Citation: GENG Rui, DONG Mei, WANG Hao, NIU Xian-jun, FAN Wei-bin, WANG Jian-guo, QIN Zhang-feng. An investigation on the catalytic performance of 10 MR zeolites in methanol aromatization reaction[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(9): 1119-1127. shu

An investigation on the catalytic performance of 10 MR zeolites in methanol aromatization reaction

GENG Rui ^1,2 ,
DONG Mei ^1,, ,
WANG Hao ¹ ,
NIU Xian-jun ^1,2 ,
FAN Wei-bin ^1,, ,
WANG Jian-guo ¹ ,
QIN Zhang-feng ¹

1.
1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: DONG Mei, FAN Wei-bin,
Received Date: 17 January 2014
Available Online: 5 March 2014
Fund Project: 国家自然科学基金(21103216,21273264,21273263) (21103216,21273264,21273263)国家重点基础研究发展规划(973计划,2011CB201403) (973计划,2011CB201403)山西省自然科学基金(2012011005-2)。 (2012011005-2)

Five zeolites ZSM-5, ZSM-22, EU-1, MCM-22, and ITQ-13 with 10 member ring channels were hydrothermally synthesized and their structure, acidity, morphology and catalytic behaviors in methanol aromatization reaction were compared. The results indicate that the morphology, microporous volumes, and physicochemical properties of the zeolites differ significantly from each other, and thus results in considerable influence on the catalytic activity and stability. Among the five zeolites studied, ZSM-5 shows the highest aromatic yield of 34.8%, followed by MCM-22 with the aromatic yield of 21.9%. However, unlike ZSM-5 and MCM-22, the other three catalysts are inactivitive for methanol aromatization. The introduction of Ga species into ZSM-5 and MCM-22, however, can improve the aromatic yield significantly. The aromatic yields on Ga/ZSM-5 and Ga/MCM-22 reach 40.8% and 27.1%, respectively. The TG/DTA and GC analyses of the coke compounds deposited on the deactivated catalysts suggest that the five zeolites display much differences in composition, location and distribution of coke deposition.
- methanol aromatization,
- 10 MR zeolites,
- ZSM-5,
- ZSM-22,
- EU-1,
- MCM-22,
- ITQ-13,
- coke deposition
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