Citation: LIN Xing-yi, ZHANG Yong, LI Ru-le, ZHAN Ying-ying, CHEN Chong-qi, YIN Ling. Catalytic properties of ZnO-modified copper ferrite catalysts in water-gas shift reaction[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(11): 1351-1356. shu

Catalytic properties of ZnO-modified copper ferrite catalysts in water-gas shift reaction

1.
National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou 350002, China

Corresponding author: LIN Xing-yi,
Received Date: 7 August 2014
Available Online: 16 September 2014
Fund Project:

The catalytic properties of ZnO-modified copper ferrite in water-gas shift (WGS) reaction were evaluated between 250 and 400 ℃. The Zn2.5-Cu/Fe (modified by 2.5% ZnO) showed high catalytic activity. The catalyst was characterized with XRD, SEM, H₂-TPR and CO₂-TPD techniques and N₂ sorption experiment. It was shown that introduction of appropriate amounts of ZnO transformed the CuFe₂O₄ from the tetrahedral crystalline phase to the cubic, enhanced the CuFe₂O₄ reducibility, and increased the amount of weak and medium basic sites. As a consequence, the interaction between copper and iron species was improved and the catalytic activity was increased.
- WGS reaction,
- copper ferrite,
- ZnO modification,
- reducibility,
- basicity
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沈阳化工大学材料科学与工程学院沈阳 110142