Citation: WANG Run-ping, MAO Shu-hong, DUAN Xiu-qin, LIN Wen-bin, WANG Qi, CHI Yong-qing. Catalytic performance of nickel-based catalysts with different supports in partial oxidation of methane to synthesis gas[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(2): 228-234. shu

Catalytic performance of nickel-based catalysts with different supports in partial oxidation of methane to synthesis gas

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School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021, China

Corresponding author: WANG Run-ping,
Received Date: 26 August 2014
Available Online: 10 November 2014
Fund Project: 太原科技大学校青年基金(20123017)。 (20123017)

A series of Ni-based catalysts with different supports (Al₂O₃, ZrO₂, CeO₂, CeO₂-Al₂O₃ and ZrO₂-Al₂O₃) were prepared by the methods of impregnation. The effects of supports on the physical structures and catalytic performance of the resultant catalysts in partial oxidation of methane (POM) were investigated. The catalysts were characterized by N₂ physical adsorption, X-ray diffraction, temperature programmed reduction by hydrogen, temperature programmed desorption of ammonia and temperature programmed oxidation. The results showed that the Ni/Al₂O₃ catalyst had a large BET specific surface area and high initial activity. However, the Ni/Al₂O₃ catalyst showed a serious deactivation due to the formation of large amount of carbon deposited on the surface of the catalyst. Ni/ZrO₂and Ni/CeO₂ catalysts displayed low activity, which resulted from its low BET specific surface area and poor NiO dispersion. The Ni/ZrO₂-Al₂O₃ catalyst showed high activity and the Ni/CeO₂-Al₂O₃ catalyst exhibited the best activity and coking resistance among the catalysts. CeO₂ could effectively suppress carbon formation and the transformation to inactive carbon species, due to the oxygen storage and release ability.
- methane,
- partial oxidation,
- nickel,
- support
1. [1]
  [1] ENGER B C, LODENG R, HOLMEN A. A review of catalytic partial oxidation of methane to synthesis gas with emphasis on reaction mechanisms over transition metal catalysts[J]. Appl Catal A: Gen, 2008, 346(1/2): 1-27.
2. [2]
  [2] ALBERTAZZI S, ARPENTINIER P, BASILE F, DELGALLO P, FORNASARI G, GARY D, VACCARI A. Deactivation of a Pt/γ-Al₂O₃ catalyst in the partial oxidation of methane to synthesis gas[J]. Appl Catal A: Gen, 2003, 247(1): 1-7.
3. [3]
  [3] ZHANG Y H, XIONG G X, SHENG S S, YANG W S. Deactivation studies over NiO/γ-Al₂O₃ catalysts for partial oxidation of methane to syngas[J]. Catal Today, 2000, 63(2/4): 517-522.
4. [4]
  [4] MIAO Q, XIONG G X, SHENG S S, CUI W, XU L, GUO X X. Partial oxidation of methane to syngas over nickel-based catalysts modified by alkali metal oxide and rare earth metal oxide[J]. Appl Catal A: Gen, 1997, 154(1/2): 17-27.
5. [5]
  [5] DISSANAYAKE D, ROSENEK M P, KHARAS K C C, LUNSFORD J H. Partial oxidation of methane to carbon monoxide and hydrogen over a Ni/Al₂O₃ catalyst[J]. J Catal, 1991, 132(1): 117-124.
6. [6]
  [6] 余长林, 胡久彪, 杨凯, 周晓春. 制备方法对Ni/CeO₂-A1₂O₃催化剂甲烷部分氧化催化性能的影响[J]. 燃料化学学报, 2013, 41(6): 722-728. (YU Chang-lin, HU Jiu-biao, YANG Kai, ZHOU Xiao-chun. Effects of preparation methods on the catalytic performance of Ni/CeO₂-Al₂O₃ catalyst in methane partial oxidation[J]. J Fuel Chem Technol, 2013, 41(6): 722-728.)
