Citation: NIU Xin, SHEN Lai-hong, XIAO Jun, JIANG Shou-xi, GU Hai-ming. Chemical looping combustion of sewage sludge with oxygen carrier of cement-modified hematite[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(11): 1402-1408. shu

Chemical looping combustion of sewage sludge with oxygen carrier of cement-modified hematite

  • Corresponding author: SHEN Lai-hong, 
  • Received Date: 27 May 2015
    Available Online: 23 July 2015

    Fund Project: 国家自然科学基金(51476029,51276037,51406035,51561125001)资助项目 (51476029,51276037,51406035,51561125001)

  • Chemical looping combustion (CLC) for sewage sludge has a relatively low efficiency using hematite as oxygen carrier. The experiments on improving the reactivity of hematite with cement modified for CLC of sewage sludge in a 1kWth continuous CLC unit were carried out. Compared to hematite oxygen carrier, the concentrations of unconverted combustible gas rapidly decrease when the cement-hematite is used. Moreover, both carbon conversion and combustion efficiency increase when the cement is added. Although some ash particles deposit on the surface of oxygen carrier and a part of Fe2O3 is reduced to FeO, there are no defluidization and sintering problems.
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    1. [1]

      [1] WERTHER J, OGADA T. Sewage sludge combustion[J]. Prog Energy Combust Sci, 1999, 25 (1): 55-116.

    2. [2]

      [2] ADANEZ J, ABAD A, GARCIA L F,GAYAN P, DE DIEGO LUIS F. Progress in chemical-looping combustion and reforming technologies[J]. Prog Energy Combust Sci, 2012, 38(2): 215-282.

    3. [3]

      [3] 金红光, 洪慧, 韩涛. 化学链燃烧的能源环境系统研究进展[J]. 科学通报, 2008, (24): 2994-3005. (JIN Hong-guang, HONG Hui, HAN Tao. The process of energy and environmental systems in chemical looping combustion[J]. Chin Sci Bull, 2008, (24): 2994-3005.)

    4. [4]

      [4] SONG T, SHEN L H, XIAO J, CHEN D Q, GU H M, ZHANG S W. Nitrogen transfer of fuel-N in chemical looping combustion[J]. Combust Flame, 2012, 159(3): 1286-1295.

    5. [5]

      [5] HUA X N, WANG W. Chemical looping combustion: A new low-dioxin energy conversion technology[J]. J Environ Sci, 2015, 32: 135-145.

    6. [6]

      [6] SONG T, SHEN L H, XIAO J, CHEN D Q, GU H M, ZHANG S W. Evaluation of hematite oxygen carrier in chemical-looping combustion of coal[J]. Fuel, 2013, 104: 244-252.

    7. [7]

      [7] GU H M, SHEN L H, XIAO J, ZHANG S W, SONG T, CHEN D Q. Iron ore as oxygen carrier improved with potassium for chemical looping combustion of anthracite coal[J]. Combust Flame, 2012, 159(7): 2480-2490.

    8. [8]

      [8] NIU X, SHEN L H, GU H M, JIANG S X, XIAO J. Characteristics of hematite and fly ash during chemical looping combustion of sewage sludge[J]. Chem Eng J, 2015, 268: 236-244.

    9. [9]

      [9] SONG T, SHEN L H, ZHANG S W, CHEN D Q, XIAO J. Performance of hematite/Ca2Al2SiO7 oxygen carrier in chemical looping combustion of coal[J]. Ind Eng Chem Res, 2013, 52(22): 7350-7361.

    10. [10]

      [10] SONG T, SHEN L H, GUO W J, CHEN D Q, XIAO J. Enhanced reaction performance with hematite/Ca2Al2SiO7 oxygen carrier in chemical looping combustion of coal[J]. Ind Eng Chem Res, 2013, 52(28): 9573-9585.

    11. [11]

      [11] SHEN L H, WU J H, GAO Z P, XIAO J. Characterization of chemical looping combustion of coal in a 1kWth reactor with a nickel-based oxygen carrier[J]. Combust Flame, 2010, 157(5): 934-942.

    12. [12]

      [12] CUADRAT A, ABAD A, GARCIA-LABIANO F, GAYAN P, DIEGO L F, ADANEZ J. Relevance of the coal rank on the performance of the in situ gasification chemical-looping combustion[J]. Chem Eng J, 2012, 195-196: 91-102.

    13. [13]

      [13] KELLER M, LEION H, MATTISSON T, LYNGFELT A. Gasification inhibition in chemical-looping combustion with solid fuels[J]. Combust Flame, 2011, 158(3): 393-400.

    14. [14]

      [14] ZHAO C S, LIN L S, PANG K L, XIANG W G, CHEN X P . Experimental study on catalytic steam gasification of natural coke in a fluidized bed[J]. Fuel Process Technol, 2010, 91(8): 805-809.

    15. [15]

      [15] DAHLIN R S, PENG W W, NELSON M, VIMALCHAND P, LIU G H. Formation and prevention of agglomerated deposits during the gasification of high-sodium lignite[J]. Energy Fuels, 2006, 20(6): 2465-2470.

    16. [16]

      [16] LANG R J, NEAVEL R C. Behaviour of calcium as a steam gasification catalyst[J]. Fuel, 1982, 61(7): 620-626.

    17. [17]

      [17] BAO J H, LI Z S, CAI N S. Reduction kinetics of foreign-ion-promoted ilmenite using carbon monoxide (CO) for chemical looping combustion[J]. Ind Eng Chem Res, 2013, 52(31): 10646-10655.

    18. [18]

      [18] BAO J H, LI Z S, CAI N S. Promoting the reduction reactivity of ilmenite by introducing foreign ions in chemical looping combustion[J]. Ind Eng Chem Res, 2013, 52(18): 6119-6128.

    19. [19]

      [19] SHEN L H, WU J H, GAO Z P, XIAO J. Reactivity deterioration of NiO/Al2O3 oxygen carrier for chemical looping combustion of coal in a 10kWth reactor[J]. Combust Flame, 2009, 156(7): 1377-1385.

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