Citation: WANG Rui-yu, GUO Ming, LI Zhong. Preparation and oxycarbonylation of activated carbon supported copper-based catalyst by deposition-precipitation method[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(9): 1142-1146. shu

Preparation and oxycarbonylation of activated carbon supported copper-based catalyst by deposition-precipitation method

WANG Rui-yu ¹ ,
GUO Ming ¹ ,
LI Zhong ^2,,

1.
1. Key Laboratory of Coal-based CO₂ Capture and Geological Storage of Jiangsu Province, China University of Mining and Technology, Xuzhou 221006, China;

Corresponding author: LI Zhong,
Received Date: 15 December 2014
Available Online: 14 April 2015
Fund Project: 国家自然科学基金(21506249) (21506249) 江苏省博士后基金(1401096c) (1401096c) 中央高校基本科研业务费(中国矿业大学,2014QNA19)。 (中国矿业大学,2014QNA19)

The activated carbon supported copper-based catalyst was prepared by deposition-precipitation method and used to catalyze the direct vapor-phase oxycarbonylation of methanol to dimethyl carbonate (DMC). The effect of preparation conditions(such as copper salt, reductant, precipitant and loading amount ect) on the catalytic performance were investigated by XRD, H₂-TPR and SEM techniques. The result showed that under the condition of MeOH/CO/O₂(volume ratio)=5:11:1, SV=6 625 h^-1, Cu₂O /AC catalyst (Cu(CH₃COO)₂·H₂O as precursor, glucose as reductant, Cu₂O loading amount of 17.1%) showed satisfactory catalytic performance for DMC synthesis. The STY reached 99.36 mg/(g·h) and the selectivity of DMC was about 83.13%.
- copper-based catalyst,
- activated carbon,
- deposition-precipitation method,
- oxidative carbonylation,
- dimethyl carbonate
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