Citation: TU Jun-ling, XU Yong-jun, DING Ming-yue, WANG Tie-jun, MA Long-long, WANG Min-long. Preparation of nano-structured Fe₃O₄ catalysts and their performance in Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(7): 839-845. shu

Preparation of nano-structured Fe₃O₄ catalysts and their performance in Fischer-Tropsch synthesis

1.
1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;

Corresponding author: DING Ming-yue,
Received Date: 4 May 2015
Available Online: 27 June 2015
Fund Project: 国家自然科学基金(U1362109, 51206172) (U1362109, 51206172) 国家重点基础研究发展规划(973 计划, 2013CB228105) (973 计划, 2013CB228105) 广东省科技计划项目(2013B010405012) (2013B010405012) 中国科学院战略性先导科技专项课题(XDA05010108)。 (XDA05010108)

Two shape-defined nano-structured Fe₃O₄ catalysts such as Nano-Microsphere (FNM) and Nano-Flake (FNF) were prepared by a simple solvothermal method. The effects of precursor type on Fe₃O₄ crystal morphology was studied. It is found that the rate of nucleation and crystal growth have a crucial influence on the particle morphology. Compared to the traditional Fe catalyst, the shape-defined nano Fe₃O₄ catalysts could be easily reduced and transferred into active phases, resulting in higher Fischer-Tropsch synthesis (F-T) activity and C₅₊ selectivity. Especially, the FNM catalyst displayed higher catalytic activity and stability than the FNF catalyst. It was found that the FNF catalyst was more favorable to agglomeration because of shape change of the flakes. In addition, the results indicate that the hydrocarbon selectivity is strongly affected by the particle morphology.
- Fe₃O₄ nanocatalyst,
- morphology-defined nanoparticle,
- Fischer-Tropsch synthesis
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of nano-structured Fe3O4 catalysts and their performance in Fischer-Tropsch synthesis

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通讯作者: 陈斌, bchen63@163.com

Preparation of nano-structured Fe₃O₄ catalysts and their performance in Fischer-Tropsch synthesis