Advanced Search

Citation: KONG Tong-tong, WANG Xia, GUO Qing-jie. Preparation and CO2 adsorption performance of a novel hierarchical micro/mesoporous solid amine sorbent[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(12): 1489-1497. shu

Preparation and CO2 adsorption performance of a novel hierarchical micro/mesoporous solid amine sorbent

  • 1.

    Key Laboratory of Clean Chemical Processing of Shandong Province, Qingdao University of Science & Technology, Qingdao 266042, China

  • Corresponding author: GUO Qing-jie, 
  • Received Date: 7 July 2015
    Available Online: 15 September 2015

    Fund Project: 国家自然科学基金(21276129) (21276129)青岛市应用基础研究计划项目(14-2-4-5-jch)资助 (14-2-4-5-jch)

  • The mixed supports were obtained at different weight ratios of HZSM-5 to MCM-41 by physical mixing processes. Tetraethylenepentamine (TEPA) modified mixed supports sorbents were prepared by the impregnation method. The sorbents were characterized by nitrogen adsorption/desorption, Fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA) techniques. The effects of mixing ratios of HZSM-5 to MCM-41, TEPA loadings, adsorption temperatures, influent velocities, and CO2 partial pressures on CO2 adsorption capacity were investigated in a fixed bed reactor. It showed that the maximum CO2 adsorption capacity was 3.57 mmol/g of HZSM-5/MCM-41-30%TEPA at the adsorption temperature of 55℃ and influent velocity of 30 mL/min. After ten-cycles, the CO2 adsorption capacity decreased by 8.1%. CO2 adsorption was determined by a two-stage process, a fast breakthrough adsorption and a gradual approaching equilibrium stage. Moreover, the breakthrough adsorption capacity accounted for approximately 80% of the equilibrium adsorption capacity. The Avrami model could fit well with the experimental data of HZSM-5/MCM-41-30%TEPA. It illustrated that the adsorption mechanism was dominated by both chemical and physical adsorption.
  • 加载中
    1. [1]

      [1] ARENILLAS A, SMITH K M, DRAGE T C, SNAPE C E. CO2 capture using some fly ash-derived carbon materials[J]. Fuel, 2005, 84(17):2204-2210.

    2. [2]

      [2] WANG X, GUO Q J, ZHAO J, CHEN L L. Mixed amine-modified MCM-41 sorbents for CO2 capture[J]. Int J Greenhouse Gas Control, 2015, 37:90-98.

    3. [3]

      [3] SAMANTA A, BANDYOPADHYAY S S. Absorption of carbon dioxide into aqueous solutions of piperazine activated 2-amino-2-methyl-propanol[J]. Chem Eng Sci, 2009, 64(6):1185-1194.

    4. [4]

      [4] YAN X L, ZHANG L, ZHANG Y, QIAO K, YAN Z F, KOMARNENI S. Amine-modified mesocellular silica foams for CO2 capture[J]. Chem Eng J, 2011, 168(2):918-924.

    5. [5]

      [5] YANG S T, KIM J Y, KIM J, AHN W S. CO2 capture over amine-functionalized MCM-22, MCM-36 and ITQ-2[J]. Fuel, 2012, 97:435-442.

    6. [6]

      [6] WANG X, GUO Q J, KONG T T. Tetraethylenepentamine-modified MCM-41/silica gel with hierarchical mesoporous structure for CO2 capture[J]. Chem Eng J, 2015, 273:472-480.

    7. [7]

      [7] KHATRI R A, CHUANG S C, SONG Y. Thermal and chemical stability of regenerable solid amine sorbent for CO2 capture[J]. Energy Fuels, 2006, 20(4):1514-1520.

    8. [8]

      [8] 刘之琳,腾阳,张锴,曹晏,潘伟平.不同有机胺修饰MCM-41的CO2吸附性能和热稳定性[J].燃料化学学报, 2013, 41(4):469-476. (LIU Zhi-lin, TENG Yang, ZHANG Kai, CAO Yan, PAN Wei-ping. CO2 adsorption properties and thermal stability of different amine-impregnated MCM-41 materials[J]. J Fuel Chem Technol, 2013, 41(4):469-476.)

