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Citation: WANG Xia, CHEN Hao, QU Ru-min, ZHANG Lin, YANG Lin-jun. Effects of the coexistent impurities in the flue gas on CO2 separation by membranes[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(1): 100-107. shu

Effects of the coexistent impurities in the flue gas on CO2 separation by membranes

  • 1.

    Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 210096, China

  • Corresponding author: YANG Lin-jun, 
  • Received Date: 21 August 2014
    Available Online: 24 September 2014

    Fund Project: 国家自然科学基金(51176034). (51176034)

  • The effects of coexistent gaseous components and fine particles on the CO2 separation performance by polydimethylsiloxane/polysulfon (PDMS-PSF) flat sheet composite membranes were investigated in a simulated test-bed. It can be found that O2 slightly inhibits the CO2 separation performance, while the effect of SO2 is negligible during the test time due to its low concentration in the flue gas. Water vapor promotes the CO2 separation performance of PDMS-PSF composite membranes. The fly ash fine particles significantly deteriorate the CO2 separation performance of PDMS-PSF membranes. Moreover, the CO2 separation experiments by PDMS-PSF membranes with an actual flue gas from a desulfurization system of the coal-fired hot testing facility were conducted for 50 h. At the beginning, the CO2 separation performance is slightly improved due to the combined effect of water vapor, O2 and SO2. With the extension of the test time, the impact of the fine particles deposited on the membrane surface increases, which gradually deteriorates the CO2 separation performance of PDMS-PSF membrane. The CO2/N2 selectivity and the CO2 permeation rate are decreased by 17.91% and 28.21%, respectively.
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    1. [1]

      [1] 刘之琳, 滕阳, 张锴, 曹晏, 潘伟平. 不同有机胺修饰MCM-41的CO2吸附性能和热稳定性[J]. 燃料化学学报, 2013, 41(4): 469-476.(LIU Zhi-lin, TENG Yang, ZHANG Kai, CAO Yan, PAN Wei-ping. CO2 adsorption properties and thermal stability of different amine-impregnated MCM-41 materials[J]. J Fuel Chem Technol, 2013, 41(4): 469-476.)

    2. [2]

      [2] LOW B T, ZHAO L, MERKEL T C, WEBER M, STOLTEN D. A parametric study of the impact of membrane materials and process operating conditions on carbon capture from humidified flue gas[J]. J Membr Sci, 2013, 431: 139-155.

    3. [3]

      [3] 谭喆, 周勇, 高从堦. 优先渗透CO2的膜材料研究进展[J]. 膜科学与技术, 2014, 34(1): 121-128.(TAN Zhe, ZHOU Yong, GAO Cong-jie. Progress of research on membrane materials for CO2-selective separation[J]. Membr Sci Technol, 2014, 34(1): 121-128.)

    4. [4]

      [4] AHMAD F, LAU K K, SHARIFF A M, MURSHID G. Process simulation and optimal design of membrane separation system for CO2 capture from natural gas[J]. Comput Chem Eng, 2012, 36: 119-128.

    5. [5]

      [5] ISMAIL A F, YAACOB N. Performance of treated and untreated asymmetric polysulfone hollow fiber membrane in series and cascade module configurations for CO2/CH4 gas separation system[J]. J Membr Sci, 2006, 275(1): 151-165.

    6. [6]

      [6] 马莎莎, 陈泽智, 龚慧娟, 虞辉, 余珉, 王梦秋, 樊杨梅. 聚壳糖/聚砜复合中空纤维膜的制备及其CO2/N2分离性能研究[J]. 现代化工, 2013, 33(6): 50-53.(MA Sha-sha, CHEN Ze-zhi, GONG Hui-juan, YU Hui, YU Min, WANG Meng-qiu, FAN Yang-mei. Preparation of chitosan/polysulfon hollow fiber composite membranes and its CO2/N2 permeation properties[J]. Mod Chem Ind, 2013, 33(6): 50-53.)

