Citation: LIU Li-hua, LIU Shu-qun, YIN Hai-liang, LIU Yun-qi, LIU Chen-guang. Hydrogen spillover effect between Ni₂P and MoS₂ catalysts in hydrodesulfurization of dibenzothiophene[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(6): 708-713. shu

Hydrogen spillover effect between Ni₂P and MoS₂ catalysts in hydrodesulfurization of dibenzothiophene

1.
1. School of Chemistry and Materials Science, Huaibei Normal University, Huaibei 235000, China;

Received Date: 20 March 2015
Available Online: 4 May 2015
Fund Project: Supported by the National Natural Science Foundation of China (21206197) (21206197) the Natural Science Foundation of Anhui Province (1408085QB44) (1408085QB44) the Science-Technology Foundation for Fostering Talents of Huaibei City (20140316) (20140316) the Youth Foundation of Huaibei Normal University (2013xqz01) (2013xqz01)and Promotive Research Fund for Excellent Young and Middle-aged Scientists of Shandong Province (BS2013CL021). (BS2013CL021)

The hydrodesulfurization of dibenzothiophene over physically separated Ni₂P//MoS₂ catalyst beds was investigated.The results indicated that the hydrogen spillover effect appears between the Ni₂P/Al₂O₃ and MoS₂/Al₂O₃ catalysts in the hydrodesulfurization reaction, which can significantly enhance the concentration of active sites and the hydrodesulfurization rate over the MoS₂ catalyst. The spillover factor on Ni₂P//MoS₂is slightly higher than that on NiS_x//MoS₂, due to the higher hydrogen dissociation activity of Ni₂P; as a result, Ni₂P is a superior promoter to NiS_x for the MoS₂ catalyst.
- Ni₂P,
- MoS₂,
- hydrodesulfurization,
- hydrogen spillover effect,
- dibenzothiophene
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沈阳化工大学材料科学与工程学院沈阳 110142

Hydrogen spillover effect between Ni2P and MoS2 catalysts in hydrodesulfurization of dibenzothiophene

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通讯作者: 陈斌, bchen63@163.com

Hydrogen spillover effect between Ni₂P and MoS₂ catalysts in hydrodesulfurization of dibenzothiophene