Advanced Search

Citation: WANG Jian, FENG Ming, ZHANG Hai-jie, XU Xiu-feng. Catalytic decomposition of N2O over Mg-Fe mixed oxides[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(12): 1464-1469. shu

Catalytic decomposition of N2O over Mg-Fe mixed oxides

  • 1.

    Institute of Applied Catalysis, Yantai University, Yantai 264005, China

  • Corresponding author: XU Xiu-feng, 
  • Received Date: 15 August 2014
    Available Online: 30 October 2014

    Fund Project: Supported by the Research Project from Department of Science and Technology of Shandong Province (2012GSF11708) (2012GSF11708)

  • A series of MgxFe1-xFe2O4 spinel oxides were prepared and characterized by means of nitrogen physisorption, X-ray diffraction (XRD) and temperature-programmed reduction of hydrogen (H2-TPR). The effect of composition, calcination temperature, and potassium doping on the catalytic activity of the Mg-Fe mixed oxides in N2O decomposition was investigated. The results indicated that the Mg0.6Fe0.4Fe2O4 catalyst calcined at 500 ℃ exhibits highest activity in N2O decomposition. Unexpectedly, the catalyst activity is depressed by the addition of potassium, as the potassium doping may inhibit the reduction of surface iron oxides and reduce the surface area of K-modified catalysts. Long-term tests at 500 ℃ for 10 h also illustrate that Mg0.6Fe0.4Fe2O4 is superior to FeOx catalyst either in the oxygen-alone or in the oxygen-steam concomitant atmosphere.
  • 加载中
    1. [1]

      [1] KOVANDA F, ROJKA T, BEZDICKA P, JIRATOVA K, OBALOVA L, PACULTOVA K, BASTL Z, GRYGAR T. Effect of hydrothermal treatment on properties of Ni-Al layered double hydroxides and related mixed oxides[J]. J Solid State Chem, 2009, 182(1): 27-36.

    2. [2]

      [2] 武海鹏, 钱振英, 徐晓玲, 徐秀峰. K改性NiAl类水滑石衍生复合氧化物催化分解N2O[J]. 燃料化学学报, 2011, 39(2): 115-121. (WU Hai-peng, QIAN Zhen-ying, XU Xiao-ling, XU Xiu-feng. N2O decomposition over K-promoted NiAl mixed oxides derived from hydrotalcite-like compounds[J]. Journal of Fuel Chemistry and Technology, 2011, 39(2): 115-121.)

    3. [3]

      [3] 潘燕飞, 冯鸣, 崔仙, 徐秀峰. 有氧气氛中碱金属改性CuAl复合氧化物催化分解N2O的活性[J]. 燃料化学学报, 2012, 40(5): 601-607. (PAN Yan-fei, FENG Ming, CUI Xian, XU Xiu-feng. Catalytic activity of alkali metal doped Cu-Al mixed oxides for N2O decomposition in the presence of oxygen[J]. Journal of Fuel Chemistry and Technology, 2012, 40(5): 601-607.)

    4. [4]

      [4] YAN L, REN T, WANG X L, JI D, SUO J S. Catalytic decomposition of N2O over MxCo1-xCo2O4 (M=Ni, Mg) spinel oxides[J]. Appl Catal B: Environ, 2003, 45(2): 85-90.

    5. [5]

      [5] YAN L, REN T, WANG X L, GAO Q, JI D, SUO J S. Excellent catalytic performance of ZnxCo1-xCo2O4 spinel catalysts for the decomposition of nitrous oxide[J]. Catal Commun, 2003, 4(10): 505-509.

    6. [6]

      [6] 窦喆, 张海杰, 潘燕飞, 徐秀峰. N2O在钾改性Cu-Co尖晶石型复合氧化物上的催化分解[J]. 燃料化学学报, 2014, 42(2): 238-245. (DOU Zhe, ZHANG Hai-jie, PAN Yan-fei, XU Xiu-feng. Catalytic decomposition of N2O over potassium-modified Cu-Co spinel oxides[J]. Journal of Fuel Chemistry and Technology, 2014, 42(2): 238-245.)

    7. [7]

      [7] AMROUSSE R, KATSUMI T. Substituted ferrite MxFe1-xFe2O4 (M=Mn, Zn) catalysts for N2O catalytic decomposition processes[J]. Catal Commun, 2012, 26: 194-198.

    8. [8]

      [8] AMROUSSE R, TSUTSUMI A, BACHAR A, LAHCENE D. N2O catalytic decomposition over nano-sized particles of Co-substituted Fe3O4 substrates[J]. Appl Catal A: Gen, 2013, 450: 253-260.

    9. [9]

      [9] CHENG H K, HUANG Y Q, WANG A Q, LI L, WANG X D, ZHANG T. N2O decomposition over K-promoted Co-Al catalysts prepared from hydrotalcite-like precursors[J]. Appl Catal B: Environ, 2009, 89(3/4): 391-397.

