Citation: JI Gui-jie, ZHANG Yao-bing, FU Ning-ning, TANG Lei, LIU Peng, SHEN Jian. Study on the preparation of Mn/Al-SBA-15 and its adsorption desulfurization performance[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(4): 449-455. shu

Study on the preparation of Mn/Al-SBA-15 and its adsorption desulfurization performance

1.
College of Petrochemical Technology, Liaoning University of Petroleum and Chemical Technology, Fushun 113001, China

Corresponding author: SHEN Jian,
Received Date: 5 September 2014

Mn/Al-SBA-15 absorbent was synthesized by impregnation using Al-SBA-15 prepared by grafting method as support, manganese acetate as precursor of active component. The samples were characterized by means of XRD, N₂ adsorption-desorption, NH₃-TPD, Py-FTIR and XPS. The adsorbent was used for adsorption desulfurization of simulated gasoline. The optimum molar ratio of Al/Si was determined through combining characterization of samples and their desulfurization performance. The mechanism of adsorption desulfurization was proposed. The regeneration properties were also studied. The results showed that when the molar ratio of Al/Si was 1:45, the performance of adsorbent was the best. The thiophene was adsorbed through acid-base reaction. The introduction of Al improved the stability and the regeneration of the adsorbent.
- thiophene,
- adsorption,
- SBA-15,
- acidity,
- regeneration
1. [1]
  [1] 王军民, 袁铁. 超低硫清洁汽油的生产技术进展[J]. 天然气与石油, 2001, 19(4):14-17. (WANG Jun-min, YUAN Tie. The progress of ultra-low sulfur clean gasoline production technology[J]. Nat Gas Oil, 2001, 19(4):14-17.)
2. [2]
  [2] 赵乐平, 关明华, 庞宏, 尤百玲. 无硫汽油技术方案的选择[C]//第十届全国工业催化技术及应用年会论文集. 西安:工业催化杂志社, 2013:303-305. (ZHAO Le-ping, GUAN Ming-hua, PANG Hong, YOU Bai-ling. No sulfur-content gasoline technology scheme[C]//The Essays of the Tenth National Industrial Catalysis Technology and Application. Xi'an:Industrial Catalysis Press, 2013:303-305.)
3. [3]
  [3] WANG W B, WANG S J, LIU H Y, WANG Z X. Desulfurization of gasoline by a new method of electrochemical catalytic oxidation[J]. Fuel, 2007, 86(17):2747-2753.
4. [4]
  [4] 朱全力, 赵旭涛, 赵振兴, 马洪江, 邓友全. 加氢脱硫催化剂与反应机理的研究进展[J]. 分子催化, 2006, 20(4):372-383. (ZHU Quan-li, ZHAO Xu-tao, ZHAO Zhen-xing, MA Hong-jiang, DONG You-quan. The research progress of hydrodesulfurization catalyst and reaction mechanism[J]. J Mol Catal (China), 2006, 20(4):372-383.)
5. [5]
  [5] SENTORUN-SHALABY C, SAHA S K, MA X L, SONG C S. Mesoporous-molecular-sieve-supported nickel sorbents for adsorptive desulfurization of commercial ultra-low-sulfur diesel fuel[J]. Appl Catal B:Environ, 2011, 101(3):718-726.
6. [6]
  [6] CHEN H, WANG Y H, YANG F H, YANG R T. Desulfurization of high-sulfur jet fuel by mesoporous π-complexation adsorbents[J]. Chem Eng Sci, 2009, 64(24):5240-5246.
7. [7]
  [7] KO C H, PARK J G, PARK J C, SONG H, HAN S, KIM J. Surface status and size influences of nickel nanoparticles on sulfur compound adsorption[J]. Appl Surf Sci, 2007, 253(13):5864-5867.
8. [8]
  [8] ALHAMED Y A, BAMUFLEH H S. Sulfur removal from model diesel fuel using granular activated carbon from dates' stones activated by ZnCl₂[J]. Fuel, 2009, 88(1):87-94.
9. [9]
  [9] TANG K, SONG L J, DUAN L H, LI X Q, GUI J Z, SUN Z L. Deep desulfurization by selective adsorption on a heteroatoms zeolite prepared by secondary synthesis[J]. Fuel Process Technol, 2008, 89(1):1-6.
