Citation: XIE Deng-yin, ZHANG Su-ping, CHEN Zhi-yuan, CHEN Zhen-qi, XU Qing-li. Co and Cu modified Ni/Al₂O₃ steam reforming catalysts for hydrogen production from model bio-oil[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(3): 302-308. shu

Co and Cu modified Ni/Al₂O₃ steam reforming catalysts for hydrogen production from model bio-oil

1.
Key Laboratory of Coal Gasification and Engineering of Ministry of Education, Shanghai 200237, China

Corresponding author: ZHANG Su-ping,
Received Date: 24 September 2014

Fund Project: 国家支撑计划(2014BAD02B03) (2014BAD02B03) 国家自然科学基金(51176049) (51176049) 教育部新世纪优秀人才支持计划(NCET-11-0642)。 (NCET-11-0642)

Ni/Al₂O₃ catalyst was selected as the reference catalyst for steam reforming of model bio-oil to produce hydrogen. Ni-Cu/Al₂O₃, Ni-Co/Al₂O₃ and Ni-Co-Cu/Al₂O₃ were prepared to investigate the influence of Co and Ni on steam reforming of bio-oil. The results show that Co can enhance the water gas shift (WGS) reaction rate, and Cu can prevent the formation of coke. The reaction conditions for the steam reforming of bio-oil with the Ni-Co-Cu/Al₂O₃ catalyst were optimized as the follows: temperature of 900 ℃, water-oil ratio (the mass ratio of steam to oil) of 6 g/g and weight hourly space velocity (WHSV) of 1 h^-1. The carbon selectivity of 87.5%, hydrogen yield of 84.2% and potential hydrogen yield of 92.4% can be obtained at the optimum conditions.
- bio-oil,
- catalytic reforming,
- hydrogen
1. [1]
  [1] PENA M A, GOMEZ J P, FIERRO J L G. New catalytic routes for syngas and hydrogen production[J]. Appl Catal A: Gen, 1996, 144(1/2): 7-57.
2. [2]
  [2] 张秀梅, 陈冠益, 孟祥梅, 李新禹. 催化热解生物质制取富氢气体的研究[J]. 燃料化学学报, 2004, 32(4): 446-449.(ZHANG Xiu-mei, CHEN Guan-yi, MENG Xiang-mei, LI Xin-yu. Production of hydrogen-rich gas from biomass by catalytic pyrolysis[J]. J Fuel Chem Technol, 2004, 32(4): 446-449.)
3. [3]
  [3] 郭建维, 宋晓锐, 崔英德. 流化床反应器中生物质的催化裂解气化研究[J]. 燃料化学学报, 2001, 29(4): 319-322.(GUO Jian-wei, SONG Xiao-rui, CUI Ying-de. Catalytic pyrogasification of biomass in a fluidized-bed reactor[J]. J Fuel Chem Technol, 2001, 29(4): 319-322.)
4. [4]
  [4] 任辉, 张荣, 王锦凤, 孙东凯, 毕继诚. 废弃生物质在超临界水中转化制氢过程的研究[J]. 燃料化学学报, 2003, 31(6): 595-599.(REN Hui, ZHANG Rong, WANG Jin-feng, SUN Dong-kai, BI Ji-cheng. Investigation of hydrogen production from waste biomass in supercritical water[J]. J Fuel Chem Technol, 2003, 31(6): 595-599.)
5. [5]
  [5] KUO J H, LIN C L, WEY M Y. Effect of agglomeration/defluidization on hydrogen generation during fluidized bed air gasification of modified biomass[J]. Int J Hydrogen Energy, 2012, 37(2): 1409-1417.
6. [6]
  [6] BORGOGNONI F, TOST S, VADRUCCI M, SANTUCCI A. Combined methane and ethanol reforming for pure hydrogen production through Pd-based membranes[J]. Int J Hydrogen Energy, 2013, 38(3): 1430-1438.
7. [7]
  [7] GARCIA L, FRENCH R, CZERNIK S. Catalytic steam reforming of bio-oils for the production of hydrogen: Effects of catalyst composition[J]. Appl Catal A: Gen, 2000, 201(2): 225-239.
8. [8]
  [8] AZAD F S, ABEDI J, SALEHI E, HARDING T. Production of hydrogen via steam reforming of bio-oil over Ni-based catalysts: Effect of support[J]. Chem Eng J, 2012, 180(15): 145-150.
9. [9]
  [9] YAN C F, CHENG F F, HU R R. Hydrogen production from catalytic steam reforming of bio-oil aqueous fraction over Ni/CeO₂-ZrO₂ catalysts[J]. Int J Hydrogen Energy, 2010, 35(21): 11693-11699.
10. [10]
  [10] 王兆祥, 朱锡锋, 潘越, 李全新. C12A7-K₂O催化水蒸气重整生物油制氢[J]. 中国科学技术大学学报, 2006, 36(4): 458-460.(WANG Zhao-xiang, ZHU Xi-feng, PAN Yue, LI Quan-xin. Hydrogen production from steam reforming of bio-oil with C12A7-K₂O catalyst[J]. J Univ Sci Technol Chin, 2006, 36(4): 458-460.)
11. [11]
