Citation: LÜ Yan-an, ZHAO Xing-ling, SUO Zhang-huai, LIAO Wei-ping, JIN Ming-shan. Low-temperature steam reforming of glycerol for hydrogen production over supported nickel catalysts[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(6): 684-691. shu

Low-temperature steam reforming of glycerol for hydrogen production over supported nickel catalysts

1.
Institute of Applied Catalysis, Yantai University, Yantai 264005, China

Corresponding author: SUO Zhang-huai,
Received Date: 19 December 2014
Available Online: 21 March 2015
Fund Project: 国家自然科学基金(21273193) (21273193)山东省自然科学基金(ZR2011BM024)。 (ZR2011BM024)

Al₂O₃, CeO₂, TiO₂ and MgO supported Ni catalysts were prepared by incipient impregnation. The activities in glycerol steam reforming to hydrogen production were evaluated at 300~500 ℃. The catalysts were characterized by XRD, N₂ adsorption, TEM, and H₂-TPR techniques. A strong effect of support on the activity of Ni catalyst was detected. Ni/CeO₂ catalyst gives the highest activity among all catalysts at 400 ℃and the following activity order is shown Ni/CeO₂> Ni/Al₂O₃> Ni/TiO₂ ~ Ni/MgO. On Ni/CeO₂, there was almost no deactivation detected after 20 h reaction with 70% conversion of glycerol and 69.2% H₂ yield. Good activity and stability of the catalyst is attributed to the intrinsic property of CeO₂ and strong interaction between CeO₂ and active nickel species. Relatively high glycerol conversion (85.7%) with low H₂ selectivity on Ni/Al₂O₃catalyst at 500 ℃ is achieved due to its high surface area and large pore volume. The formation of solid solution NiMgO₂phase observed in Ni/MgO catalyst does not show the desired activity at low temperatures though it enhanced the interactions between active phase and the support. Base oxide supports (CeO₂, MgO) seem to be more effective than acid oxide supports in preventing the formation of CO and CH₄ as by-products.
- glycerol,
- steam reforming,
- hydrogen production,
- supported nickel catalyst
1. [1]
  [1] 袁冰, 刘天, 于世涛. 基于杂多类离子液体催化体系的甘油氢解反应研究[J]. 燃料化学学报, 2014, 42(10): 1218-1224. (YUAN Bing, LIU Tian, YU Shi-tao. Hydrogenolysis of glycerol over a catalytic system based on heteropoly ionic liquid[J]. J Fuel Chem Technol, 2014, 42(10): 1218-1224.)
2. [2]
  [2] 郝顺利, 彭伟才, 赵宁, 肖福魁, 魏伟, 孙予罕, 李海. 不同载体负载Cu催化剂上甘油氢解制1,2-丙二醇催化性能的研究[J]. 燃料化学学报, 2012, 40(5): 594-600. (HAO Shun-li, PENG Wei-cai, ZHAO Ning, XIAO Fu-kui, WEI Wei, SUN Yu-han, LI Hai. Hydrogenolysis of glycerol to 1,2-propanediol over various supported Cu catalysts[J]. J Fuel Chem Technol, 2012, 40(5): 594-600.)
3. [3]
  [3] DOU B, SONG Y, WANG C, CHEN H, XU Y. Hydrogen production from catalytic steam reforming of biodiesel byproduct glycerol: Issues and challenges[J]. Renewable Sustainable Energy Rev, 2014, 30: 950-960
4. [4]
  [4] SILVA J M, SORIA M A, MADEIRA LUIS M. Challenges and strategies for optimization of glycerol steam reforming process[J]. Renewable Sustainable Energy Rev, 2015, 42: 1187-1213
5. [5]
  [5] 刘琦, 张鹏博, 王星会, 陈崇启,林性贻,郑起,詹瑛瑛. 甘油水蒸气重整制氢催化剂研究进展[J]. 分子催化, 2012, 26(1): 89-97. (LIU Qi, ZHANG Peng-bo, WANG Xing-hui, CHEN Chong-Qi, LIN Xing-yi, ZHENG Qi, ZHAN Ying-ying. Progress on glycerol steam reforming for hydrogen production[J]. J Mol Catal (China), 2012, 26(1): 89-97.)
6. [6]
  [6] POMPEO F, SANTORI G F, NICHIO N N. Hydrogen production by glycerol steam reforming with Pt/SiO₂ and Ni/SiO₂ catalysts[J]. Catal Today, 2011, 172(1): 183-188.
7. [7]
