Citation: HUANG Fan, ZHU Xing, WEI Yong-gang, ZHENG Min, WANG Hua, LI Kong-zhai. Preparation of cerium-cobalt composite oxygen carrier and its performance in methane chemical looping combustion[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(6): 761-768. shu

Preparation of cerium-cobalt composite oxygen carrier and its performance in methane chemical looping combustion

HUANG Fan ^1,2 ,
ZHU Xing ^1,3,, ,
WEI Yong-gang ^1,3 ,
ZHENG Min ^1,3 ,
WANG Hua ^1,3 ,
LI Kong-zhai ^1,3,,

1.
1. State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming 650093, China;

Corresponding author: ZHU Xing, LI Kong-zhai,
Received Date: 26 November 2014
Available Online: 13 February 2015
Fund Project: 国家自然科学基金(51174105,51306084) (51174105,51306084)云南省中青年学术技术带头人后备人(2014HB006)。 (2014HB006)

A series of CeO₂/Co₃O₄ composite oxygen carriers with different CeO₂ loadings were prepared and characterized by XRD and H₂-TPR. The performance of CeO₂/Co₃O₄ as an oxygen carrier in methane chemical looping combustion was investigated in a fixed-bed reactor by temperature-programmed and isothermal reactions; the effect of CeO₂ loading on the structure, activity and selectivity of the oxygen carrier was considered in detail. The results show that the addition of CeO₂ can reduce the reaction temperature and increase the effective reaction time of the CeO₂/Co₃O₄ oxygen carriers for methane oxidation. However, loading of excessive CeO₂ may promote the partial oxidation of methane forming CO and H₂ and leads to a decrease in the selectivity to CO₂. The CeO₂/Co₃O₄ composite oxygen carrier with a CeO₂ loading of 30% (mol ratio) exhibits the highest activity and redox stability in the chemical looping combustion of methane; over it, methane can be quickly converted to CO₂ and H₂O with high selectivity (over 90%) at 650 ℃ and the reduced oxygen carrier can be fully recovered in O₂ atmosphere. Moreover, no obvious decline in the conversion of methane and selectivity to CO₂ is observed in the successive CH₄-reduction and O₂-oxidation redox process for over 20 cycles.
- chemical looping combustion,
- CeO₂/Co₃O₄ composite oxygen carrier,
- methane,
- redox ability
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