Citation: BAI Jing-ru, CHEN Ding-xing, ZHANG Wei, WANG Qing, LI Ming-ming. Mode of occurrences of trace elements in oil shale[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(11): 1295-1301. shu

Mode of occurrences of trace elements in oil shale

1.
1. Engineering Research Centre of Ministry of Education for Comprehensive Utilization of Oil Shale, Northeast Dianli University, Jilin 132012, China;

Corresponding author: BAI Jing-ru,
Received Date: 10 June 2014
Available Online: 15 August 2014
Fund Project: 吉林省自然科学基金(201215163) (201215163) 吉林省教育厅"十二五"科学技术研究项目(2012-98). (2012-98)

The occurrences of trace elements in Fushun, Longkou and Maoming oil shale samples were determined using float-sink test and demineralization. The results of float sink test are consistent with that from demineralization. Most trace elements occur in inorganic mineral, but there are still some differences among the 3 oil shales. The trace elements of V, Mn, Zn, Sr, Mo, Ta, Cd are found in the samples. Cr, Te in Fushun, Cd, Sn in Longkou, and Cd, Sn, Pb in Maoming are primarily associated with mineral matters. The trace elements of Cr, Te in Maoming, Cd in Fushun, and Pb in Longkou oil shale samples are primarily associated with organic mineral. Part of Co, Sn, Pb in Fushun, Co in Longkou and Maoming oil shale samples are associated with organic mineral, while most of them are associated with clay mineral.
- oil shale,
- trace elements,
- mode of occurrence,
- float-sink test,
- demineralization
1. [1]
  [1] MIURA K, MAE K, ASHIDA R, TAMURA T, IHARA T. Dewatering of coal through solvent extraction[J]. Fuel, 2002, 81(11/12): 1417-1422.
2. [2]
  [2] 熊楚安, 王永刚, 许德平. 中国直接液化油煤浆及液化残渣流变特性研究进展[J]. 化工进展, 2009, 28(4): 597-604.(XIONG Chu-an, WANG Yong-gang, XU De-ping. Development of rheological properties of Chinese coal-oil slurry and liquefaction residue in direct liquefaction[J]. Chemical Industry and Engineering Process, 2009, 28(4): 597-604.)
3. [3]
  [3] MUNRO J M, LEWELLYN M M, CRACKEL P R, BAUER L G. Characterization of the rheological properties of coal-fuel oil slurries[J]. AIChe J, 1979, 25(2): 355-358.
4. [4]
  [4] GRINT A, VEAL C J. Effect of fuel-oil source on the preparation of coal oil dispersions[J]. Fuel, 1985, 64(8): 1079-1084.
5. [5]
  [5] OGDEN I K, RUTTER P R. The sedimentation stability and viscosity of coal oil dispersions[J]. Colloid Surface, 1984, 8(3): 249-259.
6. [6]
  [6] JOHNSON G R, RUTTER P R. The effect of fuel-oil chemistry on the stability of coal-oil dispersions[J]. Colloid Surf, 1985, 16(2): 103-116.
7. [7]
  [7] SAKAKI T, SHIBATA M, HIROSUE H. Effect of coal rank on rheological behavior of coal solvent slurries during heating[J]. Energy Fuels, 1995, 9(2): 314-318.
8. [8]
  [8] TSUTSUMI A, YOSHIDA K. Rheological behavior of coal-solvent slurries[J]. Fuel, 1986, 65(7): 906-909.
9. [9]
  [9] OKUTANI T, YOKOYAMA S, MAEKAWA Y. Viscosity changes in coal paste during hydrogenation[J]. Fuel, 1984, 63(2): 164-168.
10. [10]
  [10] KOU J W, BAI Z Q, LI W, BAI J, GUO Z X. Effects of mineral matters and hydrogen bonding on rheological behaviors of brown coal-oil slurries[J]. Fuel, 2014, 132: 187-193.
