Citation: WANG Teng-fei, ZHANG Ye, GE Hui, TANG Ming-xing, ZHOU Li-gong, LÜ Zhan-jun, LI Xue-kuan. Hydrodesulfurization of thiophene over Mo/AC catalyst presulfided by ammonium thiosulfate[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(2): 202-207. shu

Hydrodesulfurization of thiophene over Mo/AC catalyst presulfided by ammonium thiosulfate

WANG Teng-fei ^1,2 ,
ZHANG Ye ^1,, ,
GE Hui ¹ ,
TANG Ming-xing ¹ ,
ZHOU Li-gong ¹ ,
LÜ Zhan-jun ¹ ,
LI Xue-kuan ^1,,

1.
1. Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: ZHANG Ye, LI Xue-kuan,
Received Date: 14 October 2014
Available Online: 15 December 2014
Fund Project: 国家自然科学基金(21473231) (21473231) 中国科学院战略先导专项(XDA07020400)。 (XDA07020400)

Through the impregnation of Mo/AC catalyst with an aqueous solution of ammonium thiosulfate (ATS), the ex-situ presulfided Mo/AC-ATS catalyst was prepared; the influence of activation temperature and time on the catalytic performance in the hydrodesulfurization (HDS) of thiophene as a probe reaction was investigated. The result indicated that under the optimized activation conditions, viz., 300 ℃ and 0.5 h, the conversions of thiophene over the presulfided Mo/AC-ATS catalyst are 34% and 42% higher than those obtained over the Mo/AC catalysts sulfided with traditional DMDS and CS₂ sulfiding agents, respectively. The XPS, TPR-MS and TEM results demonstrated that the presulfided Mo/AC-ATS has a high content of Mo⁴⁺, which may contribute to its high activity in HDS.
- hydrodesulfurization,
- presulfidation,
- ammonium thiosulfate,
- sulfiding agent,
- activiated carbon,
- thiophene
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