Citation: WANG Teng-fei, ZHANG Ye, GE Hui, TANG Ming-xing, ZHOU Li-gong, LÜ Zhan-jun, LI Xue-kuan. Hydrodesulfurization of thiophene over Mo/AC catalyst presulfided by ammonium thiosulfate[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(2): 202-207. shu

Hydrodesulfurization of thiophene over Mo/AC catalyst presulfided by ammonium thiosulfate

WANG Teng-fei ^1,2 ,
ZHANG Ye ^1,, ,
GE Hui ¹ ,
TANG Ming-xing ¹ ,
ZHOU Li-gong ¹ ,
LÜ Zhan-jun ¹ ,
LI Xue-kuan ^1,,

1.
1. Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: ZHANG Ye, LI Xue-kuan,
Received Date: 14 October 2014
Available Online: 15 December 2014
Fund Project: 国家自然科学基金(21473231) (21473231) 中国科学院战略先导专项(XDA07020400)。 (XDA07020400)

Through the impregnation of Mo/AC catalyst with an aqueous solution of ammonium thiosulfate (ATS), the ex-situ presulfided Mo/AC-ATS catalyst was prepared; the influence of activation temperature and time on the catalytic performance in the hydrodesulfurization (HDS) of thiophene as a probe reaction was investigated. The result indicated that under the optimized activation conditions, viz., 300 ℃ and 0.5 h, the conversions of thiophene over the presulfided Mo/AC-ATS catalyst are 34% and 42% higher than those obtained over the Mo/AC catalysts sulfided with traditional DMDS and CS₂ sulfiding agents, respectively. The XPS, TPR-MS and TEM results demonstrated that the presulfided Mo/AC-ATS has a high content of Mo⁴⁺, which may contribute to its high activity in HDS.
- hydrodesulfurization,
- presulfidation,
- ammonium thiosulfate,
- sulfiding agent,
- activiated carbon,
- thiophene
1. [1]
  [1] TOPSOEE H, CLAUSEN B S, TOPSOEE N Y, PEDERSEN E. Recent basic research in hydrodesulfurization catalysis[J]. Ind Eng Chem Fundam, 1986, 25(1): 25-36.
2. [2]
  [2] 石国军, 赵鹬, 黄玉安, 沈俭一. 介孔碳担载的Co-Mo和Ni-Mo加氢脱硫催化剂[J]. 催化学报, 2010, 31(8): 961-964. (SHI Guo-jun, ZHAO Yu, HUANG Yu-an, SHEN Jian-yi. Mesoporous carbon supported Co-Mo and Ni-Mo catalysts for hydrodesulfurization[J]. Chin J Catal, 2010, 31(8): 961-964.)
3. [3]
  [3] HUSSAIN M, SONG S K, LEE J H, IHM S K. Characteristics of CoMo catalysts supported on modified MCM-41 and MCM-48 materials for thiophene hydrodesulfurization[J]. Ind Eng Chem Res, 2006, 45(2): 536-543.
4. [4]
  [4] FARAR H, MOCHIDA I, SAKANISHI K. Fundamental comparison studies on hydrodesulfurization of dibenzothiophenes over CoMo-based carbon and alumina catalysts[J]. Appl Catal A: Gen, 2000, 194: 147-157.
5. [5]
  [5] BREYSSE M, AFANSIEV P, GEANTET C, VRINAT M. Overview of support effects in hydrotreating catalysts[J]. Catal Today, 2003, 86(1): 5-16.
6. [6]
  [6] SILVY R P, GRANGE P, DELANNAY F, DELMON B. Influence of the nature of the activating molecules on the catalytic activity of cobalt-molybdenum/alumina catalysts[J]. Appl Catal, 1989, 46(1): 113-129.
7. [7]
  [7] 李彦鹏, 刘大鹏, 柴永明, 刘晨光. 器外预硫化型MoNiP/γ-Al₂O₃催化剂的喹啉加氢脱氮性能研究[J]. 石油学报, 2007, 22(6): 1-7. (LI Yan-peng, LIU Da-peng, CHAI Yong-ming, LIU Chen-guang. HDS and HDN performance of FCC diesel oil for ex-situ presulfided MoNiP/γ-Al₂O₃ catalyst[J]. Acta Petrol Sin, 2007, 22(6): 1-7.)
8. [8]
