Citation: CAO Cheng, WEI Tai-Bao, ZHANG Qin-Sheng, LU Yan-Yun, ZHANG You-Ming. Synthesis and Crystal Structures of a 1D Cu Coordination Polymer Based on Tetrakis[3-(carboxyphenyl)oxamethyl]methane Acid[J]. Chinese Journal of Inorganic Chemistry, ;2012, 28(12): 2530-2534. shu

Synthesis and Crystal Structures of a 1D Cu Coordination Polymer Based on Tetrakis[3-(carboxyphenyl)oxamethyl]methane Acid

1.
1. Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Northwest Normal University, Lanzhou 730070, China;

Corresponding author: ZHANG You-Ming,
Received Date: 16 February 2012
Available Online: 13 July 2012
Fund Project: 国家自然科学基金(No.21064006) (No.21064006) 甘肃省自然科学基金(No.1010RJZA018)资助项目. (No.1010RJZA018)

A semi-rigid tetrahedral linker tetrakis[3-(carboxyphenyl)oxamethyl]methane acid (H₄L) and its coordination polymer [Cu(H₂L)(Py)₂]_n (Py=pyridyne) were synthesized and characterized by elemental analyses, IR spectroscopy, etc. The single crystal structure show the title complex crystallizes in the monoclinic system with space group C2/c, a=1.943 0(7) nm, b=0.926 4(3) nm, c=2.784 9(9) nm, β=96.763(3)°, V=4.978(3) nm³, Z=4, F(000)=1 724. In the complex each Cu(Ⅱ) atoms is coordinated with two pyridyne and two oxygen atom from two arms of H₂L^2-, and displays a one-dimensional line topology with the other two arms free. Platon calculation show that the guest accessible volume (1.397 nm³ per unit cell) comprises 28.1% of the unit cell volume. The thermal analysis shows the title compound is trable up to 236.9 ℃. CCDC: 817405.
- tetrakis[3-(carboxyphenyl)oxamethyl]methane acid;coordination polymer;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142