Citation: WANG Yi-shuang, CHEN Ming-qiang, LIU Shao-min, YANG Zhong-lian, SHEN Chao-ping, LIU Ke. Hydrogen production via catalytic steam reforming of bio-oil model compounds over NiO-Fe₂O₃-loaded palygouskite[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(12): 1470-1475. shu

Hydrogen production via catalytic steam reforming of bio-oil model compounds over NiO-Fe₂O₃-loaded palygouskite

1.
1. School of Earth and Environment, Anhui University of Science and Technology, Huainan 232001, China;

Corresponding author: CHEN Ming-qiang,
Received Date: 7 July 2015
Available Online: 28 August 2015
Fund Project: 国家自然科学基金(21376007) (21376007)国家科技支撑计划项目(2014BAD02B03)资助 (2014BAD02B03)

A series of NiO-Fe₂O₃ catalysts loaded on palygouskite were prepared by co-precipitation method and used in the catalytic steam reforming to produce hydrogen in a self-made three-stage fixed bed reactor. The loading of NiO-Fe₂O₃, reaction temperature and ratio of steam to carbon (S/C) on hydrogen production were investigated, with a water-soluble mixture of acetic acid, ethanol and phenol as the bio-oil model compounds. The results indicated that under the optimum conditions, viz., 650℃, an S/C ratio of 8~10 and 50%NiO-50%Fe₂O₃/PG as the catalyst, the relative content of H₂ reaches 66.15% in the gaseous product.
- bio-oil model compound,
- steam reforming,
- hydrogen production,
- palygouskite,
- NiO-Fe₂O₃
1. [1]
  [1] PENA M, GOMEZ J, FIERRO J. New catalytic routes for syngas and hydrogen production[J]. Appl Catal A:Gen, 1996, 144(2):7-57.
2. [2]
  [2] 林鹏,虞亚辉,罗永浩,陈祎.生物质热化学制氢的研究进展[J].化学反应工程与工艺, 2007, 23(3):267-272. (LIN Peng, YU Ya-hui, LUO Yong-hao, CHEN Yi. The research progress of hydrogen production via biomass thermochemistry[J]. Chem React Eng Technol, 2007, 23(3):267-272.)
3. [3]
  [3] BOSSEL U. The future of the hydrogen economy:Bright or bleak?[J]. Cogener Compet Power J, 2009, 18(3):29-70.
4. [4]
  [4] LEVIN D B, CHAHINE R. Challenges for renewable hydrogen production from biomass[J]. Int J Hydrogen Energy, 2010, 35(10):4962-4969.
5. [5]
  [5] HERACLEOUS E. Well-to-Wheels analysis of hydrogen production from bio-oil reforming for use in internal combustion engines[J]. Fuel Energy Abstr, 2011, 36(18):11501-11511.
6. [6]
  [6] BIMBELA F, OLIVA M, RUIZ J, ARAUZO J. Hydrogen production via catalytic steam reforming of the aqueous fraction of bio-oil using nickel-based coprecipitated catalysts[J]. Int J Hydrogen Energy, 2013, 38(34):14476-14487.
7. [7]
  [7] XIE H, YU Q, WEI M, DUAN W, YAO X, QIN Q, ZUO Z. Hydrogen production from steam reforming of simulated bio-oil over Ce-Ni/Co catalyst with in continuous CO₂ capture[J]. Int J Hydrogen Energy, 2015, 40(3):1420-1428.
8. [8]
  [8] XIAO R, ZHANG S, PENG S, SHEN D, LIU K. Use of heavy fraction of bio-oil as fuel for hydrogen production in iron-based chemical looping process[J]. Int J Hydrogen Energy, 2014, 39:19955-19969.
9. [9]
  [9] DING N, AZARGOHAR R, DALAI A K, KOZINSKI J A. Catalytic gasification of cellulose and pinewood to H₂ in supercritical water[J]. Fuel, 2014, 118(1):416-425.
