Advanced Search

Citation: LIANG Peng, WANG Xiao-hang, ZHANG Xi-wang, WEI Ai-fang, JIANG Wan-min, ZHANG Rong, BI Ji-cheng. Cracking characteristics of dust-containing tar over modified dolomite catalyst[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(8): 932-939. shu

Cracking characteristics of dust-containing tar over modified dolomite catalyst

  • 1.

    1. College of Chemical Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China;

  • Corresponding author: LIANG Peng, 
  • Received Date: 29 January 2015
    Available Online: 10 April 2015

    Fund Project: 国家自然科学基金(21006059,21376142) (21006059,21376142)煤转化国家重点实验室开放基金(J12-13-202)。 (J12-13-202)

  • A Ni-dolomite catalyst with promoter Lanthanum was prepared by kneading method. The catalyst was used for the cracking reaction of tar model compound containing N-dodecane, cyclohexane, toluene and methylnaphthalene in an atmospheric fixed reactor. The effects of temperature, space velocity and the ratio of water and ingredient on the yield of gas products were examined. The stability test and reaction-regeneration experiments were conducted. Moreover, cracking characteristics of dust-containing tar over the catalyst and dust deposition mechanism were investigated. The results show that the optimum operating condition for the catalyst is reaction temperature 800℃, space velocity 300h-1, the ratio of water to ingredient 5:1. The optimum regeneration condition is 700℃ and 1h. XRD results show that MgO-NiO solid solution and La(NiO3) crystalline phase are converted in the modified dolomite catalyst. Different dust species depositing on the catalyst surface have different influences on the catalytic activity. CaO can improve the catalytic activity. The deposition of Fe2O3 can convert into a new crystalline phase NiFe2O4. SiO2 plays a promoting role in carbon deposition, which can significantly inhibit the catalytic activity.
  • 加载中
    1. [1]

      [1] TORRES W, PANSARE S S, GOODWIN J G. Hot gas removal of tars, ammonia, and hydrogen sulfide from biomass gasification gas[J]. Catal Rev, 2007, 49(4): 407-456.

    2. [2]

      [2] DOU B, ZHANG M, GAO J, SHEN W, SHA X. High temperature removal of NH3, organic sulfur, HCl and tar component from coal derived gas[J]. Ind Eng Chem Res, 2002, 41(17): 4195-4200.

    3. [3]

      [3] YUNG M M, JABLONSKI W S, MAGRINI-BAIR K A. Review of catalytic conditioning of biomass-derived syngas[J]. Energy Fuel, 2009, 23(4): 1874-1887.

    4. [4]

      [4] PINTO F, LOPES H, ANDRE R N, GULYURTLU I, CABRITA I. Effect of catalysts in the quality of syngas and by-products obtained by co-gasification of coal and wastes. 1. Tars and nitrogen compounds abatement[J]. Fuel, 2007, 86(14): 2052-2063.

    5. [5]

      [5] WANG T J, CHANG J, WU C Z, FU Y, CHEN Y. The steam reforming of naphthalene over a nickel-dolomite cracking catalyst[J]. Biomass Bioenergy, 2005, 28(5): 508-514.

    6. [6]

      [6] SUN Y J, JIANG J C, EFTHYMIOS K, XU J M, LI L N, ZHAO S H, YANG W H. Development of a bimetallic dolomite based tar cracking catalyst[J]. Catal Commun, 2012, 20: 36-40.

    7. [7]

      [7] JUMLUCK S, KAZUHIRO S, THARAPONG V, KAORU F. A highly efficient catalyst for tar gasification with steam[J]. Catal Commun, 2005, 6(6): 437-440.

    8. [8]

      [8] 蒋述兴. 白云石煅烧离解过程的工艺特性研究[J]. 非金属矿, 2011, 34(3): 22-25. (JIANG Shu-xing. Study on technological characteristic of process of calcining and decomposing dolomite ore[J]. Non-Met Mines, 2011, 34(3): 22-25.)

    9. [9]

      [9] 刘芬, 赵志娟, 邱丽美, 赵良仲. PS光电子峰和俄歇电子峰峰位表[J]. 分析测试技术与仪器, 2009, 15(1): 1-17. (LIU Fen, ZHAO Zhi-juan, QIU Li-mei, ZHAO Liang-zhong. Tables of peak positions for XPS photoelectron and auger electron peaks[J]. Anal Test Technol Inst, 2009, 15(1): 1-17.)