11. [11]
  [11] SONG C S, SAINI A K, MCCONNIE J. Strong promoting effect of H₂O on coal liquefaction using water-soluble and oil-soluable mo catalyst precursors[D]. Oviedu, Spain: Int Energy Agcy, 1995.
12. [12]
  [12] SONG C S, SAINI A K, SCHOBERT H H. Enhancing low-severity catalytic liquefaction of low-rank coal by adding water[J]. Fuel, 1993, 206: 1031-1038.
13. [13]
  [13] 王永刚, 陈伟, 丁一慧, 郝丽芳, 许德平. 溶剂和水分对液化油煤浆流变性质的影响[J]. 煤炭学报, 2009, 34(1): 100-104.(WANG Yong-gang, CHEN Wei, DING Yi-hui, HAO Li-fang, XU De-ping. Effect of solvent and moisture on rheological property of oil-coal slurry[J]. Journal of China Coal Society, 2009, 34(1): 100-104.)
14. [14]
  [14] ADIGA K C, PITHAPURWALA Y K, SHAH D O, MOUDGIL B M. Rheology of coal slurries in no.2 oil and ethanol blends: Effect of water[J]. Rheologica Acta, 1983, 22(4): 402-409.
15. [15]
  [15] FENG P, HAO L F, HUO C F, WANG Z, LIN W G, SONG W L. Rheological behavior of coal bio-oil slurries[J]. Energy, 2014, 66: 744-749.
16. [16]
  [16] YANG X L, LI Y F, ZHANG X W, HU S Q. Supportvectorregression on near-infrared spectra analysis for moisture determination in lignitic coal samples[D]. Taiwan, China: Chung Hua University, 2013.
17. [17]
  [17] 熊程程. 褐煤干燥过程的实验研究及动力学分析[D]. 北京: 中国科学院工程热物理研究所, 2011.(XIONG Cheng-cheng. Experimental study and kinetic analysis of lignite drying[D]. Beijing: Institute of Engineering Thermophysics, Chinese Academy of Sciences, 2011.)
18. [18]
  [18] LOW G S, BHATTACHARYA S N. The effect of moisture on the rheology of brown coal-oil suspensions[J]. Can J Chem Eng, 1983, 61(6): 785-790.
19. [19]
  [19] 史士东. 煤加氢液化工程学基础[M]. 北京: 化学工业出版社, 2012.(SHI Shi-dong. Coal hydrogenation liquefaction of foundation engineering[M]. Beijing: Chemical Industry Press, 2012.)
1. [1]
  Pingping Zhu , Yongjun Xie , Yuanping Yi , Yu Huang , Qiang Zhou , Shiyan Xiao , Haiyang Yang , Pingsheng He . Excavation and Extraction of Ideological and Political Elements for the Virtual Simulation Experiments at Molecular Level: Taking the Project “the Simulation and Computation of Conformation, Morphology and Dimensions of Polymer Chains” as an Example. University Chemistry, 2024, 39(2): 83-88. doi: 10.3866/PKU.DXHX202309063
2. [2]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
3. [3]
  Kun Li , Na Gao , Shuangyan Huan , Yuzhi Wang . Design of Ideological and Political Education for the Experiment of Detecting Cadmium with Anodic Stripping Voltammetry. University Chemistry, 2024, 39(2): 155-161. doi: 10.3866/PKU.DXHX202307068
4. [4]
  Yan Li , Fei Ding , Jing Wang , Jing Nan , Yijun Li , Xiaohang Qiu . Give a Man a Fish, and Teach a Man to Fish: Self-Designed Instrumental Analysis Experiments and Integration of Ideological and Political Elements. University Chemistry, 2024, 39(2): 208-213. doi: 10.3866/PKU.DXHX202310097
5. [5]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
6. [6]
  Siyao Zhan , Yajiao Wang , Zhihuan Cai , Ayizhada Maimaitiyumier , Tilan Duan , Xiangfeng Wei , Qi Wang , Jiehua Liu , Xianghua Kong . Exploration of the Chemical Elements across Time and Space. University Chemistry, 2024, 39(9): 5-10. doi: 10.12461/PKU.DXHX202403071
