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Citation: SONG Hua, ZHANG Fu-yong, XU Xiao-wei, SONG Hua-lin, LI Feng. Effect of Pr and Ce on the activity of Ni2P catalyst prepared by low temperature reduction in hydrodesulphurization[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(9): 1128-1133. shu

Effect of Pr and Ce on the activity of Ni2P catalyst prepared by low temperature reduction in hydrodesulphurization

  • 1.

    1. Provincial Key Laboratory of Oil & Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China;

  • Corresponding author: SONG Hua,  SONG Hua-lin, 
  • Received Date: 16 February 2015
    Available Online: 14 May 2015

    Fund Project: 国家自然科学基金(21276048) (21276048) 黑龙江省自然科学基金(ZD201201) (ZD201201) 黑龙江省教育厅项目(12541060)。 (12541060)

  • The Ni2P-L, Pr-Ni2P-L and Ce-Ni2P-L catalysts were prepared by thermal decomposition of hypophosphites and reduced at low temperature; they were characterized by X-ray diffraction (XRD), temperature programmed reduction with hydrogen (H2-TPR), nitrogen physisorption, CO adsorption, and X-ray photoelectron spectroscopy (XPS). The effect of the rare earth praseodymium (Pr) or cerium (Ce) elements on the activity of Ni2P-L catalyst in hydrodesulfurization (HDS) was investigated with dibenzothiophene (DBT) as a model compound. The results indicated that the addition of Pr and Ce can suppress the formation of Ni5P4 and other mixed crystal phases and then promote the formation of Ni2P phase. After adding the rare earth metals, the selectivity to BP over the Ni2P catalyst is enhanced greatly, though the total HDS activity is decreased slightly.
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