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Citation: YANG Li-xia, LIU Dan, LIU Dao-sheng, SUN Cheng-zhi, SEO Hwi-min, GUI Jian-zhou, PARK Yong-ki. TiO2 modified magnesium-based adsorbents for intermediate-temperature CO2 capture[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(12): 1498-1503. shu

TiO2 modified magnesium-based adsorbents for intermediate-temperature CO2 capture

  • 1.

    1. Division of Chemistry, Chemical Engineering and Environment, Liaoning Shihua University, Fushun 113001, China;;

  • Corresponding author: LIU Dan,  GUI Jian-zhou,  PARK Yong-ki, 
  • Received Date: 18 June 2015
    Available Online: 28 October 2015

    Fund Project: 国家自然科学基金(21576211) (21576211)新世纪优秀人才支持计划(NCET-11-1011) (NCET-11-1011)天津市应用基础与前沿技术研究计划(13JCYBJC41600) (13JCYBJC41600)韩国教育科技部(KCCS2020Project)资助项目 (KCCS2020Project)

  • A series of TiO2-modified magnesium-based sorbents, for thermo-swing absorption process in intermediate-temperature working range (250~500℃), were prepared by precipitation, and characterized by XRD, SEM and N2 absorption etc. The sorbents were evaluated by dynamic absorption-desorption cyclic tests. With the increase of TiO2 amount, the crystallinity of the sample decreased, and the BET surface area also decreased due to the formation of MgTiO3.When the TiO2 content was 2%, uniform particle size (nanostructured spheres with 4.0~5.0μm in diameter) was obtained. The absorption capacity was stabilized from the second cycle of the absorption-desorption cyclic test, and the capacity could reach 6.64% after 50 cycles, suggesting good stability of the sorbent. This should be attributed to the formation of MgTiO3, which provided a rigid framework for the sample and improved the dispersion of active species.
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    1. [1]

      [1] RAUPACH M R, MARLAND G, CIAIS P, LE Q C, CANADELL J G, KLEPPER G, FIELD C B. Global and regional drivers of accelerating CO2 emissions[J]. Proc Natl Acad Sci USA, 2007, 104(24):10288-10293.

    2. [2]

      [2] STEWART C, HESSAMI M. A study of methods of carbon dioxide capture and sequestration-the sustainability of a bioreactor approach[J]. Energy Convers Manage, 2005, 46(3):403-420.

    3. [3]

      [3] WANG Q, LUO J, ZHONG Z, BORGNA A. CO2 capture by solid adsorbents and their applications:Current status and new trends[J]. Energy Environ Sci, 2010, 4(1):42-55.

    4. [4]

      [4] ROCHELLE G T. Amine scrubbing for CO2 capture[J]. Science, 2009, 325(5948):1652-1654.

    5. [5]

      [5] LEE S Y, PARK S J. A review on solid adsorbents for carbon dioxide capture[J]. J Ind Eng Chem, 2015, 23:1-11.

    6. [6]

      [6] LIU L, SANDERS E S, KULKARNI S S, HASSE D J, KOROS W J. Sub-ambient temperature flue gas carbon dioxide capture via Matrimids hollow fiber membranes[J]. J Membr Sci, 2014, 465:49-55.

    7. [7]

      [7] VOICE A K, ROCHELLE G T. Inhibitors of monoethanolamine oxidation in CO2 capture processes[J]. Ind Eng Chem Res, 2014, 53(42):16222-16228.

    8. [8]

      [8] GAZZZNI M, TURI D M, GHONIEM A F, ENNIO M, GIAMPAOLO M. Techno-economic assessment of two novel feeding systems for a dry-feed gasifier in an IGCC plant with Pd-membranes for CO2 capture[J]. Int J Greenhouse Gas Control, 2014, 25:62-78.

    9. [9]

      [9] ANANTHARAMAN R, BERSTAD D, ROUSSANALY S. Techno-economic performance of a hybrid membrane-liquefaction process for post-combustion CO2 capture[J]. Energy Procedia, 2014, 61:1244-1247.

    10. [10]

      [10] ZHAO C, CHEN X, ZHAO C, WU Y, DONG W. K2CO3/Al2O3 for capturing CO2 in flue gas from power plants. part 3:CO2 capture behaviors of K2CO3/Al2O3 in a bubbling fluidized-bed reactor[J]. Energy Fuels, 2012, 26(5):3062-3068.

    11. [11]

      [11] ZHAO C, CHEN X, ZHAO C. Carbonation behavior and the reaction kinetic of a new dry potassium-based sorbent for CO2 capture[J]. Ind Eng Chem Res, 2012, 51(44):14361-14366.

    12. [12]

      [12] TOMKUTE V, SOLHEIM A, OLSEN E. CO2 capture by CaO in molten CaF2-CaCl2:Optimization of the process and cyclability of CO2 capture[J]. Energy Fuels, 2014, 28(8):5345-5353.

    13. [13]

      [13] DUTCHER B, FAN M H, RUSSELL A G. Amine-based CO2 capture technology development from the beginning of 2013-A review[J]. ACS Appl Mater Interfaces, 2015, 7(4):2137-2148.

    14. [14]

      [14] DONG W, CHEN X, YU F, WU Y. Na2CO3/MgO/Al2O3 solid sorbents for low-temperature CO2 capture[J]. Energy Fuels, 2015, 29(2):968-973.

    15. [15]

      [15] LI L, WEN X, FU X, WANG F, ZHAO N, XIAO F, WEI W, SUN Y. MgO/Al2O3 sorbent for CO2 capture[J]. Energy Fuels, 2010, 24(10):5773-5780.

    16. [16]

      [16] LI L, ZHANG B, WANG F, ZHAO N, XIAO F, WEI W, SUN Y. Study of the novel KMgAl sorbents for CO2 capture[J]. Energy Fuels, 2013, 27(9):5388-5396.

    17. [17]

      [17] LEE S C, CHAE H J, LEE S J, CHOI B Y, YI C K, LEE J B, RYU C K, KIM J C. Development of regenerable MgO-based sorbent promoted with K2CO3 for CO2 capture at low temperatures[J]. Environ Sci Technol, 2008, 42(8):2736-2741.

    18. [18]

      [18] FISHER J C, SIRIWARDANE R V. Mg(OH)2 for CO2 Capture from high-pressure, moderate-temperature gas streams[J]. Energy Fuels, 2014, 28(9):5936-5941.

    19. [19]

      [19] 左臣盛,周思宇,孙成志,王兴之,刘道胜,徐煇旼,朴容起,桂建舟,刘丹.变温镁基CO2吸附剂的制备及应用(一)Na/Mg摩尔比[J].燃料化学学报, 2014, 42(7):884-889. (ZUO Chen-sheng, ZHOU Si-yu, SUN Cheng-zhi, WANG Xing-zhi, LIU Dao-sheng, SEO Hwi-min, PARK Yong-Ki, GUI Jian-zhou, LIU Dan. Preparation and application of magnesium-based CO2 sorbent for temperature swing absorption(I)Na/Mg mole ratio[J]. J Fuel Chem Technol, 2014, 42(7):884-889.)

    20. [20]

      [20] PABST A. The crystallography and structure of eitelite, Na2Mg(CO3)2[J]. Am Mineral, 1973, 58:211-217.

    21. [21]

      [21] LEE S C, KWON Y M, PARK Y H, LEE W S, PARK J J, RYU C K, YI C K, KIM J C. Structure effects of potassium-based TiO2 sorbents on the CO2 capture capacity[J]. Top Catal, 2010, 53(7):641-647.

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