10. [10]
  [10] KE T, XIN H. Deep desulfurization of model gasoline by adsorption on mesoporous CeMCM-41[J]. Pet Sci Technol, 2010, 28(6):573-581.
11. [11]
  [11] TIAN F P, SHEN Q C, FU Z K, WU Y H, JIA C Y. Enhanced adsorption desulfurization performance over hierarchically structured zeolite Y[J]. Fuel Process Technol, 2014, 128:176-182.
12. [12]
  [12] NIE Y, DONG Y X, BAI L, DONG H F, ZHANG X P. Fast oxidative desulfurization of fuel oil using dialkylpyridinium tetrachloroferrates ionic liquids[J]. Fuel, 2013, 103:997-1002.
13. [13]
  [13] GAO H S, LUO M F, XING J M, WU Y, LI W L, LIU Q F, LIU H Z. Desulfurization of fuel by extraction with pyridinium-based ionic liquids[J]. Ind Eng Chem Res, 2008, 47(21):8384-8388.
14. [14]
  [14] CHEN J, LI J D, QI R B, YE H, CHEN C X. Pervaporation separation of thiophene-heptane mixtures with polydimethylsiloxane (PDMS) membrane for desulfurization[J]. Appl Biochem Biotechnol, 2010, 160(2):486-497.
15. [15]
  [15] ITO E, VAN VEEN J A. On novel processes for removing sulphur from refinery streams[J]. Catal Today, 2006, 116(4):446-460.
16. [16]
  [16] 张景成, 柳云骐, 安高军, 柴永明, 付庆涛, 刘晨光. 吸附脱硫技术生产清洁油品[J]. 化学进展, 2008, 20(11):1834-1845. (ZHANG Jing-cheng, LIU Yun-qi, AN Gao-jun, CHAI Yong-ming, FU Qing-tao, LIU Chen-guang. The adsorptive desulfurization technologies for ultra-clean oil production[J]. Prog Chem, 2008, 20(11):1834-1845.)
17. [17]
  [17] 唐晓东, 李林, 曾雪玲, 赖先熔. 汽油活性炭基脱硫吸附剂的制备与评价[J]. 燃料化学学报, 2009, 37(5):629-634. (TANG Xiao-dong, LI Lin, ZENG Xue-ling, LAI Xian-rong. Preparation and evaluation of gasoline activated carbon-based desulfurization adsorbent[J]. J Fuel Chem Technol, 2009, 37(5):629-634.)
18. [18]
  [18] 岳军, 刘晓勤, 姚虎卿. CuCl负载型吸附剂的深度脱硫性能研究[J]. 高校化学工程学报, 2007, 20(6):1001-1004. (YUE Jun, LIU Xiao-qin, YAO Hu-qing. Deep desulfurization performance of CuCl supported adsorbents[J]. J Chem Eng Chin Univ, 2007, 20(6):1001-1004.)
19. [19]
  [19] WANG Y H, YANG R T, HEINZEL J M. Desulfurization of jet fuel by π-complexation adsorption with metal halides supported on MCM-41 and SBA-15 mesoporous materials[J]. Chem Eng Sci, 2008, 63(2):356-365.
20. [20]
  [20] MENG X R, QIU G H, WANG G, CAI Q H, WANG Y H. Durable and regenerable mesoporous adsorbent for deep desulfurization of model jet fuel[J]. Fuel Process Technol, 2013, 111:78-85.
21. [21]
  [21] ZHAO D Y, FENG J L, HUO Q S, MELOSH N, FREDRICKSON G H, CHMELKA B F, STUCKY G D. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores[J]. Science, 1998, 279(5350):548-552.
22. [22]
  [22] KRUK M, JARONIEC M, KO C H, RYOO R. Characterization of the porous structure of SBA-15[J]. Chem Mater, 2000, 12(7):1961-1968.
23. [23]
  [23] 吴淑杰, 黄家辉, 吴通好, 宋科, 王虹苏, 邢丽红, 徐海燕, 徐玲, 管景奇, 阚秋斌. Al-SBA-15 介孔分子筛的合成、表征及其在苯酚叔丁基化反应中的催化性能[J]. 催化学报, 2006, 27(1):9-14. (WU Shu-jie, HUANG Jia-hui, WU Tong-hao, SONG Ke, WANG Hong-su, XING Li-hong, XU Hai-yan, XU Ling, GUAN Jing-qi, HAN Qiu-bin. Synthesis, characterization, and catalytic performance of mesoporous Al-SBA-15 for Tert-butylation of phenol[J]. Chin J Catal, 2006, 27(1):9-14.)
24. [24]
