Citation: XIA Hai-an, ZHANG Jun, YAN Xiao-pei, XU Si-quan, YANG Li. Catalytic conversion of biomass derivative γ-valerolactone to aromatics over Zn/ZSM-5 catalyst[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(5): 575-580. shu

Catalytic conversion of biomass derivative γ-valerolactone to aromatics over Zn/ZSM-5 catalyst

XIA Hai-an ^1,2,, ,
ZHANG Jun ^1,2 ,
YAN Xiao-pei ^1,2 ,
XU Si-quan ^1,2 ,
YANG Li ^1,2

1.
1. Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, Nanjing 210037, China;

Corresponding author: XIA Hai-an,
Received Date: 29 January 2015

Fund Project: 国家自然科学青年基金(31200445) (31200445) 中国科学院大连化学物理研究所催化基础国家重点实验室开放基金(N-12-09) (N-12-09) 江苏高校优势学科建设工程资助 (PAPD)。 (PAPD)

Zn/ZSM-5 zeolite catalysts with different Zn contents were prepared by impregnating method. The influence of reaction temperature, reaction time, catalyst dosage, and the acidic properties of catalysts on the conversion of γ-valerolactone to aromatic compounds was investigated.The results show that the introduction of Zn into H-ZSM-5 channel could effective modify the components of liquid product and influence the yields of gas, liquid, and solid as compared to H-ZSM-5 catalyst and non-catalytic conversion of γ-valerolactone. Zn/ZSM-5 catalyst affords the higher contents of aromatic compound compared to H-ZSM-5 and silica catalysts in the liquid product under identical reaction conditions. Therefore, Zn species of Zn/ZSM-5 can not only effectively improve the conversion of γ-valerolactone, but also enhance the formation of aromatic compounds, suggesting that Zn species play a very key role in the formation of these aromatic compounds.
- γ-valerolactone,
- aromatization,
- Zn/ZSM-5,
- Zn species
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