Citation: ZENG Zhi-wei, ZOU Jun, YANG Hai-ping, WANG Xian-hua, WU Chun-fei, PT William, CHEN Han-ping. Influence of potassium on the performance of nickel-based catalyst in the steam gasification of cellulose[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(12): 1433-1438. shu

Influence of potassium on the performance of nickel-based catalyst in the steam gasification of cellulose

1.
1. State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China;

Corresponding author: YANG Hai-ping,
Received Date: 13 May 2015
Available Online: 5 August 2015
Fund Project: 国家自然科学基金(51376076,51306066) (51376076,51306066)国家重点基础研究发展规划(973计划,2013CB228102)资助项目 (973计划,2013CB228102)

The influence of alkali metal volatilization on the performance of nickel-based catalyst in the steam gasification of cellulose biomass was investigated in a two-stage fixed bed reactor. The results show that potassium is deposited on the catalyst surface with the volatilization of potassium salt during the catalytic steam reforming of potassium-loaded cellulose. The existence and deposition of proper amount of potassium may suppress the coke deposition and enhance the activity of nickel-based catalyst, which is of benefit to producing more hydrogen in the steam gasification of biomass. However, excessive amount of potassium loaded in cellulose may reduce the activity of nickel-based catalyst; moreover, with the repetitious operations, potassium is accumulated on the catalyst surface, which may lead to an obvious inhibitory effect on the activity and stability of nickel-based catalyst in the steam gasification of biomass.
- alkali metals,
- nickel-based catalyst,
- cellulose,
- steam gasification
1. [1]
  [1] ABUADALA A, DINCER I. A review on biomass-based hydrogen production and potential applications[J]. Int J Energy Res, 2012, 36(4):415-455.
2. [2]
  [2] 王东旭,肖显斌,高静,詹芳蕾,覃吴,董长青.助剂钾对镍基催化剂性能影响研究进展[J].化工进展, 2014, 33(3):668-672. (WANG Dong-xu, XIAO Xian-bin, GAO Jing, ZHAN Fang-lei, QIN Wu, DONG Chang-qing. A review of potassium promoter effect on nickel-based catalyst performance[J]. Chem Ind Eng Prog, 2014, 33(3):668-672.)
3. [3]
  [3] 郭建维,宋晓锐,崔英德.流化床反应器中生物质的催化裂解气化研究[J].燃料化学学报, 2001, 29(4):319-322. (GUO Jian-wei, SONG Xiao-rui, CUI Ying-de. Catalytic pyrogasification of biomass in a fluidized-bed reactor[J]. J Fuel Chem Technol, 2001, 29(4):319-322.)
4. [4]
  [4] DEVI L, PTASINSKI K J, JANSSEN F. A review of the primary measures for tar elimination in biomass gasification processes[J]. Biomass Bioenergy, 2003, 24(2):125-140.
5. [5]
  [5] 李庆远,季生福,胡金勇,蒋赛.镍基催化剂上稻草水蒸气重整制富氢合成气[J].催化学报, 2013, 34(7):1462-1468. (LI Qing-yuan, JI Sheng-fu, HU Jin-yong, JIANG Sai. Catalytic steam reforming of rice straw biomass to hydrogen-rich syngas over Ni-based catalysts[J]. Chin J Catal, 2013, 34(7):1462-1468.)
6. [6]
  [6] KIMURA T, MIYAZAWA T, NISHIKAWA J, KADO S, OKUMURA K, MIYAO T, NAITO S C, KUNIMORI K, TOMISHIGE K. Development of Ni catalysts for tar removal by steam gasification of biomass[J]. Appl Catal B:Environ, 2006, 68(3/4):160-170.
7. [7]
  [7] WU C, WANG Z, DUPONT V, HUANG J, WILLIAMS P. Nickel-catalysed pyrolysis/gasification of biomass components[J]. Anal Appl, 2013, 99(0):143-148.
8. [8]
  [8] FAHMI R, BRIDGWATER A V, DARVELL L I, JONES J M, YATES N, THAIN S, DONNSION I S. The effect of alkali metals on combustion and pyrolysis of Lolium and Festuca grasses, switchgrass and willow[J]. Fuel, 2007, 86(10/11):1560-1569.
9. [9]
  [9] KEOWN D M, FAVAS G, HAYASHI J I, LI C Z. Volatilisation of alkali and alkaline earth metallic species during the pyrolysis of biomass:Differences between sugar cane bagasse and cane trash[J]. Bioresour Technol, 2005, 96(14):1570-1577.
10. [10]
  [10] KOWALSKI T, LUDWIG C, WOKAUN A. Qualitative evaluation of alkali release during the pyrolysis of biomass[J]. Energy Fuels, 2007, 21(5):3017-3022.
11. [11]
  [11] JENSEN P A, FRANDSEN F J, DAM-JOHANSEN K, SANDER B. Experimental investigation of the transformation and release to gas phase of potassium and chlorine during straw pyrolysis[J]. Energy Fuels, 2000, 14(6):1280-1285.