    9. [9]

      [9] LIU Y M, SHI J J, CHEN J, YE Q, PAN H, SHAO Z H, SHI Y. Dynamic performance of CO2 adsorption with tetraethylenepentamine-loaded KIT-6[J]. Microporous Mesoporous Mater, 2010, 134(1/3):16-21.

    10. [10]

      [10] ZHU T, YANG S, CHOI D K, ROW H K. Adsorption of carbon dioxide using polyethyleneimine modified silica gel[J]. Chem Eng J, 2010, 27(6):1910-1915.

    11. [11]

      [11] SARMAH M, BARUAH B P, KHARE P. A comparison between CO2 capturing capacities of fly ash based composites of MEA/DMA and DEA/DMA[J]. Fuel Process Technol, 2013, 106:490-497.

    12. [12]

      [12] KAMARUDIN K S N, ALIAS N. Adsorption performance of MCM-41 impregnated with amine for CO2 removal[J]. Fuel Process Technol, 2013, 106:332-337.

    13. [13]

      [13] 李勇,李磊,闻霞,王峰,赵宁,肖福魁,魏伟,孙予罕.二次嫁接法制备氨基修饰的硅基二氧化碳吸附剂[J].燃料化学学报, 2013, 41(9):1122-1128. (LI Yong, LI Lei, WEN Xia, WANG Feng, ZHAO Ning, XIAO Fu-kui, WEI Wei, SUN Yu-han. Synthesis of amine modified silica for the capture of carbon dioxide by a twice grafting method[J]. J Fuel Chem Technol, 2013, 41(9):1122-1128.)

    14. [14]

      [14] KISHOR R, GHOSHAL A K. APTES grafted ordered mesoporous silica KIT-6 for CO2 adsorption[J]. Chem Eng J, 2015, 262:882-890.

    15. [15]

      [15] CHATTI R, BANSIWAL A K, THOTE J A, KUMAR V, JADHAV P, LOKHANDE S K, BINIWALE R B, LABHSETWAR N K, RAYALU S S. Amine loaded zeolites for carbon dioxide capture:Amine loading and adsorption studies[J]. Microporous Mesoporous Mater, 2009, 121(1/3):84-89.

    16. [16]

      [16] JING Y, WEI L, WANG Y D, YU Y X. Molecular simulation of MCM-41:Structural properties and adsorption of CO2, N2 and flue gas[J]. Chem Eng J, 2013, 220:264-275.

    17. [17]

      [17] 马燕辉,赵会玲,唐圣杰,胡军,刘洪来.微孔/介孔复合分子筛的合成及其对CO2的吸附性能[J].物理化学学报, 2011, 27(3):689-696. (MA Yan-hui, ZHAO Hui-ling, TANG Sheng-jie, HU Jun, LIU Hong-lai. Synthesis of micro/mesoporous composites and their application as CO2 adsorbents[J]. Acta Phys Chim Sin, 2011, 27(3):689-696.)

    18. [18]

      [18] 周建海,赵会玲,胡军,刘洪来,胡英.氨基修饰微孔/介孔复合材料AM-5A-MCM-41对CO2吸附分离的分子模拟[J].化工学报, 2014, 65(5):1680-1687. (ZHOU Jian-hai, ZHAO Hui-ling, HU Jun, LIU Hong-lai, HU Ying. Molecular simulation of CO2 adsorption on amine modified micro/mesoporous composite of AM-5A-MCM-41[J]. J Chem Ind Eng, 2014, 65(5):1680-1687.)

    19. [19]

      [19] WANG W, YANG X, FANG Y, DING J. Preparation and performance of form-stable polyethylene glycol/silicon dioxide composites as solid-liquid phase change materials[J]. Appl Energy, 2009, 86(2):170-174.

