Citation: CHU Qi, FENG Jie, ZHANG Li-li, XU Kun, XIE Ke-chang. Promoting effect of potassium on sulfur resistance in benzene hydrogenation over Ni₂Mo₃N[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(2): 208-213. shu

Promoting effect of potassium on sulfur resistance in benzene hydrogenation over Ni₂Mo₃N

1.
State Key Laboratory Training Base of Coal Science and Technology, Key Laboratory of Coal Science and Technology for Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: FENG Jie,
Received Date: 22 October 2014
Available Online: 5 December 2014
Fund Project: 国家高技术研究发展计划(863计划, 2011AA05A204) (863计划, 2011AA05A204) 教育部长江学者奖励计划(2009)。 (2009)

To improve sulfur resistance of bimetallic nitrides in benzene hydrogenation reaction, K-promoted (K-Ni₂Mo₃N) catalysts were prepared to investigate the effect of potassium on sulfur resistance. K-Ni₂Mo₃N expressed a higher sulfur resistance than Ni₂Mo₃N when used in benzene hydrogenation with 0.01% thiophene condition. Combined XPS and H₂-TPR characterization results, it could be concluded the potassium species might donate electrons to nickel species to make nickel species an electron-enriched state, which might weaken the interaction bewteen thiophene and nickel species. The TPD-MS results also confirmed the potassium species weakened the thiophene adsorption on the catalyst surface. The critical parameter of sulfur resistance are the suitable adsorption strength which could be handled by the electron condition of active site.
- Ni₂Mo₃N,
- potassium,
- sulfur resistance,
- thiophene,
- benzene hydrogenation
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Promoting effect of potassium on sulfur resistance in benzene hydrogenation over Ni2Mo3N

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通讯作者: 陈斌, bchen63@163.com

Promoting effect of potassium on sulfur resistance in benzene hydrogenation over Ni₂Mo₃N