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Citation: YANG Li-xia, LIU Dan, LIU Dao-sheng, SUN Cheng-zhi, SEO Hwi-min, GUI Jian-zhou, PARK Yong-ki. TiO2 modified magnesium-based adsorbents for intermediate-temperature CO2 capture[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(12): 1498-1503. shu

TiO2 modified magnesium-based adsorbents for intermediate-temperature CO2 capture

  • 1.

    1. Division of Chemistry, Chemical Engineering and Environment, Liaoning Shihua University, Fushun 113001, China;;

  • Corresponding author: LIU Dan,  GUI Jian-zhou,  PARK Yong-ki, 
  • Received Date: 18 June 2015
    Available Online: 28 October 2015

    Fund Project: 国家自然科学基金(21576211) (21576211)新世纪优秀人才支持计划(NCET-11-1011) (NCET-11-1011)天津市应用基础与前沿技术研究计划(13JCYBJC41600) (13JCYBJC41600)韩国教育科技部(KCCS2020Project)资助项目 (KCCS2020Project)

  • A series of TiO2-modified magnesium-based sorbents, for thermo-swing absorption process in intermediate-temperature working range (250~500℃), were prepared by precipitation, and characterized by XRD, SEM and N2 absorption etc. The sorbents were evaluated by dynamic absorption-desorption cyclic tests. With the increase of TiO2 amount, the crystallinity of the sample decreased, and the BET surface area also decreased due to the formation of MgTiO3.When the TiO2 content was 2%, uniform particle size (nanostructured spheres with 4.0~5.0μm in diameter) was obtained. The absorption capacity was stabilized from the second cycle of the absorption-desorption cyclic test, and the capacity could reach 6.64% after 50 cycles, suggesting good stability of the sorbent. This should be attributed to the formation of MgTiO3, which provided a rigid framework for the sample and improved the dispersion of active species.
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