Citation: XIAO Shen, SHEN Lai-hong, XIAO Jun, NIU Xin, GU Hai-ming, SONG Tao. NO_x release in chemical looping combustion of biomass based on hematite[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(4): 490-498. shu

NO_x release in chemical looping combustion of biomass based on hematite

1.
Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Southeast University, Nanjing 210096, China

Corresponding author: SHEN Lai-hong,
Received Date: 28 October 2014

Fund Project: 国家自然科学基金(51276037,51476029,51406035)。 (51276037,51476029,51406035)

Nitrogen emission during chemical looping combustion (CLC) of rice husk based on hematite in a batch fixed bed reactor was studied. Different variables affecting the process, such as reduction temperature and steam content, were tested. The results show that higher reduction temperature results in a higher carbon conversion which reaches the highest value when the steam flow is 1.0 g/min. Furthermore, there are no NO₂ detected at all experiments. The rise of reduction temperature from 750 to 900 ℃ could contribute to the rise of NO, whereas the concentration of N₂O reaches the highest value at 850 ℃. Both N₂O and NO increase remarkably with the increase of steam flow. Nevertheless, the increasing rate of NO is faster than that of N₂O. Besides, KAlSi₃O₈ is detectable in the reduced oxygen carrier, attributing to the reaction of K in biomass with hematite.
- chemical looping combustion,
- biomass,
- hematite,
- NO_x
1. [1]
  [1] BERGUER N, LYNGFELT A. Design and operation of a 10 kW_th chemical-looping combustor for solid fuels-Testing with south African coal[J]. Fuel, 2008, 872(12):2731-2726.
2. [2]
  [2] LEION H, LYNGFELT A. JOHHANSSON M, JERNDAL E. MATTISSON T. The use of ilmenite as an oxygen carrier in chemical-looping combustion[J]. Chem Eng Res Des, 2008, 86(9):1017-1026.
3. [3]
  [3] BERGUER N, LYNGFELT A. The use of petroleum coke as fuel in a 10 kW_th chemical-looping combustor[J]. Int J Greenhouse Gas Control, 2008, 2(2):169-179.
4. [4]
  [4] MATTISSON T, LYNGFELT A, CHO P. The use of iron oxide as an oxygen carrier in chemical-looping combustion of methane with inherent separation of CO₂[J]. Fuel, 2001, 80(13):1953-1962.
5. [5]
  [5] LEION H, MATTISSON T, LYNGFELT A. Solid fuels in chemical-looping combustion[J]. Int J Greenhouse Gas Control, 2008, 2(2):180-193.
6. [6]
  [6] SHEN L H, WU J H, XIAO J. Experiment on chemical looping combustion of coal with NiO based oxygen carrier[J]. Combust Flame, 2009, 156(3):721-728.
7. [7]
  [7] MENDIARA T, ABAD A, DE DIEGO L F, GARCÍA-LABIANO F, GAYN P, ADNEZ J. Biomass combustion in a CLC system using an iron ore as an oxygen carrier[J]. Int J Greenhouse Gas Control, 2013, 11(19):322-330.
8. [8]
  [8] GU H M, SHEN L H, ZHONG Z P, NIU X, GE H J, ZHOU Y F, XIAO S, JIANG S X. NO release during chemical looping combustion with iron ore as an oxygen carrier[J]. Chem Eng J, 2015, 264:211-220.
9. [9]
  [9] SONG T, SHEN L H, XIAO J, CHEN D Q, GU H M, ZHANG S W. Nitrogen transfer of fuel-N in chemical looping combustion[J]. Combust Flame, 2012, 159(3):1286-1295.
10. [10]
  [10] SUNG R S, SANG D K. Chemical-looping combustion with NiO and Fe₂O₃ in a thermobalance and circulating fluidized bed reactor with double loops[J]. Ind Eng Chem Res, 2006, 45(8):2689-2696.
11. [11]
