Citation: SHI Bin, CHENG Wen-wen, KONG Qing-yang. Hydrogenation of phenol over Urushibara Ni catalysts reduced by zinc powder[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(10): 1252-1257. shu

Hydrogenation of phenol over Urushibara Ni catalysts reduced by zinc powder

1.
1. State Key Laboratory of Heavy Oil, China University of Petroleum (Huadong), Qingdao 266580;

Corresponding author: SHI Bin,
Received Date: 8 February 2015
Available Online: 2 June 2015
Fund Project: 中央高校基本科研业务费专项资金(27R1104054A)资助项目 (27R1104054A)

Urushibara nickel catalysts were prepared from aqueous NiCl₂ solution with zinc powder as a reducing agent and used in phenol hydrogenation. The effects of zinc powder amount, reduction temperature and pretreatment-activation method on the catalytic performance of Urushibara nickel in phenol hydrogenation was investigated. To inhibit the magnetic agglomeration of the pure nickel catalyst, γ-Al₂O₃, CaCO₃ and MgO were added as a support. The results indicated that the nickel catalysts obtained by zinc reduction can be pretreated and activated by NaOH or acetic acid solution, though the former is superior to the latter. The catalytic activity of Urushibara nickel is related to the amount of zinc used for the reduction. The nickel catalyst reduced at 100 ℃ with an n(Zn)/n(NiCl₂·6H₂O) ratio of 4.5 exhibits the highest hydrogenation activity. γ-Al₂O₃ as a support can promote the dispersion and sediment of the reduced nickel and alleviate the magnetic agglomeration. The Urushibara nickel catalysts are active for phenol hydrogenation at 120~160 ℃, with cyclohexanol and cyclohexanone as the main products; the conversion of phenol reaches 53%~66%, with the selectivity of 95.0%~96.0% to cyclohexanol.
- Urushibara nickel,
- catalytic,
- phenol,
- hydrogenation,
- zinc,
- reduction,
- support
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