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Citation: LIU Ji, WANG Dong-xu, XIAO Xian-bin, CHEN Xu-jiao, QIN Wu, DONG Chang-qing. Effect of calcination temperature on Ni/γ-Al2O3 reduction and catalytic steam reforming of toluene[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(10): 1225-1232. shu

Effect of calcination temperature on Ni/γ-Al2O3 reduction and catalytic steam reforming of toluene

  • 1.

    National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, Beijing 102206, China

  • Corresponding author: XIAO Xian-bin, 
  • Received Date: 11 May 2014
    Available Online: 19 July 2014

    Fund Project: 国家自然科学基金(51206050) (51206050) 教育部高等学校博士学科点专项科研基金(20120036120008)。 (20120036120008)

  • The influence of calcination temperature on Ni/γ-Al2O3 reducing conditions and catalytic steam reforming of toluene was studied. The results indicate that the catalyst calcined at 700 ℃ showed good catalytic performance at reaction temperature of 680 ℃ and maintained a high catalytic activity, stability without pre-reduction and 99% of toluene conversion was obtained under optimum conditions. The catalysts were also characterized by BET, XRD, TG-DTG and other techniques before and after reaction. As the calcination temperature was raised, the interaction between nickel and carrier was gradually enhanced, surface area and total pore volume decreased, and amount of NiAl2O4 in the catalyst increased. These are considered the main reasons for the effect of calcination temperature on the catalyst reduction conditions. Finally, the structure of the catalyst calcined at 700 ℃ is further analyzed using TEM, XPS.
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