  [11] 吴家桦, 沈来宏, 肖军, 王雷, 郝建刚. 10 kW_th 级串行流化床木屑化学链燃烧试验[J]. 化工学报, 2009, 60(8):2080-2088. (WU Jia-hua, SHEN Lai-hong, XIAO Jun, WANG Lei, HAO Jian-gang.Experiments on chemical looping combustion of sawdust in a 10 kWth interconnected fluidized bed[J]. J Chem Ind Eng, 2009, 60(8):2080-2088.)
12. [12]
  [12] SHEN L H, WU J H, XIAO J, WANG L, HAO J G. Chemical-looping combustion of biomass in a 10 kWth reactor with iron oxide as an oxygen carrier[J]. Energy Fuels, 2009, 23(5):2498-2505.
13. [13]
  [13] 苟进胜, 常建民, 任学勇. 生物质热解过程中氮元素迁移规律研究进展[J]. 科技导报, 2012, (14):70-74. (GOU Jin-sheng, CHANG Jian-min, REN Xue-yong. A review on the release characterization of nitrogen speicies during biomass pyrolysis[J]. Sci Technol Rev, 2012, (14):70-74.)
14. [14]
  [14] ABELHA P, GULYURTLU, CABRITA I. Release of nitrogen precursors from coal and biomass residuces in a bubbling fluidized bed[J]. Energy Fuels, 2008, 22(1):363-371.
15. [15]
  [15] 黄振, 何方, 李新爱, 赵坤, 李海滨, 赵增立. Fe₂O₃-水蒸气生物质化学链共气化制合成气[J]. 太阳能学报, 2013, 34(12):2056-2062. (HUANG Zhen, HE Fang, LI Xin-ai, ZHAO Kun, LI Hai-bin, ZHAO Zeng-li. Syngas generated by chemical-looping gasification of biomass using Fe₂O₃ as oxygen carrier in presence of steam[J]. Acta Energy Sol Sin, 2013, 34(12):2056-2062.)
16. [16]
  [16] KELLER M, LEION H, MATTISSON T, LYNGFELT A. Gasification inhibition in chemical-looping combustion with solid fuels[J]. Combust Flame, 2011, 158(3):393-400.
17. [17]
  [17] GU H, SHEN L, XIAO J, ZHANG S, SONG T, Chemical looping combustion of biornass/coal with natural iron ore oxygen carrier in a continuous reactor[J]. Energy Fuels, 20l1, 5(1):446-455.
18. [18]
  [18] 郝建刚, 吴家桦, 王雷, 沈来宏, 肖军. 基于Fe基载氧体的生物质化学链燃烧试验研究[J]. 锅炉技术, 2010, (2):65-70. (HAO Jian-gang, WU Jia-hua, WANG Lei, SHEN Lai-hong, XIAO Jun. Experiments on chemical looping combustion of biomass with a Fe₂O₃ based oxygen carrier[J]. Boiler Technol, 2010, (2):65-70.)
19. [19]
  [19] LEION H, MATTISSON T, LYNGFELT A. Solid fuels in chemical-looping combustion[J]. Int J Greenhouse Gas Control, 2008, 2(2):180-193.
20. [20]
  [20] LEION H, MATTISSON T, LYNGFELT A. The use of petroleum coke as fuel in chemical-looping combustion[J]. Fuel, 2007, 86(12/13):1947-1958.
21. [21]
  [21] 柏继松. 生物质燃烧过程氮和硫的迁移、转化特性研究[D]. 浙江:浙江大学, 2012. (BO Ji-song. Nitrogen and sulfur conversion mechanism during biomass combustion[D]. Zhejiang:Zhejiang University, 2012.)
22. [22]
  [22] ZHOU H, JENSEN A D, GLARBORG P, KAVALIAUSKAS A. Formation and reduction of nitric oxide in fixed-bed combustion of straw[J]. Fuel, 2006, 85(5/6):705-716.
23. [23]
  [23] WERTHER J, OGAD T. Sewage sludge combustion[J]. Prog Energy Combust Sci, 1999, 25(1):55-116.
24. [24]
  [24] PRAKASH P K, SHEEBA NARAYANAN. Hydrogen production from steam gasification of biomass influence of process parameters on hydrogen yield-A review[J]. Renew Energy, 2014, 66:570-579.
25. [25]
  [25] 常丽萍. 煤热解、气化过程中含氮化合物的生成与释放研究[D]. 太原:太原理工大学, 2004. (CHANG Li-ping. Study on the formation and release of nitrogen-containing compounds during coal pyrolysis and gasification[D]. Taiyuan:Taiyuan University of Technology, 2004.)
26. [26]
  [26] FURIMSKY E, OHTSUKA Y. Formation of nitrogen-containing compounds during slow pyrolysis and oxidation of petroleum coke[J]. Energy Fuels, 1997, 11(5):1073-1080.
27. [27]
  [27] JOHNSSON J E. Formation and reduction of nitrogen oxides in fluided-bed combustion[J]. Fuel, 1994, 73(9):1398-1415.
28. [28]
  [28] GLARBORG P, JENSEN A D, JOHNSSON J E. Fuel nitrogen conversion in solid fuel fired systems[J]. Prog Energy Combust Sci, 2003, 29(2):89-113.
