Advanced Search

Citation: ZHANG Wei, LIU Xiao-dan, BAI Ying-zhi, WANG Hai-yan, WEI Min. Study on the structure and performance of MoO3-ZrO2 composite catalysts with different Mo/Zr mass ratios[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(8): 998-1003. shu

Study on the structure and performance of MoO3-ZrO2 composite catalysts with different Mo/Zr mass ratios

  • 1.

    1. School of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China;

  • Corresponding author: WANG Hai-yan, 
  • Received Date: 4 January 2015
    Available Online: 26 March 2015

    Fund Project: 国家自然科学基金(21276253)。 (21276253)

  • Mesoporous MoO3-ZrO2 composite oxides were prepared by sol-gel method. The influence of the mass ratio of MoO3/ZrO2 on the crystal phase, specific surface area, pore size and morphology characteristics were investigated. The synthesized composite oxides were characterized by XRD, BET, SEM and FT-IR. With FCC gasoline fraction as the raw material, the catalytic activity was evaluated by hydrodesulfurization reaction after the prevulcanization of the composite oxides. The results show that the ZrO2 containing MoO3 had less monoclinic phase than ZrO2 and mainly existed in stable tetragonal phase. The appropriate improvement of the mass ratio of MoO3/ZrO2 were beneficial to the increase of specific surface area and average pore size. The excessive mass ratio of MoO3/ZrO2 depressed the formation of mesopores and produced a new type chemical bond and a small amount of Zr(MoO4)2 crystal phase. When the mass ratio of MoO3/ZrO2 was 30%, the worm structure appeared on the surface of ZrO2, and the desulfurization rate reached its maximum. Thus, the appropriate improvement of the mass ratio of MoO3/ZrO2 could obtain a higher desulfurization rate.
  • 加载中
    1. [1]

      [1] MAZURELLE J, LAMONIER C, LANCELOT C, PAYEN E, PICHON C. Use of the cobalt salt of the heteropolyanion [Co2Mo10O38H4]6-for the preparation of CoMo HDS catalysts supported on Al2O3, TiO2 and ZrO2[J]. Catal Today, 2008, 130(1): 41-49.

    2. [2]

      [2] WANG C, TSAI T, WANG I. Deep hydrodesulfurization over Co/Mo catalysts supported on oxides containing vanadium[J]. J Catal, 2009, 262(2): 206-214.

    3. [3]

      [3] KALUŽ L, ZDRAŽIL M, VÍT Z, GULKOVÁ D. CoMo/ZrO2 hydrodesulfurization catalysts prepared by chelating agent assisted spreading[J]. Procedia Eng, 2012, 142(8): 261-266.

    4. [4]

      [4] 张华阳, 李锋, 宋华. Ni-Mo-P/Al2O3-ZrO2催化剂的制备及加氢脱硫脱氮活性[J]. 科学技术与化工, 2012, 12(18): 4434-4439.(ZHANG Hua-yang, LI Feng, SONG Hua. Preparation, hydrodesulfurization and hydrogenitrogenation herformance of Ni-Mo-P/Al2O3-ZrO2 catalyst[J]. Sci Technol Eng, 2012, 12(18): 4434-4439.)

    5. [5]

      [5] EL-SHARKAWY E A, KHDER A S, AHMED A I. Structural characterization and catalytic activity of molybdenum oxide supported zirconia catalysts[J]. Microporous Mesoporous Mater, 2007, 102(1/3): 128-137.

    6. [6]

      [6] KEMDEO S M, SAPKAL V S, CHAUDHARI G N. TiO2-SiO2 mixed oxide supported MoO3 catalyst: Physicochemical characterization and activities in nitration of phenol[J]. J Mol Catal A: Chem, 2010, 323(1): 70-77.

    7. [7]

      [7] LI Y X, GALATSIS K, WLODARSKI W, PASSACANTANDO M, SANTUCCI S, SICILIANO P, CATALANO M. Microstructural characterization of MoO3-TiO2 nanocomposite thin films for gas sensing[J]. Sens Actuators B, 2001, 77(1/2): 27-34.

    8. [8]

      [8] CATTIN L, MORSLI M, DAHOU F, YAPI ABE S, KHELIL A, BERNÈDE J C. Investigation of low resistance transparent MoO3/Ag/MoO3 multilayer and application as anode in organic solar cells[J]. Thin Solid Films, 2010, 518(16): 4560-4563.

    9. [9]

      [9] TRIWAHYONO S, JALIL A A, RUSLAN N N, SETIABUDI H D. C5-C7 linear alkane hydroisomerization over MoO3-ZrO2 and Pt/MoO3-ZrO2 catalysts[J]. J Catal, 2013, 303(2): 50-59.