10. [10]
  [10] RESENDE K A, ÁVILA-NETO C N, RABELO-NETO R C, NORONHA F B, HORI C E. Hydrogen production by reforming of acetic acid using La-Ni type perovskites partially substituted with Sm and Pr[J]. Catal Today, 2015, 242:71-79.
11. [11]
  [11] YAO D, WU C, YANG H, HU Q, NAHIL M A, CHEN H, WILLIAMS P T. Hydrogen production from catalytic reforming of the aqueous fraction of pyrolysis bio-oil with modified Ni-Al catalysts[J]. Int J Hydrogen Energy, 2014, 39(27):14642-14652.
12. [12]
  [12] WANG D, CZERNIK S, MONTANE D, MANN M, CHORNET E. Biomass to hydrogen via fast pyrolysis and catalytic steam reforming of the pyrolysis oil or its fractions[J]. Ind Eng Chem Res, 1997, 36(5):1507-1518.
13. [13]
  [13] XIE H, YU Q, WANG K, SHI X, LI X. Thermodynamic analysis of hydrogen production from model compounds of bio-oil through steam reforming[J]. Environ Prog Sustainable Energy, 2014, 33(3):1008-1016.
14. [14]
  [14] WANG D, MONTANE D, CHORNET E. Catalytic steam reforming of biomass-derived oxygenates:Acetic acid and hydroxyacetaldehyde[J]. Appl Catal A:Gen, 1996, 143(2):245-270.
15. [15]
  [15] 林少斌.用纳米SiO₂担载的Ni-Cu-Zn催化剂对电催化水蒸气重整生物油制氢的研究[D].合肥:中国科学技术大学, 2010. (LIN Shao-bing. Research on the hydrogen production from Bio-oil by electrochemical catalytic steam reforming using Ni-Cu-Zn-nano SiO₂[D]. Hefei:University of Science and Technology of China, 2010.)
16. [16]
  [16] MORAES T, NETO R, RIBEIRO M, MATTOS L, KOURTELESIS M, LADAS S, VERYKIOS X, NORONHA F. The study of the performance of PtNi/CeO₂-nanocube catalysts for low temperature steam reforming of ethanol[J]. Catal Today, 2015, 242:35-49.
17. [17]
  [17] BUSSI J, BESPALKO N, VEIGA S, AMAYA A, FACCIO R, ABELLO M. The preparation and properties of Ni-La-Zr catalysts for the steam reforming of ethanol[J]. Catal Commun, 2008, 10(1):33-38.
18. [18]
  [18] GALLEGOS-SUAREZ E, GUERRERO-RUI Z, FERNANDEZ-GARCIA M, RODRIGUEZ-RAMOS I, KUBACKA A. Efficient and stable Ni-Ce glycerol reforming catalysts:Chemical imaging using X-ray electron and scanning transmission microscopy[J]. Appl Catal B:Environ, 2015, 165:139-148.
19. [19]
  [19] NOGUEIRA F, ASSAF P, CARVALHO H, ASSAF E. Catalytic steam reforming of acetic acid as a model compound of bio-oil[J]. Appl Catal B:Environ, 2014, 160(7):188-199.
20. [20]
  [20] HE Z, YANG M, WANG X, ZHAO Z, DUAN A. Effect of the transition metal oxide supports on hydrogen production from bio-ethanol reforming[J]. Catal Today, 2012, 194(1):2-8.
21. [21]
  [21] SCOTT M, GOEFFROY M, CHIU W, BLACKFORD M, IDRISS H. Hydrogen production from ethanol over Rh-Pd/CeO₂ catalysts[J]. Top Catal, 2008, 51(1/4):13-21.
22. [22]
  [22] CHIOU J, WANG C, YANG S, BI J, SHEN C, WANG C. Reforming of ethanol to produce hydrogen over PtRuMg/ZrO₂ catalyst[J]. J Nanosci Nanotechnol, 2012, 2012:1-6.
23. [23]
  [23] XIAO R, ZHANG S, PENG S, SHEN D, LIU K. Use of heavy fraction of bio-oil as fuel for hydrogen production in iron-based chemical looping process[J]. Int J Hydrogen Energy, 2014, 39:19955-19969.