7. [7]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
8. [8]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
9. [9]
  Zhongyan Cao , Youzhi Xu , Menghua Li , Xiao Xiao , Xianqiang Kong , Deyun Qian . Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes. University Chemistry, 2025, 40(4): 277-281. doi: 10.12461/PKU.DXHX202407017
10. [10]
  Mengyao Shi , Kangle Su , Qingming Lu , Bin Zhang , Xiaowen Xu . Determination of Potassium Content in Tobacco Stem Ash by Flame Atomic Absorption Spectroscopy. University Chemistry, 2024, 39(10): 255-260. doi: 10.12461/PKU.DXHX202404105
11. [11]
  Xiangli Wang , Yuanfu Deng . Teaching Design of Elemental Chemistry from the Perspective of “Curriculum Ideology and Politics”: Taking Arsenic as an Example. University Chemistry, 2024, 39(2): 270-279. doi: 10.3866/PKU.DXHX202308092
12. [12]
  Wei Shao , Wanqun Zhang , Pingping Zhu , Wanqun Hu , Qiang Zhou , Weiwei Li , Kaiping Yang , Xisheng Wang . Design and Practice of Ideological and Political Cases in the Course of Instrument Analysis Experiment: Taking the GC-MS Experiment as an Example. University Chemistry, 2024, 39(2): 147-154. doi: 10.3866/PKU.DXHX202309048
13. [13]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
14. [14]
  Zongpei Zhang , Yanyang Li , Yanan Si , Kai Li , Shuangquan Zang . Developing a Chemistry Experiment Center Employing a Multifaceted Approach to Serve High-Quality Laboratory Education. University Chemistry, 2024, 39(7): 13-19. doi: 10.12461/PKU.DXHX202404041
15. [15]
  Wei Yan , Cailing Wang , Li Wang , Yonghai Song . Promoting the Reform of Basic Chemistry Experimental Courses through Laboratory Skill Competition. University Chemistry, 2024, 39(10): 189-194. doi: 10.3866/PKU.DXHX202403042
16. [16]
  Yan Liu , Xiaojun Han , Ping Xu , Guoxu Zhang , Yu Wang , Zhicheng Zhang , Dianpeng Qi . “Five Measures” Based Science and Education Integration Experimental Teaching Mode to Promote the Construction of “Specialized Experiment” Curriculum. University Chemistry, 2024, 39(10): 299-307. doi: 10.12461/PKU.DXHX202405002
17. [17]
  Kejie Li , Dongmei Qi . Exploration and Practice of Traditional Chinese Medicine Chemistry Laboratory Management Based on the “Smart Laboratory”. University Chemistry, 2024, 39(10): 353-360. doi: 10.12461/PKU.DXHX202406080
18. [18]
  Houzhen Xiao , Mingyu Wang , Yong Liu , Bangsheng Lao , Lingbin Lu , Minghuai Yu . Course Ideological and Political Design of Combustion Heat Measurement Experiment. University Chemistry, 2024, 39(2): 7-13. doi: 10.3866/PKU.DXHX202310011
19. [19]
  Yuan Chun , Lijun Yang , Jinyue Yang , Wei Gao . Ideological and Political Design of BZ Oscillatory Reaction Experiment. University Chemistry, 2024, 39(2): 72-76. doi: 10.3866/PKU.DXHX202308072
20. [20]
  Mei Yan , Rida Feng , Yerdos·Tohtarkhan , Biao Long , Li Zhou , Chongshen Guo . Expansion and Extension of Liquid Saturated Vapor Measurement Experiment. University Chemistry, 2024, 39(3): 294-301. doi: 10.3866/PKU.DXHX202308103

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(388)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142