    10. [10]

      [10] 罗金岳, 张晓萍, 安鑫南. MoO3/ZrO2催化α-蒎烯异构化反应的研究[J]. 林产化学与工业, 2004, 24(3): 26-30.(LUO Jin-yue, ZHANG Xiao-ping, AN Xin-nan. Study α-pinene isomerization catalyzed by MoO3/ZrO2solid superacid[J]. Chem Ind Forest Prod, 2004, 24(3): 26-30.)

    11. [11]

      [11] 孙闻东, 许利苹, 刘海燕, 褚莹, 吴越. MoO3/ZrO2纳米固体强酸催化剂的制备及其在异丁烷-丁烯烷基化反应中的应用[J]. 高等学校化学学报, 2004, 25(8): 1499-1503.(SUN Wen-dong, XU Li-ping, LIU Hai-yan, ZHU Ying, WU Yue. Synthesis of strong solid MoO3/ZrO2 and application to the alkylation of isobutene with butane[J]. Chem J Chin Univ, 2004, 25(8): 1499-1503.)

    12. [12]

      [12] 张胜红, 张鸿鹏, 李为臻, 张伟, 黄华, 刘海超. ZrO2晶相对MoO3/ZrO2催化剂结构及其甲醇选择氧化性能的影响[J]. 物理化学学报, 2010, 26(7): 1879-1886.(ZHANG Sheng-hong, ZHANG Hong-peng, LI Wei-zhen, ZHANG Wei, HUA Hua, LIU Hai-chao. Effects of zirconia crystallite phases on the structure of MoO3/ZrO2 catalysts and their properties in the selective oxidation of methanol[J]. Acta Phys Chim Sin, 2010, 26(7): 1879-1886.)

    13. [13]

      [13] LI Z, TIAN Y, HE J, WANG B, MA X. High CO methanation activity on zirconia-supported molybdenum sulfide catalyst[J]. J Energy Chem, 2014, 23(5): 625-632.

    14. [14]

      [14] 宁小飞. 负载型氧化物固体超强酸的制备及催化性能研究[D]. 安徽: 合肥工业大学, 2013.(NING Xiao-fei. Preparation and catalytic properties of supported oxides solid superacid[D]. Anhui: Hefei University of Technology, 2013.)

    15. [15]

      [15] JIN G, LU G, GUO Y, GUO Y, WANG J, KONG W, LIU X. Effect of preparation condition on performance of Ag-MoO3/ZrO2catalyst for direct epoxidation of propylene by molecular oxygen[J]. J Mol Catal A: Chem, 2005, 232(1): 165-172.

    16. [16]

      [16] SAMANTARAY S, MISHRA B G, PRADHAN D K, HOTA G. Solution combustion synthesis and physicochemical characterization of ZrO2-MoO3 nanocomposite oxides prepared using different fuels[J]. Ceram Int, 2011, 37(8): 3101-3108.

    17. [17]

      [17] SAMANTARAY S, HOTA G, MISHRA B G. Physicochemical characterization and catalytic applications of MoO3-ZrO2 composite oxides towards one pot synthesis of amidoalkyl naphthols[J]. Catal Commun, 2011, 12(13): 1255-1259.

    18. [18]

      [18] 刘海燕. 水热法制备复合氧化物固体酸及其在异丁烷-丁烯烷基化反应中的应用[D]. 吉林: 东北师范大学, 2005.(LIU Hai-yan. Hydrothermal synthesis of compound oxides and application in isobutene-butene alkylation[D]. Jilin: Notheast Normal University, 2005.)

    19. [19]

      [19] SARKAR A, PRAMANIK S, ACHARIYA A, PRAMANIK P. A novel sol-gel synthesis of mesoporous ZrO2-MoO3/WO3 mixed oxides[J]. Microporous Mesoporous Mater, 2008, 115(3): 426-431.

    20. [20]

      [20] 赵璧英, 马华容, 唐有祺. 制备方法对MoO3/ZrO2结构的影响及MoO3/ZrO2固体超强酸的结构特征Ⅰ. ZrO2的形态与样品比表面的研究[J]. 催化学报, 1995, 16(3): 171-176.(ZHAO Bi-ying, MA Hua-rong, TANG You-qi. The effect of preparation method on the structure of MoO3/ZrO2 and the structural characteristics of MoO3/ZrO2 solid superacidⅠ. Studies on morphology of the samples[J]. Chin J Catal, 1995, 16(3): 171-176.)

    21. [21]

      [21] LI Z, CHENG B, SU K, GU Y, XI P, GUO M. The synthesis of diphenyl carbonate from dimethyl carbonate and phenol over mesoporous MoO3/SiMCM-41[J]. J Mol Catal A: Chem, 2008, 289(1/2): 100-105.