  [11] IWASA N, YAMANE T, ARAI M. Influence of alkali metal modification and reaction conditions on the catalytic activity and stability of Ni containing smectite-type material for steam reforming of acetic acid[J]. Int J Hydrogen Energy, 2011, 36(10): 5904-5911.
12. [12]
  [12] GARBARINO G, LAGAZZO A, RIANI P, BUSCA G. Steam reforming of ethanol-phenol mixture on Ni/Al₂O₃: Effect of Ni loading and sulphur deactivation[J]. Appl Catal B: Environ, 2013, 129: 460-472.
13. [13]
  [13] HU X, LU G X. Comparative study of alumina-supported transition metal catalysts for hydrogen generation by steam reforming of acetic acid[J]. Appl Catal B: Environ, 2010. 99(1/2): 289-297.
14. [14]
  [14] REMON J, MEDRANO J A, BIMBELA F, GARCIA L, ARAUZO J. Ni/Al-Mg-O solids modified with Co or Cu for the catalytic steam reforming of bio-oil[J]. Appl Catal B: Environ, 2013, 132-133: 433-444.
15. [15]
  [15] MEDRANO J A, OLIVA M, RUIZ J, GARCIA L, ARAUZO J. Hydrogen from aqueous fraction of biomass pyrolysis liquids by catalytic steam reforming influidized bed[J]. Energy, 2011, 36(4): 2215-2224.
16. [16]
  [16] MEDRANO J A, OLIVA M, RUIZ J, GARCIA L, ARAUZO J. Catalytic steam reforming of model compounds of biomass pyrolysis liquids in fluidized bed reactor with modified Ni/Al catalysts[J]. J Anal Appl Pyrolysis, 2009, 85(1/2): 214-225.
17. [17]
  [17] BASAGIANNIS A C, VERYKIOS X E. Catalytic steam reforming of acetic acid for hydrogen production[J]. Int J Hydrogen Energy, 2007, 32(15): 3343-3355.
18. [18]
  [18] FURUSAWA T, SAITO K, KORI Y, MIURA Y, SATO M, SUZUKI N. Steam reforming of naphthalene/benzene with various types of Pt- and Ni-based catalysts for hydrogen production[J]. Fuel, 2013, 103: 111-121.
19. [19]
  [19] PANT K K, MOHANTY P, AGARWAL S, DALAI A K. Steam reforming of acetic acid for hydrogen production over bifunctional Ni-Co catalysts[J]. Catal Today, 2013, 207: 36-43.
20. [20]
  [20] HU X, LU G. Investigation of steam reforming of acetic acid to hydrogen over Ni-Co metal catalyst[J]. J Mol Catal A: Chem, 2007, 261(1): 43-48.
21. [21]
  [21] RIOCHE C, KULKARNI S, MEUNIER F C, JOHN P B, BURCH R. Steam reforming of model compounds and fast pyrolysis bio-oil on supported noble metal catalysts[J]. Appl Catal B: Environ, 2005, 61(1/2): 130-139.
22. [22]
  [22] BIMBELA F, CHEN D, RUIZ J, GARCIA L, ARAUZO J. Ni/Al coprecipitated catalysts modified with magnesium and copper for the catalytic steam reforming of model compounds from biomass pyrolysis liquids[J]. Appl Catal B: Environ, 2012, 119-120: 1-12.
23. [23]
  [23] ECHEGOYEN Y, SUELVES I, LAZARO M J, SANJUAN M L, MOLINER R. Thermo catalytic decomposition of methane over Ni-Mg and Ni-Cu-Mg catalysts Effect of catalyst preparation method[J]. Appl Catal A: Gen, 2007, 333(2): 229-237.
24. [24]
  [24] HU X, LU G. Comparative study of alumina supported transition metal catalysts for hydrogen generation by steam reforming of acetic acid[J]. Appl Catal B: Environ, 2010, 99(1/2): 289-297.
25. [25]
  [25] PINTO F, FRANCO C, ANDRE R N, TAVARES C, DIAS M, GULYURTLU I. Effect of experimental conditions on co-gasification of coal, biomass and plastics wastes with air/steam mixtures in a fluidized bed system[J]. Fuel, 2003, 82(15/17): 1967-1976.
26. [26]
  [26] WANG J B, CHENG G, YOU Y L, XIAO B, LIU S, HE P, GUO D, GUO X J, ZHANG G J. Hydrogen-rich gas production by steam gasification of municipal solid waste(MSW) using NiO supported on modified dolomite[J]. Int J Hydrogen Energy, 2012, 37(8): 6503-6510.
27. [27]
  [27] GOYAL N, PANT K K, GUPTA R. Hydrogen production by steam reforming of model bio-oil using structured Ni/Al₂O₃ catalysts[J]. Int J Hydrogen Energy, 2013, 38(2): 921-933.
28. [28]
  [28] SEYEDEYN-AZAD F, SALEHI E, ABEDI J, HARDING T. Biomass to hydrogen via catalytic steam reforming of bio-oil over Ni-supported alumina catalysts[J]. Fuel Process Technol, 2011, 92(3): 563-569.
