Citation: ZHANG Lu, LIN Rui, HUANG Zhen, FAN Ren-jie. Study on preparation of cobalt-polypyrrole-carbon black supported Pt catalyst and its single cell performance[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(3): 352-359. shu

Study on preparation of cobalt-polypyrrole-carbon black supported Pt catalyst and its single cell performance

ZHANG Lu ^1,2 ,
LIN Rui ^1,2,, ,
HUANG Zhen ^1,2 ,
FAN Ren-jie ^1,2

1.
1. Clean Energy Automotive Engineering Center, Tongji University, Shanghai 201804, China;

Corresponding author: LIN Rui,
Received Date: 9 September 2014

Fund Project: 国家自然科学基金(21276199) (21276199)

Cobalt-polypyrrole-carbon black supported Pt catalyst (Pt/Co-PPy-C) was prepared by pulse-microwave assisted chemical reduction and used as a cathode catalyst for oxygen reduction reaction (ORR) in a single cell; the influence of operation temperature and H₂/air stoichiometric ratio on the cell performances was investigated, in comparison with the commercial Pt/C catalyst. The results indicated that the cell performs best at 70 ℃ and with a H₂/Air ratio of 1.2:2.5. During the 150 h durability test at a galvanostatic operation condition of 600 mA/cm², the voltage degradation rate with Pt/Co-PPy-C as the cathode catalyst is 0.119 mV/h, about 26% of that with the commercial Pt/C catalyst. The cathode charge transfer impedances before and after durability test are about 7.176 and 8.767 mohm, respectively, much smaller than those with the Pt/C catalyst. The average particle size of Pt in Pt/Co-PPy-C is increased from 2.46 to 3.18 nm, also smaller than that for the Pt/C catalyst. The Pt/Co-PPy-C catalyst exhibits superior performance in ORR and may have an enormous application potential in fuel cell.
- polypyrrole,
- fuel cell,
- cathode catalyst,
- single cell,
- durability,
- oxygen reduction reaction
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