    10. [10]

      [10] 黎先财, 陈娟荣, 赖志华, 魏元珍, 何琲.不同载体对镍基催化剂的XPS影响[J]. 稀土, 2006, 27(1): 8-10. (LI Xian-cai, CHEN Juan-rong, LAI Zhi-hua, WEI Yuan-zhen, HE Fei. XPS effect of different supports on Ni-based catalyst[J]. Chin Rare Earths, 2006, 27(1): 8-10.)

    11. [11]

      [11] 岳宝华, 孔令华, 汪学广, 鲁雄刚, 丁伟忠. Ni/MgAl(O)催化剂上高温焦炉煤气中焦油组分的催化转化[J]. 催化学报, 2010, 31(2): 218-224. (YUE Bao-hua, KONG Ling-hua, WANG Xue-guang, LU Xiong-gang, DING Wei-zhong. Catalytic conversion of tar components from hot coke oven gas over Ni/MgAl(O) catalyst[J]. Chin J Catal, 2010, 31(2): 218-224.)

    12. [12]

      [12] 于飞, 岳宝华, 汪学广, 耿淑华, 鲁雄刚, 丁伟忠. Ni/Ce-ZrO2/γ-Al2O3催化剂上高温焦炉煤气中焦油组分的常压加氢裂解[J]. 催化学报, 2009, 30(7): 690-696. (YU Fei, YUE Bao-hua, WANG Xue-guang, GENG Shu-hua, LU Xiong-gang, DING Wei-zhong. Hydrocracking of tar components from hot coke oven gas over a Ni/Ce-ZrO2/γ-Al2O3 catalyst at atmospheric pressure[J]. Chin J Catal, 2009, 30(7): 690-696.)

    13. [13]

      [13] 米铁, 吴正舜, 余新明, 吴学军. CaO催化裂解生物质气化焦油实验研究[J]. 太阳能学报, 2011, 32(5): 724-729. (MI Tie, WU Zheng-shun, YU Xin-ming, WU Xue-jun. The experimental study on biomass tar-cracking by CaO catalyst[J]. Acta Energy Sol Sin, 2011, 32(5): 724-729.)

  • 加载中
    1. [1]

      Hengyi ZHU , Liyun JU , Haoyue ZHANG , Jiaxin DU , Yutong XIE , Li SONG , Yachao JIN , Mingdao ZHANG . Efficient regeneration of waste LiNi0.5Co0.2Mn0.3O2 cathode toward high-performance Li-ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 625-638. doi: 10.11862/CJIC.20240358

    2. [2]

      Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202

    3. [3]

      Fangxuan Liu ,  Ziyan Liu ,  Guowei Zhou ,  Tingting Gao ,  Wenyu Liu ,  Bin Sun . Hollow structured photocatalysts. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-. doi: 10.1016/j.actphy.2025.100071

    4. [4]

      Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO2 hydrogenation over a Mg-doped In2O3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421

    5. [5]

      Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

    6. [6]

      Xuejie Wang ,  Guoqing Cui ,  Congkai Wang ,  Yang Yang ,  Guiyuan Jiang ,  Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044

    7. [7]

      Juntao Yan ,  Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024

    8. [8]

      Yuanyin Cui ,  Jinfeng Zhang ,  Hailiang Chu ,  Lixian Sun ,  Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016

    9. [9]

      Dan Li ,  Hui Xin ,  Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046

    10. [10]

      Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048

    11. [11]

      Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH2 supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317

    12. [12]

      Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H2 production activity of BaTiO3 nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102

    13. [13]

      Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165

    14. [14]

      Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO2 methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276

    15. [15]

      Asif Hassan Raza ,  Shumail Farhan ,  Zhixian Yu ,  Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020

    16. [16]

      Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028

    17. [17]

      Zhiquan Zhang ,  Baker Rhimi ,  Zheyang Liu ,  Min Zhou ,  Guowei Deng ,  Wei Wei ,  Liang Mao ,  Huaming Li ,  Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO2 Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029

    18. [18]

      Shuang Yang ,  Qun Wang ,  Caiqin Miao ,  Ziqi Geng ,  Xinran Li ,  Yang Li ,  Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044

    19. [19]

      Yulian Hu ,  Xin Zhou ,  Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO2 Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088

    20. [20]

      Xue Liu ,  Lipeng Wang ,  Luling Li ,  Kai Wang ,  Wenju Liu ,  Biao Hu ,  Daofan Cao ,  Fenghao Jiang ,  Junguo Li ,  Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(431)
  • HTML views(11)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return