  [24] 郭卓, 朱广山, 辛明红, 刘成站, 裘式纶. C₆₀/SBA-15介孔复合材料的合成及其荧光性质的研究[J]. 高等学校化学学报, 2005, 26(10):1917-1920. (GUO Zhuo, ZHU Guang-shan, XIN Ming-hong, LIU Cheng-zhan, QIU Shi-lun.Synthesis and fluorescence properties of fulleride encapsulated in mesoporous SBA-15 host[J]. Chem J Chin Univ, 2005, 26(10):1917-1920.)
25. [25]
  [25] 陈杨英, 韩秀文, 包信和. W-SBA-15介孔分子筛的直接合成及其对环己烯环氧化反应的催化性能[J]. 催化学报, 2005, 26(5):412-416. (CHEN Yang-ying, HAN Xiu-wen, BAO Xin-he. Direct synthesis of W-SBA-15 mesoporous molecular sieves and their catalytic performance for epoxidation of cyclohexene[J]. Chin J Catal, 2005, 26(5):412-416.)
26. [26]
  [26] HUANG P, PAN S W, HUANG B C, CHENG H, YE D Q, WU L J, FU M L, LU S L. Structural properties of MnO_x/Al-SBA-15 in low-temperature selective catalytic reduction of NO_x with NH₃[J]. Acta Phys-Chim Sin, 2013, 29(1):176-182.
27. [27]
  [27] PUTZ M V, RUSSO N, SICILIA E. On the applicability of the HSAB principle through the use of improved computational schemes for chemical hardness evaluation[J]. J Comput Chem, 2004, 25(7):994-1003.
28. [28]
  [28] PEARSON R G. Hard and soft acids and bases[J]. J Am Chem Soc, 1963, 85(22):3533-3539.
1. [1]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
2. [2]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-0. doi: 10.1016/j.actphy.2024.100039
3. [3]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
4. [4]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
5. [5]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
6. [6]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
7. [7]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
8. [8]
  Wei Li , Jinfan Xu , Yongjun Zhang , Ying Guan . 共价有机框架整体材料的制备及食品安全非靶向筛查应用——推荐一个仪器分析综合化学实验. University Chemistry, 2025, 40(6): 276-285. doi: 10.12461/PKU.DXHX202406013
9. [9]
  Yang ZHOU , Lili YAN , Wenjuan ZHANG , Pinhua RAO . Thermal regeneration of biogas residue biochar and the ammonia nitrogen adsorption properties. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1574-1588. doi: 10.11862/CJIC.20250032
10. [10]
  Hengyi ZHU , Liyun JU , Haoyue ZHANG , Jiaxin DU , Yutong XIE , Li SONG , Yachao JIN , Mingdao ZHANG . Efficient regeneration of waste LiNi_0.5Co_0.2Mn_0.3O₂ cathode toward high-performance Li-ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 625-638. doi: 10.11862/CJIC.20240358
11. [11]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
12. [12]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
13. [13]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
14. [14]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
15. [15]
  Jingyi Xie , Qianxi Lü , Weizhen Qiao , Chenyu Bu , Yusheng Zhang , Xuejun Zhai , Renqing Lü , Yongming Chai , Bin Dong . Enhancing Cobalt―Oxygen Bond to Stabilize Defective Co₂MnO₄ in Acidic Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305021-0. doi: 10.3866/PKU.WHXB202305021
16. [16]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
17. [17]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
18. [18]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
19. [19]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
20. [20]
  Jianan Zhang , Mengzhen Xu , Jiamin Liu , Yufei He . 面向“双碳”目标的脱氯吸附剂开发研究型综合实验设计. University Chemistry, 2025, 40(6): 248-255. doi: 10.12461/PKU.DXHX202408068

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(399)
HTML views(51)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142