepared CaF₂ microcrystals present morphologies of highly dispersed hollow polyhedra and hollow spheres obtained from KBF₄ and K₂SiF₆, respectively. Meanwhile, the CaF₂ hollow spheres were assembled from numerous nanocubes. In the synthetic process, glycine, fluoride source and reaction time play crucial role in confining the growth of the different morphological CaF₂ microcrystals. The growth mechanism for products with diverse microstructures have been proposed based on the experimental results.
- CaF₂;nanomaterials;hydrothermal route;glycine;photoluminescence
1. [1]
  [1] Nakajima T, Zemva B, Tressaud A. Advanced Inorganic Fluorides. Amsterdam: Elsevier, 2000.
2. [2]
  [2] Kinsman B E, Hanney R. Adv. Mater. Opt. Electron., 1995,5:109-115
3. [3]
  [3] Moon H J, Kim K N, Kim K M, et al. J. Biomed. Mater. Res. Part A, 2005,74A:497-502
4. [4]
  [4] Feldmann C, Roming M, Trampert K. Small, 2006,2:1248-1250
5. [5]
  [5] Sun X M, Li Y D. Chem. Commun., 2003:1768-1769
6. [6]
  [6] Zhang C M, Li C X, Peng C, et al. Chem. Eur. J., 2010,16: 5672-5680
7. [7]
  [7] Zhang X M, Quan Z W, Yang J, et al. Nanotechnology, 2008,19:075603(8pp)
8. [8]
  [8] Hou S Y, Zou Y C, Liu X C, et al. CrystEngComm, 2011,13:835-840
9. [9]
  [9] Quan Z W, Yang D M, Yang P P, et al. Inorg. Chem., 2008,47:9509-9517
10. [10]
  [10] Du Y P, Sun X, Zhang Y W, et al. Cryst. Growth Des., 2009,9:2013-2019
11. [11]
  [11] Mao Y B, Zhang F, Wong S S. Adv. Mater., 2006,18:1895-1899
12. [12]
  [12] Wang W S, Zhen L, Xu C Y, et al. ACS Appl. Mater. Interfaces, 2009,1:780-788
13. [13]
  [13] Guo F Q, Zhang Z F, Li H F, et al. Chem. Commun., 2010, 46:8237-8239
14. [14]
  [14] WANG Miao(王淼), CHEN Ting-Ting(陈婷婷), TANG Yan-Feng(汤艳峰), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28:185-190
15. [15]
  [15] Yang X F, Dong X T, Wang J X, et al. J. Alloy Compd., 2009,487:298-303
16. [16]
  [16] Yang X F, Dong X T, Wang J X, et al. Mater. Lett., 2009, 63:629-631
17. [17]
  [17] Chen H M, Zhao Y Q, He J H, et al. Analytica Chimica Acta, 2010,659:266-273
18. [18]
  [18] Wang M, Shi Y J, Jiang G Q. Mater. Res. Bull., 2012,47: 18-23
19. [19]
  [19] CHEN Guang-De(陈广德), XU Zhen-Mei(徐贞梅). Fine Chem.(Jingxi Huagong), 2002,19:701-702,726
20. [20]
  [20] ZHANG Da-Fei(张大飞), ZHAO Ri-Getu(照日格图), LIU Jian-Hua(刘建华), et al. Chinese J. Spect. Lab.(Guangpu Shiyanshi), 2006,23:91-95
21. [21]
  [21] CAO Xiao-Feng(曹霄峰), ZHANG Lei(张雷), MA Ying-Li (马英丽),et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26:787-792
22. [22]
  [22] Qian H S, Yu S H, Gong J Y, et al. Cryst. Growth Des. 2005,5:935-939
23. [23]
  [23] WANG Miao(王淼), SHI Yu-Jun(石玉军), JIANG Guo-Qing (江国庆). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25:1785-1790
24. [24]
  [24] Wei Z G, Sun L D, Jiang X C, et al. Chem. Mater., 2003,15: 3011-3017
25. [25]
  [25] Jiang X C, Sun L D, Yan C H. J. Phys. Chem. B, 2004,108: 3387-3390
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沈阳化工大学材料科学与工程学院沈阳 110142

Glycine-Assisted Hydrothermal Synthesis of CaF2∶Ln3+(Ln=Eu, Tb) Microcrystals with Different Morphologies

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通讯作者: 陈斌, bchen63@163.com

Glycine-Assisted Hydrothermal Synthesis of CaF₂∶Ln³⁺(Ln=Eu, Tb) Microcrystals with Different Morphologies