Citation: DAI Nan, YANG Zhen, HUANG Yao-bing, FU Yao. Preparation of liquid fuel from lignin phenolic monomers[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(1): 48-53. shu

Preparation of liquid fuel from lignin phenolic monomers

DAI Nan ^1,2 ,
YANG Zhen ¹ ,
HUANG Yao-bing ¹ ,
FU Yao ^1,2,,

1.
1. Department of Chemistry, Anhui Province Key Laboratory of Biomass Clean Energy, University of Science and Technology of China, Hefei 230026, China;

Corresponding author: FU Yao,
Received Date: 30 June 2014
Available Online: 27 September 2014
Fund Project: 国家重点基础研究发展规划(973计划, 2012CB215306,2013CB228103) (973计划, 2012CB215306,2013CB228103) 国家自然科学基金(21325208,21361140372,21172209) (21325208,21361140372,21172209) 教育部中央高校基本科研业务费专项(WK2060190025) (WK2060190025) 高等学校博士点基金(20123402130008) (20123402130008)中国科学院基金(KJSTBZ2-EW-J02) (KJSTBZ2-EW-J02)

Long-chain alkanes fuel were produced from lignin deploymerization model compounds by introducing small intermediate molecules through Friedel-Crafts alkylation and subsequent hydrogenation. The effect of catalyst, small intermediate molecules, temperature, reaction time, feed mixture ratio, and raw materials on the conversion of the lignin phenolic monomers to dimmers was investigated; after that, the C_13~19 alkanes fuel was obtained by hydrogenating the lignin phenolic dimers. The results showed that over Amberlyst-15 catalyst, with a n(guaiacol)/n(small intermediate molecules) ratio of 15:3, after reaction under 100 ℃ for 24 h, the yield of lignin phenolic dimers products reaches 68%; the lignin phenolic dimers can be further converted to alkanes completely through hydrogenation. Such a route for producing long-chain fuel may provide a new alternative for the utilization of lignin.
- lignin,
- guaiacol,
- Friedel-Crafts alkylation,
- alkanes fuel
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