    22. [22]

      [22] 尹衍升. 氧化锆陶瓷及其复合材料[M]. 北京: 化学工业出版社, 2003: 71-79.(YIN Yan-sheng. Zirconia ceramic and its composite materials[M]. Beijing: Chemical Industry Press, 2003: 71-79.)

    23. [23]

      [23] 刘天成, 宁平, 王亚明, 高红. 固体超强酸MoO3/ZrO2结构的初步表征[J]. 昆明理工大学学报(理工版), 2007, 32(1): 102-104.(LIU Tian-cheng, Ning Ping, WANG Ya-ming, GAO Hong. Study on MoO3/ZrO2 solid superacid[J]. J Kunming Univ Sci Technol (Sci Technol), 2007, 32(1): 102-104.)

    24. [24]

      [24] 柴永明, 安高军, 柳云骐, 刘晨光. 过渡金属硫化物催化剂催化加氢作用机理[J]. 化学进展, 2007, 19(2/3): 234-242.(CHAI Yong-ming, AN Gao-jun, LIU Yun-qi, LIU Chen-guang. Transition metal sulfides hydrogenation catalysts: active phase structure and mechanism of the catalytic reaction[J]. Prog Chem, 2007, 19(2/3): 234-242.)

  • 加载中
    1. [1]

      Zunyuan Xie ,  Lijin Yang ,  Zixiao Wan ,  Xiaoyu Liu ,  Yushan He . Exploration of the Preparation and Characterization of Nano Barium Titanate and Its Application in Inorganic Chemistry Laboratory Teaching. University Chemistry, 2024, 39(4): 62-69. doi: 10.3866/PKU.DXHX202310137

    2. [2]

      Zehao Zhang , Zheng Wang , Haibo Li . Preparation of 2D V2O3@Pourous Carbon Nanosheets Derived from V2CFx MXene for Capacitive Desalination. Acta Physico-Chimica Sinica, 2024, 40(8): 2308020-0. doi: 10.3866/PKU.WHXB202308020

    3. [3]

      Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077

    4. [4]

      Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO2 mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398

    5. [5]

      Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al2O3 for promoting plasma-catalyzed CO2 hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054

    6. [6]

      Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

    7. [7]

      Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO2 hydrogenation over a Mg-doped In2O3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421

    8. [8]

      Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO2-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036

    9. [9]

      Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi2O3 pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256

    10. [10]

      Yan'e LIU , Shengli JIA , Yifan JIANG , Qinghua ZHAO , Yi LI , Xinshu CHANG . MoO3/cellulose derived carbon aerogel: Fabrication and performance as cathode for lithium-sulfur battery. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1565-1573. doi: 10.11862/CJIC.20250054

    11. [11]

      Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO2 Hydrogenation by Decoration of K on MoS2 Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017

    12. [12]

      Yongqing Xu , Yuyao Yang , Mengna Wu , Xiaoxiao Yang , Xuan Bie , Shiyu Zhang , Qinghai Li , Yanguo Zhang , Chenwei Zhang , Robert E. Przekop , Bogna Sztorch , Dariusz Brzakalski , Hui Zhou . Review on Using Molybdenum Carbides for the Thermal Catalysis of CO2 Hydrogenation to Produce High-Value-Added Chemicals and Fuels. Acta Physico-Chimica Sinica, 2024, 40(4): 2304003-0. doi: 10.3866/PKU.WHXB202304003

    13. [13]

      Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO2 Methanation of Derived Ni-Al2O3 Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002

    14. [14]

      Yuting Bai , Cenqi Yan , Zhen Li , Jiaqiang Qin , Pei Cheng . Preparation of High-Strength Polyimide Porous Films with Thermally Closed Pore Property by In Situ Pore Formation Method. Acta Physico-Chimica Sinica, 2024, 40(9): 2306010-0. doi: 10.3866/PKU.WHXB202306010

    15. [15]

      Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 2408004-0. doi: 10.3866/PKU.WHXB202408004

    16. [16]

      Huafeng SHI . Construction of MnCoNi layered double hydroxide@Co-Ni-S amorphous hollow polyhedron composite with excellent electrocatalytic oxygen evolution performance. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1380-1386. doi: 10.11862/CJIC.20240378

    17. [17]

      Qiang Zhou ,  Pingping Zhu ,  Wei Shao ,  Wanqun Hu ,  Xuan Lei ,  Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064

    18. [18]

      Hui Shi ,  Shuangyan Huan ,  Yuzhi Wang . Ideological and Political Design of Potassium Permanganate Oxidation-Reduction Titration Experiment. University Chemistry, 2024, 39(2): 175-180. doi: 10.3866/PKU.DXHX202308042

    19. [19]

      Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369

    20. [20]

      Yuena Yang ,  Xufang Hu ,  Yushan Liu ,  Yaya Kuang ,  Jian Ling ,  Qiue Cao ,  Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(610)
  • HTML views(67)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return