12. [12]
  [12] DAYTON D C, JENKINS B M, TURN S Q, BAKKER R R, WILLIAMS R B, OUDRY D B, HILL L M. Release of inorganic constituents from leached biomass during thermal conversion[J]. Energy Fuels, 1999, 13(4):860-870.
13. [13]
  [13] JIANG L, HU S, XIANG J, SU S, SUN L S, XU K, YAO Y. Release characteristics of alkali and alkaline earth metallic species during biomass pyrolysis and steam gasification process[J]. Bioresour Technol, 2012, 116:278-284.
14. [14]
  [14] ZHANG Z H, SONG Q, YAO Q, YANG R M. Influence of the atmosphere on the transformation of alkali and alkaline earth metallic species during rice straw thermal conversion[J]. Energy Fuels, 2012, 26(3):1892-1899.
15. [15]
  [15] 韩旭,张岩丰,姚丁丁,钱柯贞,杨海平,王贤华.生物质气化过程中碱金属和碱土金属的析出特性研究[J].燃料化学学报, 2014, 42(7):792-798. (HAN Xu, ZHANG Yan-feng, YAO Ding-ding, QIAN Ke-zhen, YANG Hai-ping, WANG Xian-hua. Releasing behavior of alkali and alkaline earth metals during biomass gasification[J]. J Fuel Chem Technol, 2014, 42(7):792-798.)
16. [16]
  [16] 杨海平,陈汉平,杜胜磊,陈应泉,王贤华,张世红.碱金属盐对生物质三组分热解的影响[J].中国电机工程学报, 2009, 29(17):70-75. (YANG Hai-ping, CHEN Han-ping, DU Sheng-lei, CHEN Ying-quan, WANG Xian-hua, ZHANG Shi-hong. Influence of alkali salts on the pyrolysis of biomass three components[J]. Pro CSEE, 2009, 29(17):70-75.)
17. [17]
  [17] 王贤华,陈汉平,王静,辛芬,杨海平.无机矿物质盐对生物质热解特性的影响[J].燃料化学学报, 2008, 36(6):679-683. (WANG Xian-hua, CHEN Han-ping, WANG-Jing XIN Fen, YANG Hai-ping. Influences of mineral matters on biomass pyrolysis characteristics[J]. J Fuel Chem Technol, 2008, 36(6):679-683.)
18. [18]
  [18] EOM I Y, KIM J Y, KIM T S, LEE S M, CHOI D, CHOI I G, CHOI J W. Effect of essential inorganic metals on primary thermal degradation of lignocellulosic biomass[J]. Bioresour Technol, 2012, 104(0):687-694.
19. [19]
  [19] 郝庆兰,李博仑,刘垒,张征标,豆宝娟,王昶.钾元素对生物质及其三组分热解的影响[J].燃料化学学报, 2015, 43(1):34-41. (HAO Qing-lan, LI Bo-lun, LIU Lei, ZHANG Zheng-biao, DOU Bao-juan, WANG Chang. Effect of potassium on pyrolysis of rice husk and its components[J]. J Fuel Chem Technol, 2015, 43(1):34-41.)
20. [20]
  [20] HOSOKAI S, HAYASHI J I, SHIMADA T, KOBAYASHI Y, KURAMOTO K, LI C-Z, CHIBA T. Spontaneous generation of tar decomposition promoter in a biomass steam reformer[J]. Chem Eng Res Des, 2005, 83(A9):1093-1102.
21. [21]
  [21] KEOWN D M, HAYASHI J I, LI C Z. Effects of volatile-char interactions on the volatilisation of alkali and alkaline earth metallic species during the pyrolysis of biomass[J]. Fuel, 2008, 87(7):1187-1194.
22. [22]
  [22] KUCHONTHARA P, PUTTASAWAT B, PIUMSOMBOON P, MEKASUT L, VITIDSANT T. Catalytic steam reforming of biomass-derived tar for hydrogen production with K₂CO₃/NiO/γ-Al₂O₃ catalyst[J]. Korean J Chem Eng, 2012, 29(11):1525-1530.
23. [23]
  [23] KUCHONTHARA P, VITIDSANT T, TSUTSUMI A. Catalytic effects of potassium on lignin steam gasification with γ-Al₂O₃ as a bed material[J]. Korean J Chem Eng, 2008, 25(4):656-662.
24. [24]
  [24] WU C, WANG Z, HUANG J, WILLIAMS P T. Pyrolysis/gasification of cellulose, hemicellulose and lignin for hydrogen production in the presence of various nickel-based catalysts[J]. Fuel, 2013, 106:697-706.
25. [25]
  [25] 武宏香,赵增立,张伟,李海滨,何方.碱/碱土金属对纤维素热解特性的影响[J].农业工程学报, 2012, 28(4):215-220. (WU Hong-xiang, ZHAO Zeng-li, ZHANG Wei, LI Hai-bin, HE Fang. Effects of alkali/alkaline earth metals on pyrolysis characteristics of cellulose[J]. Trans Chin Soc Agric Eng, 2012, 28(4):215-220.)
26. [26]
  [26] PATWARDHAN P, SATRIO J A, BROWN R C, SHANKS B H. Influence of inorganic salts on the primary pyrolysis products of cellulose[J]. Bioresour Technol, 2010, 101(12):4646-4655.
27. [27]
  [27] JUAN-JUAN J, ROM N-MART NEZ M C, ILL N-G MEZ M J. Effect of potassium content in the activity of K-promoted Ni/Al₂O₃ catalysts for the dry reforming of methane[J]. Appl Catal A:Gen, 2006, 301(1):9-15.
28. [28]
  [28] JUAN-JUAN J, ROM N-MARTÍNEZ M C, ILL N-G MEZ M J. Catalytic activity and characterization of Ni/Al₂O₃ and NiK/Al₂O₃ catalysts for CO₂ methane reforming[J]. Appl Catal A:Gen, 2004, 264(2):169-174.
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