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Citation: KONG Tong-tong, WANG Xia, GUO Qing-jie. Preparation and CO2 adsorption performance of a novel hierarchical micro/mesoporous solid amine sorbent[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(12): 1489-1497. shu

Preparation and CO2 adsorption performance of a novel hierarchical micro/mesoporous solid amine sorbent

  • 1.

    Key Laboratory of Clean Chemical Processing of Shandong Province, Qingdao University of Science & Technology, Qingdao 266042, China

  • Corresponding author: GUO Qing-jie, 
  • Received Date: 7 July 2015
    Available Online: 15 September 2015

    Fund Project: 国家自然科学基金(21276129) (21276129)青岛市应用基础研究计划项目(14-2-4-5-jch)资助 (14-2-4-5-jch)

  • The mixed supports were obtained at different weight ratios of HZSM-5 to MCM-41 by physical mixing processes. Tetraethylenepentamine (TEPA) modified mixed supports sorbents were prepared by the impregnation method. The sorbents were characterized by nitrogen adsorption/desorption, Fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA) techniques. The effects of mixing ratios of HZSM-5 to MCM-41, TEPA loadings, adsorption temperatures, influent velocities, and CO2 partial pressures on CO2 adsorption capacity were investigated in a fixed bed reactor. It showed that the maximum CO2 adsorption capacity was 3.57 mmol/g of HZSM-5/MCM-41-30%TEPA at the adsorption temperature of 55℃ and influent velocity of 30 mL/min. After ten-cycles, the CO2 adsorption capacity decreased by 8.1%. CO2 adsorption was determined by a two-stage process, a fast breakthrough adsorption and a gradual approaching equilibrium stage. Moreover, the breakthrough adsorption capacity accounted for approximately 80% of the equilibrium adsorption capacity. The Avrami model could fit well with the experimental data of HZSM-5/MCM-41-30%TEPA. It illustrated that the adsorption mechanism was dominated by both chemical and physical adsorption.
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