7. [7]
  [7] 余长林, 胡久彪, 翁维正, 周晓春, 陈喜蓉. Co/Ce_0.5Zr_0.5O₂催化剂的制备及甲烷部分氧化制合成气[J]. 燃料化学学报, 2012, 40(4): 418-423. (YU Chang-lin, HU Jiu-biao, WENG Wei-zheng, ZHOU Xiao-chun, CHEN Xi-rong. Preparation of Co/Ce_0.5Zr_0.5O₂ catalysts and their catalytic performance in methane partial oxidation to produce synthesis gas[J]. J Fuel Chem Technol, 2012, 40(4): 418-423.)
8. [8]
  [8] SONG Y Q, HE D H, XU B Q. Effects of preparation methods of ZrO₂ support on catalytic performances of Ni/ZrO₂ catalysts in methane partial oxidation to syngas[J]. Appl Catal. A: Gen, 2008, 337(1/2): 19-28.
9. [9]
  [9] PENGPANICH S, MEEYOO V, RIRKSOMBOON T. Methane partial oxidation over Ni/CeO₂-ZrO₂ mixed oxide solid solution catalysts[J]. Catal Today, 2004, 93-95(1): 95-105.
10. [10]
  [10] ZHU T L, FLYTZANI-STEPHANOPOULOS M. Catalytic partial oxidation of methane to synthesis gas over Ni-CeO₂[J]. Appl Catal A: Gen, 2001, 208(2): 403-417.
11. [11]
  [11] MARIA D, SALAZA V, BRYAN R. Hydrogen production over Ni/ceria supported catalysts by partial oxidation of methane[J]. Int J Hydrogen Energy, 2009, 34(24): 9723-9729.
12. [12]
  [12] KIM P, KIM Y H, KIM H S, SONG I S, YI J H. Synthesis and characterization of mesoporous alumina with nickel incorporated for use in the partial oxidation of methane into synthesis gas[J]. Appl Catal A: Gen, 2004, 272(1/2): 157-166.
13. [13]
  [13] XU S, WANG X L. Highly active and coking resistant Ni/CeO₂-ZrO₂ catalyst for partial oxidation of methane[J]. Fuel, 2005, 84(3): 563-567.
14. [14]
  [14] MEI D J, CHEN Y Q, ZHONG J B, WEI Z L, MA D G, MAO C. Catalytic partial oxidation of methane over Ni/CeO₂-ZrO₂-A1₂O₃[J]. J Rare Earth, 2007, 25(3): 311-315.
15. [15]
  [15] BARTHOLOMEW C H, PANNELL R B. The stoichiometry of hydrogen and carbon monoxide chemisorption on alumina- and silica-supported nickel[J]. J Catal, 1980, 65(2): 390-401.
16. [16]
  [16] 孙卫中, 莫若飞, 靳国强, 郭向云. 不同载体的镍基催化剂在甲烷部分氧化反应中的催化行为[J].天然气化工, 2006, 31(6): 1-5. (SUN Wei-zhong, MO Ruo-fei, JIN Guo-qiang, GUO Xiang-yun. Catalytic behaviors of nickel based catalysts with different supports in partial oxidation of methane[J]. Nat Gas Chem Ind, 2006, 31(6): 1-5.)
17. [17]
  [17] DONGARE M K, MALSHE K, GOPINATH C S, URWAN I K, KEMNITZ E. Oxidation activity and ¹⁸O-isotope exchange behavior of nickel oxide-stabilized cubic zirconia[J]. J Catal, 2004, 222(1): 80-86.
18. [18]
  [18] KOBAYASHI Y, HORIGUCHI J, KOBAYASHI S, YAMAZAKI Y, OMATT K, NAGAO D, KONNO M, YAMADA M. Effect of NiO content in mesoporous NiO-Al₂O₃ catalysts for high pressure partial oxidation of methane to syngas[J]. Appl Catal A: Gen, 2011, 395(1/2): 129-137.
19. [19]
  [19] OZDEMIR H, FARUK OKSUZOMER M A, GURKAYNAK M A. Preparation and characterization of Ni based catalysts for the catalytic partial oxidation of methane: Effect of support basicity on H₂/CO ratio and carbon deposition[J]. Int J Hydrogen Energy, 2010, 35(22): 12147-12160.
20. [20]
  [20] CHEN L, LU Y, HONG Q, LIN J, DAUTZENBERG F M. Catalytic partial oxidation of methane to syngas over Ca-decorated Al₂O₃ supported Ni and NiB catalyst[J]. Appl Catal A: Gen, 2005, 292(2): 295-304.
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