1. [1]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
2. [2]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of Electron Bridge and Activation of MoS₂ Inert Basal Planes by Ni Doping for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-0. doi: 10.3866/PKU.WHXB202406024
3. [3]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
4. [4]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Research on Cu-Based and Pt-Based Catalysts for Hydrogen Production through Methanol Steam Reforming. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-0. doi: 10.1016/j.actphy.2025.100049
5. [5]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
6. [6]
  Zhaoxin LI , Ruibo WEI , Min ZHANG , Zefeng WANG , Jing ZHENG , Jianbo LIU . Advancements in the construction of inorganic protocells and their cell mimic and bio-catalytical applications. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2286-2302. doi: 10.11862/CJIC.20240235
7. [7]
  Xiaogang Liu , Mengyu Chen , Yanyan Li , Xiantao Ma . Experimental Reform in Applied Chemistry for Cultivating Innovative Competence: A Case Study of Catalytic Hydrogen Production from Liquid Formaldehyde Reforming at Room Temperature. University Chemistry, 2025, 40(7): 300-307. doi: 10.12461/PKU.DXHX202408007
8. [8]
  Lu Zhuoran , Li Shengkai , Lu Yuxuan , Wang Shuangyin , Zou Yuqin . Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2306003-0. doi: 10.3866/PKU.WHXB202306003
9. [9]
  Yue Zhang , Bao Li , Lixin Wu . GO-Assisted Supramolecular Framework Membrane for High-Performance Separation of Nanosized Oil-in-Water Emulsions. Acta Physico-Chimica Sinica, 2024, 40(5): 2305038-0. doi: 10.3866/PKU.WHXB202305038
10. [10]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
11. [11]
  Xinlong XU , Chunxue JING , Yuzhen CHEN . Bimetallic MOF-74 and derivatives: Fabrication and efficient electrocatalytic biomass conversion. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1545-1554. doi: 10.11862/CJIC.20250046
12. [12]
  Lijun Yue , Siya Liu , Peng Liu . 不同晶相纳米MnO₂的制备及其对生物乙醇选择性氧化催化性能的测试——一个科研转化的综合化学实验. University Chemistry, 2025, 40(8): 225-232. doi: 10.12461/PKU.DXHX202410005
13. [13]
  . . Chinese Journal of Inorganic Chemistry, 2024, 40(12): 0-0.
14. [14]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
15. [15]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
16. [16]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
17. [17]
  Zhibei Qu , Changxin Wang , Lei Li , Jiaze Li , Jun Zhang . Organoid-on-a-Chip for Drug Screening and the Inherent Biochemistry Principles. University Chemistry, 2024, 39(7): 278-286. doi: 10.3866/PKU.DXHX202311039
18. [18]
  Yang Liu , Peng Chen , Lei Liu . Chemistry “101 Plan”: Design and Construction of Chemical Biology Textbook. University Chemistry, 2024, 39(10): 45-51. doi: 10.12461/PKU.DXHX202407085
19. [19]
  Tianyu Feng , Guifang Jia , Peng Zou , Jun Huang , Zhanxia Lü , Zhen Gao , Chu Wang . Construction of the Chemistry Biology Experiment Course in the Chemistry “101 Program”. University Chemistry, 2024, 39(10): 69-77. doi: 10.12461/PKU.DXHX202409002
20. [20]
  Jinghan ZHANG , Guanying CHEN . Progress in the application of rare-earth-doped upconversion nanoprobes in biological detection. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2335-2355. doi: 10.11862/CJIC.20240249

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(535)
HTML views(60)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Co and Cu modified Ni/Al2O3 steam reforming catalysts for hydrogen production from model bio-oil

Metrics

通讯作者: 陈斌, bchen63@163.com

Co and Cu modified Ni/Al₂O₃ steam reforming catalysts for hydrogen production from model bio-oil