Citation: DONG Hui-huan, GUO Xing-cui, QIN Zhang-feng, HAN Sheng, MU Xin-dong. Effect of modified groups of carbon nanotubes on catalytic properties of Ru/CNTs catalysts for hydrogenolysis of sorbitol[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(12): 1454-1460. shu

Effect of modified groups of carbon nanotubes on catalytic properties of Ru/CNTs catalysts for hydrogenolysis of sorbitol

1.
1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China;

Corresponding author: HAN Sheng, MU Xin-dong,
Received Date: 9 June 2015
Available Online: 14 September 2015
Fund Project: 国家自然科学基金(21406251,21201174) (21406251,21201174)煤转化国家重点实验室开放课题(J13-14-603)资助 (J13-14-603)

Ruthenium catalysts supported on carbon nanotubes with different functional groups (MCN, AMCN and GMCN) were prepared by incipient wetness impregnation with ultrasonic-assistance and used for the hydrogenolysis of sorbitol. The catalysts were characterized by X-ray diffraction (XRD), HRTEM, X-ray photoelectron spectroscopy (XPS) and ICP-AES. The effects of functional group species, and base additives on the catalytic performance of Ru/CNTs in the sorbitol hydrogenolysis reaction were investigated. Nearly 99.5% of sorbitol conversion and 47.7% total yield of ethylene glycol and 1,2-propanediol (1,2-PD) could be achieved over Ru/AMCN under mild reaction conditions (205℃, 5.0 MPa), using Ca(OH)₂ as additive. The conversion of sorbitol and the selectivity to ethylene glycol (EG) and 1,2-propanediol (1,2-PD) did not decrease over the five repeated runs, which confirmed that the Ru/AMCN catalyst exhibited high stability in the aqueous hydrogenolysis of sorbitol to glycols.
- sorbitol,
- hydrogenolysis,
- 1,2-propanediol,
- ethylene glycol,
- Ru/CNTs,
- functionalization
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