Citation: ZHAO Xing-ling, LÜ Yan-an, LIAO Wei-ping, JIN Ming-shan, SUO Zhang-huai. Hydrogen production from steam reforming of ethylene glycol over supported nickel catalysts[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(5): 581-588. shu

Hydrogen production from steam reforming of ethylene glycol over supported nickel catalysts

1.
Institute of Applied Catalysis, Yantai University, Yantai 264005, China

Corresponding author: SUO Zhang-huai,
Received Date: 22 January 2015

Fund Project: 国家自然科学基金(21273193) (21273193) 山东省自然科学基金(ZR2011BM024)。 (ZR2011BM024)

A series of nickel catalysts were prepared by the impregnation and co-precipitation methods and characterized by X-ray diffraction, nitrogen physisorption, and H₂ temperature-programmed reduction. The effects of nickel loading, calcination temperature, reaction temperature, support modification and cobalt oxide addition on the catalytic activity and selectivity to H₂ in the steam reforming of ethylene glycol were investigated. The results indicate that the nickel catalyst prepared by co-precipitation has smaller particle size and relatively higher activity in comparison with the catalyst prepared by impregnation. Adding a small amount of cobalt oxide to the Ni/CeO₂ catalysts can enhance the catalytic activity; over the Ni-Co bimetallic catalyst, the yield of hydrogen reaches 72.6%. Modifying CeO₂ with Al₂O₃, TiO₂ and ZrO₂ also has a certain influence on the catalytic activity and the Ni/CeO₂-Al₂O₃ catalyst exhibits the highest activity, with an ethylene glycol conversion of 94% to gaseous products and a hydrogen yield of 67.0%. However, Ni/CeO₂-SiO₂ shows a very low activity in spite of its large surface area and pore volume.
- ethylene glycol,
- steam reforming,
- supported nickel catalyst,
- hydrogen production
1. [1]
  [1] 蒋剑春. 生物质热化学转化制液体燃料的研究进展[J]. 生物质化学工程, 2007, 41(5): 45-51.(JIANG Jian-chun. Research progress on thermo-chemical conversion of biomass into liquid fuels in China[J]. Biomass Chem Eng, 2007, 41(5): 45-51.)
2. [2]
  [2] 蒋剑春. 生物质能源应用研究现状与发展前景[J]. 林产化学与工业, 2002, 22(2): 75-80.(JIANG Jian-chun. Research progress and development prospect of biomass energy[J]. Chem Ind For Prod, 2002, 22(2): 75-80.)
3. [3]
  [3] 郑志锋, 蒋剑春, 戴伟娣, 孙云娟. 生物质能源转化技术与应用[J]. 生物质化学工程, 2007, 41(5): 67-77.(ZHENG Zhi-feng, JIANG Jian-chun, DAI Wei-di, SUN Yun-juan. Conversion technology and utilization of biomass energy[J]. Biomass Chem Eng, 2007, 41(5): 67-77.)
4. [4]
  [4] 李海滨, 袁振宏, 马骁茜. 现代生物质能利用技术[M] . 北京: 化学工业出版社, 2012, 330-331.(LI Hai-bing, YUAN Zhen-hong, MA Xiao-qian. Utilization technology of modern biomass energy[M]. Beijing: Chemical Industry Press, 2012, 330-331.)
5. [5]
  [5] 龙向东, 李泽龙, 高广, 夏春谷, 李福伟. 乙酰丙酸催化加氢制备γ -戊内酯的研究进展[J]. 分子催化, 2014, 28(4): 384-392.(LONG Xiang-dong, LI Ze-long, GAO Guang, XIA Chun-gu, LI Fu-wei. Research progress of hydrogenation of levulinic acid into γ-valerolactone[J]. J Mol Catal, 2014, 28(4): 384-392.)
6. [6]
  [6] ZHAO Y, FU Y, GUO Q X. Production of aromatic hydrocarbons through catalytic pyrolysis of γ-valerolactone from biomass[J]. Bioresour Technol, 2012, 114: 740-744.
7. [7]
  [7] 张建伟, 樊金龙, 吴卫泽. 乙酰丙酸加氢生成γ-戊内酯的反应动力学[J]. 北京化工大学学报(自然科学版), 2010, 37(5): 25-29.(ZHANG Jian-wei, FAN Jin-long, WU Wei-ze. The reaction kinetic of hydrogenation of levulinic acid into γ-valerolactone[J]. J Beijing Univ Chem Technol (Nat Sci), 2010, 37(5): 25-29.)
8. [8]
  [8] WILLIAM R H, PALKOVITS R. Development of heterogeneous catalysts for the conversion of levulinic acid to γ-valerolactone[J]. ChemSusChem, 2012, 5(9): 1567-1577.
9. [9]
  [9] BOND J Q, ALONSO D M, WANG D, WEST R M, DUMESIC J A. Integrated catalytic conversion of γ-valerolactone to liquid alkenes for transportation fuels[J]. Science, 2010, 327(5969): 1110-1114.
10. [10]
  [10] CHENG Y T, JAE J, SHI J, FAN W, HUBER G W. Production of renewable aromatic compounds by catalytic fast pyrolysis of lignocellulosic biomass with bifunctional Ga/ZSM-5 catalysts[J]. Angew Chem Int Ed, 2012, 51(6): 1387-1390.
11. [11]
  [11] SAMI M T, BRAHIM M, PIETER C M, MAGUSIN M, PIDKO E A, HENSEN E J M. Structure and reactivity of Zn-modified ZSM-5 zeolites: The importance of clustered cationic Zn complexes[J]. ACS Catal, 2012, 2(1): 71-83.
12. [12]
  [12] YU L, HUANG S, ZHANG S, LIU Z, XIN W, XIE S, XU L. Transformation of isobutyl alcohol to aromatics over zeolite-based catalysts[J]. ACS Catal, 2012, 2(6): 1203-1210.
13. [13]
  [13] 夏海岸, 王秀聪, 徐然然, 吴品, 吴义珠, 杨莉, 左宋林. 分子筛基Brønsted 酸和路易斯酸性位对纤维素热解行为的影响[J]. 林产化学与工业, 2013, 33(6): 29-36.(XIA Hai-an, WANG Xiu-chong, XU Ran-ran, WU Pin, WU Yi-zhu, YANG Li, ZUO Song-lin, Influence of Brønsted and lewis acid sites on pyrolytic behaviors of cellulose over zeolite-based catalysts[J]. Chem Ind For Prod, 2013, 33(6): 29-36.)
14. [14]
  [14] XIA H, SUN K, FENG Z, LI C. The inhibiting effect of H₂O on N₂O decomposition over the bi-nuclear Fe sites in Fe/ZSM-5[J]. J Phys Chem C, 2011, 115(2): 542-548.
15. [15]
  [15] XIA H, SUN K, LIU Z, FENG Z, YING P, LI C. The promotional effect of NO on N₂O decomposition over the bi-nuclear Fe sites in Fe/ZSM-5[J]. J Catal, 2010, 270(1): 103-109.
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沈阳化工大学材料科学与工程学院沈阳 110142