    20. [20]

      [20] WANG J T, CHEN H C, ZHOU H H, LIU X J, QIAO W M, LONG D H, LING L C. Carbon capture using polyethylemine-loaded mesoporous carbon[J]. J Environ Sci, 2013, 25(1):124-132.

    21. [21]

      [21] WANG X, CHEN L L, GUO Q J. Development of hybrid amine-functionalized MCM-41 sorbents for CO2 capture[J]. Chem Eng J, 2015, 260:573-581.

    22. [22]

      [22] 谢菲,王艳莉,詹亮,葛明,梁晓怿,乔文明,凌立成.沥青基球形活性炭对CO2的吸脱附行为研究[J].无机材料学报, 2011, 26(2):149-154. (XIE Fei, WANG Yang-li, ZHAN Liang, GE Ming, LIANG Xiao-yi, QIAO Wen-ming, LING Li-cheng. Adsorption/desorption performance of CO2 on pitch-based spherical activated carbons[J]. J Inorg Mater, 2011, 26(2):149-154.)

    23. [23]

      [23] 陈琳琳,王霞,郭庆杰.四乙烯五胺修饰介孔硅胶吸附CO2性能的研究[J].燃料化学学报, 2015, 43(1):108-115. (CHEN Lin-lin, WANG Xia, GUO Qing-jie. Study on CO2 adsorption properties of tetraethylenepentamine modified mesoporous silica gel[J]. J Fuel Chem Technol, 2015, 43(1):108-115.)

  • 加载中
    1. [1]

      Shasha Ma ,  Zujin Yang ,  Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr2O72−: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008

    2. [2]

      Xueqi Yang ,  Juntao Zhao ,  Jiawei Ye ,  Desen Zhou ,  Tingmin Di ,  Jun Zhang . 调节NNU-55(Fe)的d带中心以增强CO2吸附和光催化活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-. doi: 10.1016/j.actphy.2025.100074

    3. [3]

      Xianghai Song ,  Xiaoying Liu ,  Zhixiang Ren ,  Xiang Liu ,  Mei Wang ,  Yuanfeng Wu ,  Weiqiang Zhou ,  Zhi Zhu ,  Pengwei Huo . Insights into the greatly improved catalytic performance of N-doped BiOBr for CO2 photoreduction. Acta Physico-Chimica Sinica, 2025, 41(6): 100055-. doi: 10.1016/j.actphy.2025.100055

    4. [4]

      Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408

    5. [5]

      Shanghua Li ,  Malin Li ,  Xiwen Chi ,  Xin Yin ,  Zhaodi Luo ,  Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003

    6. [6]

      Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029

    7. [7]

      Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO2 by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385

    8. [8]

      Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169

    9. [9]

      Pei Li ,  Yuenan Zheng ,  Zhankai Liu ,  An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012

    10. [10]

      Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO2 reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350

    11. [11]

      You Wu ,  Chang Cheng ,  Kezhen Qi ,  Bei Cheng ,  Jianjun Zhang ,  Jiaguo Yu ,  Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H2O2及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027

    12. [12]

      Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061

    13. [13]

      Xiuyun Wang ,  Jiashuo Cheng ,  Yiming Wang ,  Haoyu Wu ,  Yan Su ,  Yuzhuo Gao ,  Xiaoyu Liu ,  Mingyu Zhao ,  Chunyan Wang ,  Miao Cui ,  Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067

    14. [14]

      Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036

    15. [15]

      Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093

    16. [16]

      Jiayu Gu ,  Siqi Wang ,  Jun Ling . Kinetics of Living Copolymerization: A Brief Discussion. University Chemistry, 2025, 40(4): 100-107. doi: 10.12461/PKU.DXHX202406012

    17. [17]

      Xinyu Yin ,  Haiyang Shi ,  Yu Wang ,  Xuefei Wang ,  Ping Wang ,  Huogen Yu . Spontaneously Improved Adsorption of H2O and Its Intermediates on Electron-Deficient Mn(3+δ)+ for Efficient Photocatalytic H2O2 Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007

    18. [18]

      Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030

    19. [19]

      Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060

    20. [20]

      Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(619)
  • HTML views(50)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return