24. [24]
  [24] LIU S, CHEN M, LEI C, YANG Z, ZHU C, WANG J, CHEN M. Catalytic steam reforming of bio-oil aqueous fraction for hydrogen production over Ni-Mo supported on modified sepiolite catalysts[J]. Int J Hydrogen Energy, 2013, 38(10):3948-3955.
25. [25]
  [25] 陈天虎,彭书传,黄川徽,史晓莉,冯有亮.从苏皖凹凸棒石粘土制备纯凹凸棒石[J].硅酸盐学报, 2004, 32(8):965-969. (CHEN Tian-hu, PENG Shu-zhuan, HUANG Chuan-wei, SHI Xiao-li, FENG You-liang. Preparation of pure palygorskite from palygorskite claysin JiangSu and AnHui[J]. J Chin Ceram Soc, 2004, 32(8):965-969.)
26. [26]
  [26] CHEN T, XU H, LU A, XU X, PENG S, YUE S. Direct evidence of transformation from smectite to palygorskite:TEM investigation[J]. Sci China, 2004, 47(11):985-994.
27. [27]
  [27] WANG L, KOIKE M, KOSO S. Catalytic performance and characterization of Ni-Fe catalysts for the steam reforming of tar from biomass pyrolysis[J]. Proc Jpi, 2010:120.
28. [28]
  [28] HOU T, ZHANG S, CHEN Y, WANG D, CAI W. Hydrogen production from ethanol reforming:Catalysts and reaction mechanism[J]. Renew Sust Energy Rev, 2015, 44:132-148.
29. [29]
  [29] ABELLO S, BOLSHAK E, MONTANE D. Ni-Fe catalysts derived from hydrotalcite-like precursors for hydrogen production by ethanol steam reforming[J]. Appl Catal A:Gen, 2013, 450(2):261-274.
30. [30]
  [30] LAOSIRIPOJANA N, SUTTHISRIPOK W, CHAROJROCHKUL S, ASSABUMRUNGRAT S. Development of Ni-Fe bimetallic based catalysts for biomass tar cracking/reforming:Effects of catalyst support and co-fed reactants on tar conversion characteristics[J]. Fuel Process Technol, 2014, 127(11):26-32.
31. [31]
  [31] FU P, YI W, LI Z, BAI X, ZHANG A, LI Y, LI Z. Investigation on hydrogen production by catalytic steam reforming of maize stalk fast pyrolysis bio-oil[J]. Int J Hydrogen Energy, 2014, 39(26):13962-13971.
32. [32]
  [32] DOMINE M, IOJOIU E, DAVIDIAN T, GUILHAUME, MIRODATOS C. Hydrogen production from biomass-derived oil over monolithic Pt-and Rh-based catalysts using steam reforming and sequential cracking processes[J]. Catal Today, 2008, 133(2):565-573.
33. [33]
  [33] IWASA N, YAMANE T, ARAI M. Influence of alkali metal modification and reaction conditions on the catalytic activity and stability of Ni containing smectite-type material for steam reforming of acetic acid[J]. Int J Hydrogen Energy, 2011, 36(10):5904-5911.
34. [34]
  [34] WANG S, FAN Z, CAI Q, LI X, ZHU L, WANG Q, LUO Z. Catalytic steam reforming of bio-oil model compounds for hydrogen production over coal ash supported Ni catalyst[J]. Int J Hydrogen Energy, 2014, 39(5):2018-2025.
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沈阳化工大学材料科学与工程学院沈阳 110142

Hydrogen production via catalytic steam reforming of bio-oil model compounds over NiO-Fe2O3-loaded palygouskite

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通讯作者: 陈斌, bchen63@163.com

Hydrogen production via catalytic steam reforming of bio-oil model compounds over NiO-Fe₂O₃-loaded palygouskite