29. [29]
  [29] 黄容, 高瑗, 高明, 廖燕妮, 陈佳烨. 生物质灰渣物质特性和保水性的研究[J]. 水土保持学报, 2013, (6):130-133. (HUANG Rong, GAO Yuan, GAO Ming, LIAO Yan-ni, CHEN Jia-ye. Study on material properties and water absorption capacity of biomass ash[J]. J Soil Water Conserv, 2013, (6):130-133.)
30. [30]
  [30] 肖瑞瑞, 陈雪莉, 王辅臣, 于广锁. 不同生物质灰的理化特性[J]. 太阳能学报, 2011, (3):364-369. (XIAO Rui-rui, CHEN Xue-li, WANG Fu-chen, YU Guang-suo. The physicochemical properties of different biomass ash[J]. Acta Energy Sol Sin, 2011, (3):364-369.)
1. [1]
  Zhonghan Xu , Yuejia Li , Kin Shing Chan . 碳中和新旅程. University Chemistry, 2025, 40(6): 167-171. doi: 10.12461/PKU.DXHX202407075
2. [2]
  Qianqian ZHU , Lihui XU , Hong PAN , Chengjian YAO , Hong ZHAO , Nan MA , Xiaolin SHI , Zihan SHEN , Weijun ZHANG , Zhongjian WANG . Waste cotton fabric-ased porous carbon materials: Preparation and wave-absorbing properties. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1555-1564. doi: 10.11862/CJIC.20250040
3. [3]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
4. [4]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
5. [5]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . Performance and Electrochemical Asymmetry Optimization of Hydrogen Electrode Supported Reversible Solid Oxide Cell. Acta Physico-Chimica Sinica, 2025, 41(1): 100005-0. doi: 10.3866/PKU.WHXB202309037
6. [6]
  Kuaibing Wang , Feifei Mao , Weihua Zhang , Bo Lv . Design and Practice of a Comprehensive Teaching Experiment for Preparing Biomass Carbon Dots from Rice Husk. University Chemistry, 2025, 40(5): 342-350. doi: 10.12461/PKU.DXHX202407042
7. [7]
  Lu Zhuoran , Li Shengkai , Lu Yuxuan , Wang Shuangyin , Zou Yuqin . Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2306003-0. doi: 10.3866/PKU.WHXB202306003
8. [8]
  Xinlong XU , Chunxue JING , Yuzhen CHEN . Bimetallic MOF-74 and derivatives: Fabrication and efficient electrocatalytic biomass conversion. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1545-1554. doi: 10.11862/CJIC.20250046
9. [9]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
10. [10]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-0. doi: 10.3866/PKU.WHXB202311005
11. [11]
  Tianyang Yu , Hao Wei . “Illness Enters through the Mouth”: A Brief Overview of Toxic Chemical Substances in Common Foods. University Chemistry, 2025, 40(7): 225-231. doi: 10.12461/PKU.DXHX202409083
12. [12]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
13. [13]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
14. [14]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, 2024, 40(9): 2307008-0. doi: 10.3866/PKU.WHXB202307008
15. [15]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
16. [16]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 2404023-0. doi: 10.3866/PKU.WHXB202404023
17. [17]
  Lijun Yue , Siya Liu , Peng Liu . 不同晶相纳米MnO₂的制备及其对生物乙醇选择性氧化催化性能的测试——一个科研转化的综合化学实验. University Chemistry, 2025, 40(8): 225-232. doi: 10.12461/PKU.DXHX202410005
18. [18]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
19. [19]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
20. [20]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(690)
HTML views(69)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

NOx release in chemical looping combustion of biomass based on hematite

Metrics

通讯作者: 陈斌, bchen63@163.com

NO_x release in chemical looping combustion of biomass based on hematite