Citation: WANG Xiao-jing, LIU Chao, DONG Yue, LI Fa-tang, ZHAO Jun, LI Yu-pei. Modification of activated carbon with tetrafluoroboric acid and its performance in adsorption desulfurization of dibenzothiophene[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(5): 607-613. shu

Modification of activated carbon with tetrafluoroboric acid and its performance in adsorption desulfurization of dibenzothiophene

WANG Xiao-jing ¹ ,
LIU Chao ² ,
DONG Yue ¹ ,
LI Fa-tang ^1,, ,
ZHAO Jun ¹ ,
LI Yu-pei ¹

1.
1. College of Science, Hebei University of Science and Technology, Shijiazhuang 050018, China;

Corresponding author: LI Fa-tang,
Received Date: 29 October 2014

Fund Project: 国家自然科学基金(21406054, 21376061) (21406054, 21376061) 教育部新世纪优秀人才支持计划(NCET-12-0686) (NCET-12-0686) 河北省自然科学基金(B2015208005, B2015208010)。 (B2015208005, B2015208010)

The activated carbon adsorbent was modified with tetrafluoroboric acid (HBF₄) by impregnation and characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and N₂ physisorption. The performance of modified activated carbon in adsorption desulfurization of dibenzothiophene (DBT) in model diesel fuel was investigated and the influences of HBF₄ concentration, calcination temperature and the initial DBT concentration on the sulfur removal efficiency were considered. The results show that the adsorbent modified with 0.5% HBF₄ solution and calcined at 140 ℃ performs best in DBT desulfurization; when the adsorbent/oil ratio is 1:100, the HBF₄-modified adsorbent exhibits an adsorption capacity of 352 mg/g, which is 72.5% higher than that of the unmodified activated carbon.
- adsorptive desulfurization,
- modified activated carbon,
- tetrafluoroboric acid,
- dibenzothiophene
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