  [7] ZHANG B, TANG X, LI Y, XU Y, SHEN W. Hydrogen production from steam reforming of ethanol and glycerol over ceria-supported metal catalysts[J]. Int J Hydrogen Energy, 2007, 32(13): 2367-2373.
8. [8]
  [8] CHIODO V, FRENI S, GALVAGNO A, MONDELLO N, FRUSTERI F. Catalytic features of Rh and Ni supported catalysts in the steam reforming of glycerol to produce hydrogen[J]. Appl Catal A: Gen, 2010, 381(1/2): 1-7.
9. [9]
  [9] MENEZES A O, RODRIGUES M T, ZIMMARO A, BORGES L E P, FRAGA M A. Production of renewable hydrogen from aqueous-phase reforming of glycerol over Pt catalysts supported on different oxides[J]. Renewable Energy, 2011, 36(2): 595-599.
10. [10]
  [10] NICHELE V, SIGNORETTO M, MENEGAZZO F, GALLO A, SANTO V D, CRUCIANI G, CERRATO G. Glycerol steam reforming for hydrogen production: Design of Ni supported catalysts[J]. Appl Catal B: Environ, 2012, 111-112: 225-232.
11. [11]
  [11] SÁNCHEZ E A, D'ANGELO M A, COMELLI R A. Hydrogen production from glycerol on Ni/Al₂O₃ catalyst[J]. Int J Hydrogen Energy, 2010, 35(11): 5902-5907.
12. [12]
  [12] CHENG C K, FOO S Y, ADESINA A A. Steam reforming of glycerol over Ni/Al₂O₃ catalyst[J]. Catal Today, 2011, 178(1): 25-33.
13. [13]
  [13] WANG C, DOU B, CHEN H, SONG Y, XU Y, DU X, LUO T, TAN C. Hydrogen production from steam reforming of glycerol by Ni-Mg-Al based catalysts in a fixed-bed reactor[J]. Chem Eng J, 2013, 220: 133-142.
14. [14]
  [14] BUFFONI I N, POMPEO F, SANTORI G F, NICHIO N N. Nickel catalysts applied in steam reforming of glycerol for hydrogen production[J]. Catal Commun, 2009, 10(13): 1656-1660.
15. [15]
  [15] IRIONDO A, BARRIO V L, CAMBRA J F, ARIAS P L, GUEMEZ M B, SANCHEZ-SANCHEZ M C, NAVARRO R M, FIERRO J L G. Glycerol steam reforming over Ni catalysts supported on ceria and ceria-promoted alumina[J]. Int J Hydrogen Energy, 2010, 35(20): 11622-11633.
16. [16]
  [16] ADHIKARI S, FERNANDO S D, HARYANTO A. Hydrogen production from glycerin by steam reforming over nickel catalysts[J]. Renew Energy, 2008, 33(5): 1097-1100.
17. [17]
  [17] SHAO S, SHI A W, LIU C L, YANG R Z, DONG W S. Hydrogen production from steam reforming of glycerol over Ni/CeZrO catalysts[J]. Fuel Proc Technol, 2014, 125: 1-7.
18. [18]
  [18] DAVE C D, PANT K K. Renewable hydrogen generation by steam reforming of glycerol over zirconia promoted ceria supported catalyst[J]. Renewable Energy, 2011, 36(11): 3195-3202.
19. [19]
  [19] CHEN H, DING Y, CONG N T, DOU B, DUPONT V, GHADIRI M, WILLIAMS P T. A comparative study on hydrogen production from steam-glycerol reforming: Thermodynamics and experimental[J]. Renewable Energy, 2011, 36(2): 779-788.
20. [20]
  [20] ADHIKARI S, FERNANDO S, GWALTNEY S R, TO S D F, BRICKA R M, STEELE P H, HARYANTO A. A thermodynamic analysis of hydrogen production by steam reforming of glycerol[J]. Int J Hydrogen Energy, 2007, 32(14): 2875-2880.
21. [21]
  [21] CAMPBELL C T, PEDEN C H F. Oxygen vacancies and catalysis on ceria surfaces[J]. Science, 2005, 309(5735): 713-714.
22. [22]
  [22] POMPEOF, SANTORIG, NICHION N. Hydrogen and/or syngas from steam reforming of glycerol. Study of platinum catalysts[J]. Int J Hydrogen Energy, 2010, 35(17): 8912-8920.
23. [23]
  [23] IRIONDO A, BARRIO V L, CAMBRA J F, ARIAS P L, GÜEMEZ M B, NAVARRO R M, SÁNCHEZ-SÁNCHEZ M C, FIERRO J L G. Hydrogen production from glycerol over nickel catalysts supported on Al₂O₃ modified by Mg, Zr, Ce or La[J]. Top Catal, 2008, 49(1/2): 46-58.
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