  [8] 葛晖, 李学宽, 王国富, 秦张峰, 吕占军, 王建国. 硫代硫酸铵对CoMo和NiMoP催化剂的预硫化[J]. 催化学报, 2010, 31(1): 18-20. (GE Hui, LI Xue-kuan, WANG Guo-fu, QIN Zhang-feng, LV Zhan-jun, WANG Jian-guo. Presulfidation of CoMo and NiMoP catalysts by ammonium thiosulfate[J]. Chin J Catal, 2010, 31(1): 18-20.)
9. [9]
  [9] 葛晖, 李学宽, 王建国, 吕占军, 秦张峰. 硫代硫酸铵预硫化的Mo/Al₂O₃催化剂加氢脱硫反应性能研究[J]. 燃料化学学报, 2009, 37(2): 199-204. (GE Hui, LI Xue-kuan, WANG Jian-guo, LV Zhan-jun, QIN Zhang-feng. Study on hydrodesulfurization of thiophene over Mo/Al₂O₃ catalyst presulfided by thiosulphate ammonium[J]. J Fuel Chem Technol, 2009, 37(2): 199-204.)
10. [10]
  [10] TAN Z L, XIAO H N, ZHANG R D, ZHANG Z S, KALIAGUINE S. Potential to use mesoporous carbon as catalyst support for hydrodesulfurization[J]. New Carbon Mater, 2009, 24(4): 333-343.
11. [11]
  [11] 商红岩, 徐永强, 赵会吉, 刘晨光. 碳纳米管负载的Co-Mo催化剂的 HDS 性能研究[J]. 分子催化, 2004, 18(1): 41-46. (SHANG Hong-yan, XU Yong-qiang, ZHAO Hui-ji, LIU Chen-guang. Study of carbon nanotube supported Co-Mo HDS catalysts[J]. J Mol Catal, 2004, 18(1): 41-46.)
12. [12]
  [12] HUSSAIN M, IHM S K. Synthesis, characterization, and hydrodesulfurization activity of new mesoporous carbon supported transition metal sulfide catalysts[J]. Ind Eng Chem Res, 2008, 48(2): 698-707.
13. [13]
  [13] QIU L M, XU G T. Peak overlaps and corresponding solutions in the X-ray photoelectron spectroscopic study of hydrodesulfurization catalysts[J]. Appl Surf Sci, 2010, 256(11): 3413-3417.
14. [14]
  [14] VISSERS J P R, SCHEFFER B, DE BEER V H J, MOULIJN J A, PRINS R. Effect of the support on the structure of Mo-based hydrodesulfurization catalysts: Activated carbon versus alumina[J]. J Catal, 1987, 105(2): 277-284.
15. [15]
  [15] ARNOLDY P, VAN DEN HEIJKANT J A M, DE BOK G D, MOULIJN J A. Temperature-programmed sulfiding of MoO₃/Al₂O₃ catalysts[J]. J Catal, 1985, 92(1): 35-55.
16. [16]
  [16] CRUZ-REYES J, AVALOS-BORJA M, FARIAS M H, FUENTES S. Hydrodesulfurization catalysts prepared by two methods analyzed by transmission electron microscopy[J]. J Catal, 1992, 137(1): 232-242.
17. [17]
  [17] VAZQUEZ A, YANEZ M J, FUENTES S, AVALOS-BORJA M. High resolution electron microscopy characterization of sulfided palladium particles on amorphous SiO₂[J]. Catal Lett, 1994, 28(2/4): 351-360.
18. [18]
  [18] VRADMAN L, LANDAU M V. Structure-function relations in supported Ni-W sulfide hydrogenation catalysts[J]. Catal Lett, 2001, 77(1/3): 47-54.
19. [19]
  [19] ZHANG L, LONG X, LI D, GAO X D. Study on high-performance unsupported Ni-Mo-W hydrotreating catalyst[J]. Catal Commun, 2011, 12(11): 927-931.
20. [20]
  [20] AFANASIEV P. The influence of reducing and sulfiding conditions on the properties of unsupported MoS₂-based catalysts[J]. J Catal, 2010, 269(2): 269-280.
21. [21]
  [21] TEXIER S, BERHAULT G, PEROT G, DIEHL F. Activation of alumina-supported hydrotreating catalysts by organosulfides or H₂S: Effect of the H₂S partial pressure used during the activation process[J]. Appl Catal A: Gen, 2005, 293: 105-119.
22. [22]
  [22] FARAG H, WHITEHURST D D, MOCHIDA I. Synthesis of active hydrodesulfurization carbon-supported Co-Mo catalysts. Relationships between preparation methods and activity/selectivity[J]. Ind Eng Chem Res, 1998, 37(9): 3533-3539.
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