    10. [10]

      [10] STELMACHOWSKI P, MANIAK G, KOTARBA A, SOJKA Z. Strong electronic promotion of Co3O4 towards N2O decomposition by surface alkali dopants[J]. Catal Commun, 2009, 10(7): 1062-1065.

    11. [11]

      [11] PASHA N, LINGAIAH N, REDDY P S S, PRASAD P S S. Direct decomposition of N2O over cesium-doped CuO catalysts[J]. Catal Lett, 2009, 127(1/2): 101-106.

    12. [12]

      [12] OBALOVÁ L, KARÁSKOVÁ K, JIRÁTOVÁ K, KOVANDA F. Effect of potassium in calcined Co-Mn-Al layered double hydroxide on the catalytic decomposition of N2O[J]. Appl Catal B: Environ, 2009, 90(1/2): 132-140.

    13. [13]

      [13] OBALOVÁ L, MANIAK G, KARÁSKOVÁ K, KOVANDA F, KOTARBA A. Electronic nature of potassium promotion effect in Co-Mn-Al mixed oxide on the catalytic decomposition of N2O[J]. Catal Commun, 2011, 12(12): 1055-1058.

    14. [14]

      [14] 冯鸣, 窦喆, 徐秀峰. Zn-Fe尖晶石型复合氧化物催化分解N2O[J]. 燃料化学学报, 2013, 41(6): 729-734. (FENG Ming, DOU Zhe, XU Xiu-feng. Catalytic decomposition of N2O over Zn-Fe spinel oxides[J]. Journal of Fuel Chemistry and Technology, 2013, 41(6): 729-734.)

  • 加载中
    1. [1]

      Xueqi Yang ,  Juntao Zhao ,  Jiawei Ye ,  Desen Zhou ,  Tingmin Di ,  Jun Zhang . 调节NNU-55(Fe)的d带中心以增强CO2吸附和光催化活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-. doi: 10.1016/j.actphy.2025.100074

    2. [2]

      Wei Zhong ,  Dan Zheng ,  Yuanxin Ou ,  Aiyun Meng ,  Yaorong Su . K原子掺杂高度面间结晶的g-C3N4光催化剂及其高效H2O2光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005

    3. [3]

      Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi2O3 pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256

    4. [4]

      Xuejiao Wang ,  Suiying Dong ,  Kezhen Qi ,  Vadim Popkov ,  Xianglin Xiang . Photocatalytic CO2 Reduction by Modified g-C3N4. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005

    5. [5]

      Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

    6. [6]

      Lina Guo ,  Ruizhe Li ,  Chuang Sun ,  Xiaoli Luo ,  Yiqiu Shi ,  Hong Yuan ,  Shuxin Ouyang ,  Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al2O3催化剂光热催化CO2甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002

    7. [7]

      Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO2 hydrogenation over a Mg-doped In2O3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421

    8. [8]

      Qin Hu ,  Liuyun Chen ,  Xinling Xie ,  Zuzeng Qin ,  Hongbing Ji ,  Tongming Su . Ni掺杂构建电子桥及激活MoS2惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024

    9. [9]

      Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

    10. [10]

      Yadan Luo ,  Hao Zheng ,  Xin Li ,  Fengmin Li ,  Hua Tang ,  Xilin She . Modulating reactive oxygen species in O, S co-doped C3N4 to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-. doi: 10.1016/j.actphy.2025.100052

    11. [11]

      Guoqiang Chen ,  Zixuan Zheng ,  Wei Zhong ,  Guohong Wang ,  Xinhe Wu . 熔融中间体运输导向合成富氨基g-C3N4纳米片用于高效光催化产H2O2. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021

    12. [12]

      Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369

    13. [13]

      Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469

    14. [14]

      Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014

    15. [15]

      Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO2 cycloaddition over W18O49/NH2-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349

    16. [16]

      Yu Wang ,  Haiyang Shi ,  Zihan Chen ,  Feng Chen ,  Ping Wang ,  Xuefei Wang . 具有富电子Ptδ-壳层的空心AgPt@Pt核壳催化剂：提升光催化H2O2生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-. doi: 10.1016/j.actphy.2025.100081

    17. [17]

      Yi Yang ,  Xin Zhou ,  Miaoli Gu ,  Bei Cheng ,  Zhen Wu ,  Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn2S4 photocatalyst for H2O2 production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-. doi: 10.1016/j.actphy.2025.100064

    18. [18]

      Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V2O5/TiO2 catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210

    19. [19]

      Heng Chen ,  Longhui Nie ,  Kai Xu ,  Yiqiong Yang ,  Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C3N4纳米片及其高效光催化产H2O2. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019

    20. [20]

      Xin Han ,  Zhihao Cheng ,  Jinfeng Zhang ,  Jie Liu ,  Cheng Zhong ,  Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(323)
  • HTML views(3)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return