Citation: LUO Jing, LI Hong-guang, ZHAO Ning, WANG Feng, XIAO Fu-kui. Selective oxidation of glycerol to dihydroxyacetone over layer double hydroxide intercalated with sulfonato-salen metal complexes[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(6): 677-683. shu

Selective oxidation of glycerol to dihydroxyacetone over layer double hydroxide intercalated with sulfonato-salen metal complexes

LUO Jing ^1,2 ,
LI Hong-guang ^1,2 ,
ZHAO Ning ^1,, ,
WANG Feng ^1,, ,
XIAO Fu-kui ¹

1.
1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: ZHAO Ning, WANG Feng,
Received Date: 26 January 2015
Available Online: 10 March 2015
Fund Project: 国家自然科学基金(51206188) (51206188)山东省优秀中青年科学家科研奖励基金(BS2013SW032) (BS2013SW032)长江学者和创新团队发展计划资助(IRT1294)。 (IRT1294)

A series of sulfonato-salen metal complexes were intercalated into Mg-Al layer double hydroxide (LDH) and used for selective oxidation of glycerol to dihydroxyacetone (DHA). The X-ray diffraction, Fourier transform infrared spectroscopy and elemental analysis results of the as-prepared catalysts demonstrated that the metal ions were combined with sulfonato-salen ligands to form metal complexes that intercalated in the LDH. The Cr(III) and Cu(II) sulfonato-salen complex-intercalated LDH catalysts were favorable for activation of H₂O₂, promoting the oxidation of glycerol to DHA. It was found that the Cu(II) sulfonato-salen-intercalated LDH catalyst was also beneficial for the dehydrogenation of glycerol, resulting in a high selectivity to DHA. The glycerol conversion and DHA selectivity obtained over the Cu(II) sulfonato-salen-intercalated LDH catalyst reached 40.3% and 52.9% respectively under the optimum reaction conditions of 60 ℃, 4 h and pH value 7.
- glycerol,
- dihydroxyacetone,
- sulfonato-salen metal complexes,
- heterogeneous catalyst,
- selective oxidation
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