Citation: LI Lan-lan, ZHENG An-qing, FENG Yi-peng, MENG Jun-guang, ZHAO Zeng-li, LI Hai-bin. Effects of olivine on catalytic reforming of toluene[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(7): 806-815. shu

Effects of olivine on catalytic reforming of toluene

1.
1. The Key Laboratory of Renewable Energy of Chinese Academy of Sciences, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;

Corresponding author: ZHAO Zeng-li,
Received Date: 20 January 2015
Available Online: 19 March 2015
Fund Project: 国家自然科学基金(51376186, 21406227) (51376186, 21406227) 广东省科技计划项目(2012B050500007)。 (2012B050500007)

With toluene as the model compound of tar from biomass gasification, the catalytic properties of olivine and nickel catalysts supported on the olivine were analyzed for its performance on the reactions of toluene cracking and toluene/steam reforming in a fixed bed reactor. The catalysts were characterized by SEM, BET, XRD, and H₂-TPR. The results show that calcination changes the physical and chemical characteristics of the raw ore. The olivine catalysts show a catalytic activity on the reactions of catalytic cracking and steam reforming of toluene. However, with the addition of Ni the catalytic activity for toluene cracking reaction decreases, the toluene conversion rate reduces by 2.2%~9.8%; while the catalytic activity for toluene/steam reforming reaction rise obviously, the toluene conversion rate reaches up to 97.0%, and nickel catalyst supported on olivine shows great stability in steam reforming of toluene.
- olivine,
- nickel catalyst,
- toluene,
- catalytic reforming
1. [1]
  [1] 龚媛媛, 石金明, 林敏, 王歆. 生物质焦油的特性及其净化研究现状[J]. 能源研究与管理, 2013, (4): 19-24. (GONG Yuan-yuan, SHI Jin-ming, LIN Min, WANG Xin. Characteristics of biomass tar and research status on its purification[J]. Energy Res Manage, 2013, (4): 19-24.)
2. [2]
  [2] SUN Y J, JIANG J C, KANTARELIS E, XU J M, LI L N, ZHAO S H, YANG W H. Development of a bimetallic dolomite based tar cracking catalyst[J]. Catal Commun, 2012, 20: 36-40.
3. [3]
  [3] FURUSAWA T, SAITO K, KORI Y, MIURA Y, SATO M, SUZUKI N. Steam reforming of naphthalene/benzene with various types of Pt- based and Ni-based catalysts for hydrogen production[J]. Fuel, 2013, 103: 111-121.
4. [4]
  [4] CORELLA J, TOLEDO J M, PADILLA R. Olivine or dolomite as in-bed additive in biomass gasification with air in a fluidized bed: Which is better[J]? Energy Fuels, 2004, 18(3): 713-720.
5. [5]
  [5] DEVI L, CRAJE M, THVNE P, PTASINSKI K J, JANSSEN F J J G. Olivine as tar removal catalyst for biomass gasifiers: Catalyst characterization[J]. Appl Catal A: Gen, 2005, 294(1): 68-79.
6. [6]
  [6] DEVI L, PTASINSKI K J, JANSSEN F J J G, PAASEN S V B, BERGMAN P C A, KIEL J H A. Catalytic decomposition of biomass tars: Use of dolomite and untreated olivine[J]. Renew Energy, 2005, 30(4): 565-587.
7. [7]
  [7] CHRISTODOULOU C, GRIMEKIS D, PANOPOULOS K D, PACHATOURIDOU E P, ILIOPOULOU E F, KAKARAS E. Comparing calcined and un-treated olivine as bed materials for tar reduction in fluidized bed gasification[J]. Fuel Process Technol, 2014, 124: 275-285.
8. [8]
  [8] VIRGINIE M, COURSON C, NIZNANSKY D, CHAOUI N, KIENNEMANN A. Characterization and reactivity in toluene reforming of a Fe/olivine catalyst designed for gas cleanup in biomass gasification[J]. Appl Catal B: Environ, 2010, 101(1/2): 90-100.
9. [9]
  [9] RAPAGNÀ S, VIRGINIE M, GALLUCCI K, COURSON C, MARCELLO M D, KIENNEMANN A, FOSCOLO P U. Fe/olivine catalyst for biomass steam gasification: Preparation, characterization and testing at real process conditions[J]. Catal Today, 2011, 176(1): 163-168.
10. [10]
  [10] MICHEL R, ŁAMACZ A, KRZTON A, MARIADASSOU G D, BURG P, COURSON C, GRUBE R. Steam reforming of α-methylnaphthalene as a model tar compound over olivine and olivine supported nickel[J]. Fuel, 2013, 109: 653-660.
11. [11]
  [11] 杨小芹, 徐绍平, 胡冠, 刘长厚. 不同矿源橄榄石对催化苯水蒸气重整的影响[J]. 催化学报, 2009, 30(6): 497-502. (YANG Xiao-qin, XU Shao-ping, HU Guan, LIU Chang-hou. Effects of olivines from different quarries on the steam reforming of benzene[J]. Chin J Catal, 2009, 30(6): 497-502.)
12. [12]
  [12] 魏立纲, 徐绍平, 刘长厚, 刘淑芹. 预煅烧对橄榄石生物质气化催化性能的影响[J]. 燃料化学学报, 2008, 36(4): 426-430. (WEI Li-gang, XU Shao-ping, LIU Chang-hou, LIU Shu-qin. Effects of precalcination on catalytic activity of olivine in biomass gasification[J]. J Fuel Chem Technol, 2008, 36(4): 426-430.)
13. [13]
  [13] KUHN J N, ZHAO Z K, Larry G, FELIX L G, SLIMANE R B, CHOI C W, OZKAN U S. Olivine catalysts for methane- and tar-steam reforming[J]. Appl Catal B: Environ, 2008, 81(1/2): 14-26.
14. [14]
  [14] CHEN T H, LIU H B, SHI P C, CHEN D, SONG L, HE H P, FROST R L. CO₂ reforming of toluene as model compound of biomass tar on Ni/palygorskite[J]. Fuel, 2013, 107: 699-705.
15. [15]
  [15] VIRGINIE M, COURSON C, KIENNEMANN A. Toluene steam reforming as tar model molecule produced during biomass gasification with an iron/olivine catalyst[J]. C R Chim, 2010, 13(10): 1319-1325.
16. [16]
  [16] ŜWIERCZYÑSKI D, LIBS S, COURSON C, KIENNEMANN A. Steam reforming of tar from a biomass gasification process over Ni/olivine catalyst using toluene as a model compound[J]. Appl Catal B: Environ, 2007, 74(3/4): 211-222.
17. [17]
  [17] NITSCH X, COMMANDRÉ J M, CLAVEL P, MARTIN E, VALETTE J, VOLLE G. Conversion of phenol-based tars over olivine and sand in a biomass gasification atmosphere[J]. Energy Fuels, 2013, 27(9): 5459-5465.
18. [18]
  [18] SWIERCZYNSKI D, COURSON C, KIENNEMANN A. Study of steam reforming of toluene used as model compound of tar produced by biomass gasification[J]. Chem Eng Process, 2008, 47(3): 508-513.
1. [1]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
2. [2]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
3. [3]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
4. [4]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
5. [5]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
6. [6]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . Hollow structured photocatalysts. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-. doi: 10.1016/j.actphy.2025.100071
7. [7]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
8. [8]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
9. [9]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
10. [10]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
11. [11]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
12. [12]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
13. [13]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
14. [14]
  Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048
15. [15]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
16. [16]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
17. [17]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
18. [18]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
19. [19]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
20. [20]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(386)
HTML views(24)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142