    7. [7]

      [7] PAKIZEH M, MANSOORI S A A, CHENAR M P, MAHBOUB M N. Modification of PSf membrane nanostructure using different fabrication parameters and investigation of the CO2 separation properties of PDMS-coated PSf composite membranes[J]. Braz J Chem Eng, 2013, 30(2): 345-354.

    8. [8]

      [8] THUNDYIL M J, JOIS Y H, KOROS W J. Effect of permeate pressure on the mixed gas permeation of carbon dioxide and methane in a glassy polyimide[J]. J Membr Sci, 1999, 152(1): 29-40.

    9. [9]

      [9] SCHOLES C A, STEVENS G W, KENTISH S E. Permeation through CO2 selective glassy polymeric membranes in the presence of hydrogen sulfide[J]. AlChE J, 2012, 58(3): 967-973.

    10. [10]

      [10] SCHOLES C A, KENTISH S E, STEVENS G W. The effect of condensable minor components on the gas separation performance of polymeric membranes for carbon dioxide capture[J]. Energy Procedia, 2009, 1(1): 311-317.

    11. [11]

      [11] KIM T J, UDDIN M W, SANDRU M, HÄGG M B. The effect of contaminants on the composite membranes for CO2 separation and challenges in up-scaling of the membranes[J]. Energy Procedia, 2011, 4: 737-744.

    12. [12]

      [12] ANDERSON C J, TAO W, SCHOLES C A, STEVENS G W, KENTISH S E. The performance of carbon membranes in the presence of condensable and non-condensable impurities[J]. J Membr Sci, 2011, 378(1/2): 117-127.

    13. [13]

      [13] BRANDS K, UHLMANN D, SMART S, BRAM M, DINIZ DA COSTA J C. Long-term flue gas exposure effects of silica membranes on porous steel substrate[J]. J Membr Sci, 2010, 359(1): 110-114.

    14. [14]

      [14] BRAM M, BRANDS K, DEMEUSY T, ZHAO L, MEULENBERG W A, PAULS J, GÖTTLICHER G, PEINEMANN K V, SMART S, BUCHKREMER H P, STÖVER D. Testing of nanostructured gas separation membranes in the flue gas of a post-combustion power plant[J]. Int J Greenh Gas Control, 2011, 5(1): 37-48.

    15. [15]

      [15] 王学松. 气体膜技术[M]. 北京: 化学工业出版社, 2010.(WANG Xue-song. Membrane technologies for gas separation[M]. Beijing: Chemical Industry Press, 2010.)

    16. [16]

      [16] SCHOLES C A, KENTISH S E, STEVENS G W. Effects of minor components in carbon dioxide capture using polymerics gas separation membranes[J]. Sep Purif Rev, 2009, 38(1): 1-44.

    17. [17]

      [17] 陈勇, 王从厚, 吴鸣. 气体膜分离技术与应用[M]. 北京: 化学工业出版社, 2004.(CHEN Yong, WANG Cong-hou, WU Ming. Membrane technologies and applications for gas separation[M]. Beijing: Chemical Industry Press, 2004.)

    18. [18]

      [18] 何宏舟, 骆仲泱, 王勤辉, 岑可法. 燃烧福建无烟煤的循环流化床锅炉飞灰及其未燃炭分析[J]. 燃料化学学报, 2006, 34(3): 285-291.(HE Hong-zhou, LUO Zhong-yang, WANG Qin-hui, CEN Ke-fa. Characterization of fly ash and unburned carbon from CFB boiler with burning Fujian anthracite[J]. J Fuel Chem Technol, 2006, 34(3): 285-291.)

    19. [19]

      [19] 殷立宝, 高正阳, 徐齐胜, 郑双清, 钟俊, 陈传敏. 燃煤电站锅炉颗粒Hg形态及其释放动力学参数[J]. 燃料化学学报, 2013, 41(12): 1451-1458.(YIN Li-bao, GAO Zheng-yang, XU Qi-sheng, ZHENG Shuang-qing, ZHONG Jun, CHEN Chuan-min. Analysis of species and thermal stability of particulate-bound mercury in coal-fired boiler[J]. J Fuel Chem Technol, 2013, 41(12): 1451-1458.)

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