Citation: CHEN Hui-Fen, WANG Shuai-Hua, XU Zhong-Ning, WANG Guan-E, WANG Ming-Sheng, GUO Guo-Cong. Syntheses and Crystal Structures of Two Europium(Ⅲ) and Terbium(Ⅲ) Complexes with 6,7-Dicyanodipyridoquinoxaline[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2558-2564. shu

Syntheses and Crystal Structures of Two Europium(Ⅲ) and Terbium(Ⅲ) Complexes with 6,7-Dicyanodipyridoquinoxaline

1.
1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;

Corresponding author: WANG Ming-Sheng,
Received Date: 24 December 2011
Available Online: 8 August 2012
Fund Project: 国家自然科学基金(No.90922013,21101152,90922035) (No.90922013,21101152,90922035)福建省杰出青年基金(No.2011J06006)资助项目. (No.2011J06006)

Two lanthanide^Ⅲ metal-organic complexes, [Eu(DICNQ)₂(NO₃)₃]·(CH₃CN)₂ (1) and [Tb(DICNQ)(NO₃)₃]₂ (2), were prepared from Eu(NO₃)₃·6H₂O and Tb(NO₃)₃·6H₂O with 6,7-dicyanodipyridoquinoxaline (DICNQ) by solvothermal reactions, respectively, and characterized by single-crystal X-ray diffraction analyses. Compound 1 crystallizes in the monoclinic noncentrosymmetric space group Cc, with a=1.157 7(6) nm, b=3.193 4(2) nm, c=1.106 6(6) nm, β=97.633(2)°, V=4.055(4) nm³, Z=4, M_r=984.63, D_c=1.613 g·cm^-3, μ=1.623 mm^-1, F(000)=1 952, S=1.035 and T=293(2) K. The final R=0.033 5 and wR=0.078 1 for 6 467 observed reflections with I>2σ(I). Compound 2 crystallizes in the triclinic centrosymmetric space group P1, with a=0.871 1(3) nm, b=0.890 8(3) nm, c=1.544 9(5) nm, α=80.852(9)°, β=84.217(9)°, γ=65.475(7)°, V=1.076 0(6) nm³, Z=1, M_r=1 254.44, D_c=1.936 g·cm^-3, μ=3.356 mm^-1, F(000)=604, S=1.026 and T=293(2) K. The final R=0.036 8 and wR=0.095 6 for 3 697 observed reflections with I>2σ(I). Compound 1 is built upon isolated neutral molecules, which are connected by C-H…O hydrogen-bonding interactions, while compound 2 forms a packing structure by π…π stacking interactions as well as intermolcular C-H…N and intramolecular C-H…O hydrogen-bonding interactions. CCDC: 857317, 1; 857318, 2.
- crystal structure;hydrogen-bonding interactions;metal-organic complexes;π…π stacking interactions
1. [1]
  [1] An J, Geib S J, Rosi N L. J. Am. Chem. Soc., 2010,132:38-39
2. [2]
  [2] Chen B, Xiang S C, Qian G. Acc. Chem. Res., 2010,43:1115 -1124
3. [3]
  [3] Jiang H L, Xu Q. Chem. Commun., 2011,47:3351-3370
4. [4]
  [4] Hollingsworth M D. Science, 2002,295:2410-2413
5. [5]
  [5] Lozan V, Loose C, Kortus J, et al. Coord. Chem. Rev., 2009, 253:2244-2260
6. [6]
  [6] Lozan V, Loose C, Kortus J, et al. Coord. Chem. Rev., 2009, 253:2244-2260
7. [7]
  [7] Holliday B J, Mirkin C A. Angew. Chem. Int. Ed., 2001,40: 2022-2043
8. [8]
  [8] Weng Z, Liu D, Chen Z, et al. Cryst. Growth Des., 2009,9: 4163-4170
9. [9]
  [9] Mahmoudi G, Morsali A. CrystEngComm, 2009,11:50-51
10. [10]
  [10] Tephenson M D, Hardie M J. Cryst. Growth Des., 2006,6: 423-432
11. [11]
  [11] Chen H F, Li Y, Wang M S, et al. Chinese J. Struct. Chem. (Jiegou Huaxue), 2008,11:1398-1403
12. [12]
  [12] Delahaye S, Loosli C, Liu S X, et al. Adv. Funct. Mater., 2006,16:286-295
13. [13]
  [13] Chen H F, Jiang X M, Wang M S, et al. Chinese J. Struct. Chem.(Jiegou Huaxue), 2011,30:324-329
14. [14]
  [14] Xu Z D, Liu H, Wang M, et al. J. Chinese Pharm. Sci. (Zhongguo Yaoxue), 2002,11:125-131
15. [15]
  [15] Xu Z D, Liu H, Wang M, et al. J. Inorg. Biochem., 2002, 92:149-155
16. [16]
  [16] Liu H, Du M, Ge X J, et al. Acta Crystallogr. Sect. E, 2001, 57:m100-m102
17. [17]
  [17] Si Z, Li J, Li B, et al. J. Phys. Chem. C, 2008,112:3920-3925
18. [18]
  [18] Kozlov L, Goldberg I. Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 2008,64:m123-m126
19. [19]
  [19] Chen H F, Guo G C, Wang M S, et al. Dalton Trans., 2009, 46:10166-10168
20. [20]
  [20] Rigaku. Crystal Clear Version 1.3.5, Rigaku Corporation, Japan, 2002.
21. [21]
  [21] Siemens. SHELXTL^TM Version 5 Reference Manual, Siemens Energy & Automation Inc., Madison, Wisconsin, USA, 1994.
22. [22]
  [22] Cotton S A, Franckevicius V, Mahon M F, et al. Polyhedron, 2006,25:1057-1068
23. [23]
  [23] Fukuda Y, Nakao A, Hayashi K. J. Chem. Soc., Dalton Trans., 2002:527-533
24. [24]
  [24] Yang L W, Liu S, Rettig S J, et al. Inorg. Chem., 1995,34: 4921-4925
1. [1]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
2. [2]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
5. [5]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
6. [6]
  Huiying Xu , Minghui Liang , Zhi Zhou , Hui Gao , Wei Yi . Application of Quantum Chemistry Computation and Visual Analysis in Teaching of Weak Interactions. University Chemistry, 2025, 40(3): 199-205. doi: 10.12461/PKU.DXHX202407011
7. [7]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
8. [8]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
9. [9]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
10. [10]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
11. [11]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
12. [12]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
13. [13]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
14. [14]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
15. [15]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
16. [16]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
17. [17]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
18. [18]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
19. [19]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
20. [20]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(218)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142