Advanced Search

Citation: CAO Jian, ZHU Hua-qing, WANG Hui, HUANG Li-zhi, QIN Zhang-feng, FAN Wei-bin, WANG Jian-guo. Synthesis of polyoxymethylene dimethyl ethers over zeolite catalysts[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(8): 986-993. shu

Synthesis of polyoxymethylene dimethyl ethers over zeolite catalysts

  • 1.

    1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

  • Corresponding author: ZHU Hua-qing,  FAN Wei-bin, 
  • Received Date: 27 January 2014
    Available Online: 11 April 2014

    Fund Project: 国家自然科学基金(21273264) (21273264)国家重点基础研究发展规划(973计划,2011CB201403,2011CB201406)。 (973计划,2011CB201403,2011CB201406)

  • Synthesis of polyoxymethylene dimethyl ethers was carried out on HMCM-22, Al-YNU-1 and MOR zeolites by the condensation of trioxane and methanol or methylal. The crystal structures and surface acidity of the catalysts were characterized by XRD, SEM and NH3-TPD. It was found that DMM2~8 selectivity was influenced by the acid strength and density of zeolites and reaction conditions. HMCM-22 showed much higher selectivity to DMM2~8 than Al-YNU-1 and MOR. Under the optimal conditions, the DMM2~8 selectivity reached 65.1% and 90.6% in ME/TRIox and DMM/TRIox systems respectively. It was shown that the moderately strong acid sites were probably responsible for the formation of long chain DMMn, while the strong acid sites werefor DMM.
  • 加载中
    1. [1]

      [1] 雷艳华, 孙清, 陈兆旭, 沈俭一. 合成聚甲醛二甲基醚反应热力学的理论计算[J]. 化学学报, 2009, 67(8): 767-772. (LEI Yan-hua, SUN Qing, CHEN Zhao-xu, SHEN Jian-yi. Theoretical calculations on the thermodynamics for the synthesis reactions of polyoxymethylene dimethyl ethers[J]. Acta Chimica Sinica, 2009, 67(8): 767-772.)

    2. [2]

      [2] ARVIDSON M, FAKLEY M E, SPENCER M S. Lithium halide-assisted formation of polyoxymethylene dimethyl ethers from dimethoxymethane and formaldehyde[J]. J Mol Catal, 1987, 41(2): 39l-393.

    3. [3]

      [3] BURGER J, SIEGERT M, STROFER E, HASSE H. Poly(oxymethylene) dimethyl ethers as components of tailored diesel fuel: Properties, synthesis and purification concepts[J]. Fuel, 2010, 89(11): 3315-3319.

    4. [4]

      [4] 赵启, 王辉, 秦张峰, 吴志伟, 武建兵, 樊卫斌, 王建国. 分子筛催化剂上甲醇与三聚甲醛缩合制聚甲氧基二甲醚[J]. 燃料化学学报, 2011, 39(12): 918-923. (ZHAO Qi, WANG Hui, QIN Zhang-feng, WU Zhi-wei, WU Jian-bing, FAN Wei-bin, WANG Jian-guo. Synthesis of polyoxymethylene dimethyl ethers from methanol and trioxymethylene with molecular sieves as catalysts[J]. Journal of Fuel Chemistry and Technology, 2011, 39(12): 918-923.)

    5. [5]

      [5] FLEISCH T H, SILLS R A. Beyond GTL-FT: Large-scale gas conversion through oxygenates[J]. Stud Surf Sci Catal, 2004, 147(1): 31-36.

    6. [6]

      [6] YING W, GEN B L, WEI Z. Study on the application of DME/diesel blends in a diesel engine[J]. Fuel Process Technol, 2008, 89(12): 1272-1280.

    7. [7]

      [7] CHEN J, TANG Z H, XIA C G, ZHANG X Z, LI Z. Method for preparing polymethoxymethylal: US, 7560599[P]. 2009-07-14.

    8. [8]

      [8] SCHELLING H, STROEFER E, PINKOS R, HAUNERT A, TEBBEN G D, HASSE H, BLAGOV S. Method for producing polyoxymethylene dimethyl ethers: CN, 101048357A[P]. 2007-10-03.

    9. [9]

      [9] 陈静, 唐中华, 夏春谷, 张新志, 李臻. 聚甲氧基甲缩醛的制备方法: 中国, 101182367A[P]. 2008-05-21. (CHEN Jing, TANG Zhong-hua, XIA Chun-gu, ZHANG Xin-zhi, LI Zhen. Method for preparing polymethoxymethylal: CN, 101182367A[P]. 2008-05-21.)

    10. [10]

      [10] 高晓晨, 杨为民, 刘志成, 高焕新. HZSM-5分子筛用于合成聚甲醛二甲基醚[J]. 催化学报, 2012, 33(8): 1389-1394. (GAO Xiao-chen, YANG Wei-min, LIU Zhi-cheng, GAO Huan-xin. Catalytic performance of HZSM-5 molecular sieve for synthesis of polyoxymethylene dimethyl ethers[J]. Chinese Journal of Catalysis, 2012, 33(8): 1389-1394.)

    11. [11]

      [11] BURGER J, SIEGERT M, STROFER E, HASSE H. Chemical equilibrium and reaction kinetics of the heterogeneously catalyzed formation of poly(oxymethylene) dimethyl ethers from methylal and trioxane[J]. Ind Eng Chem Res, 2012, 51(39): 12751-12761.

    12. [12]

      [12] FAN W, PENG W, NAMBA S, TATSUMI T. Synthesis and catalytic properties of a new titanosilicate molecular sieve with the structure analogous to MWW-type lamellar precursor[J]. J Catal, 2006, 243(1): 183-191.

    13. [13]

      [13] CORMA A, CORELL C, PEREZ-PARIENTE J. Infrared spectroscopy, thermoprogrammed desorption, and nuclear magnetic resonance study of the acidity, structure, and stability of zeolite MCM-22[J]. Zeolites, 1995, 15(7): 576-582.

    14. [14]

      [14] BRENDAN C, WILLIAM M C, WILLIAM A M. Heteroionic forms of zeolites L and mordenite: A heat of immersion study[J]. J Catal, 1976, 45(2): 332-338.

    15. [15]

      [15] FAN W B, WEI S Q, TOSHIYUKI Y, SATOSHI I, LI J F, WANG J G, TATSUMI T. Synthesis, characterization, and catalytic properties of H-Al-YNU-1 and H-Al-MWW with different Si/Al ratios[J]. J Catal, 2009, 266(2): 268-278.

    16. [16]

      [16] AYRAULT P, DATKA J, LAFORGE S, MARTIN D, GUISNET M. Characterization of the internal and external acidity of H-MCM-22 zeolites[J]. J Phys Chem B, 2004, 108(36): 13755-13763.

  • 加载中
    1. [1]

      Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO2 Hydrogenation by Decoration of K on MoS2 Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017

    2. [2]

      Yongmei Liu ,  Lisen Sun ,  Zhen Huang ,  Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020

    3. [3]

      Wanmin Cheng ,  Juan Du ,  Peiwen Liu ,  Yiyun Jiang ,  Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066

    4. [4]

      Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al2O3 for promoting plasma-catalyzed CO2 hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054

    5. [5]

      Yinuo Wang ,  Siran Wang ,  Yilong Zhao ,  Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063

    6. [6]

      Jian Jin ,  Jing Cheng ,  Xueping Yang . Integration Practice of Organic Chemistry Experiment and Safety Education: Taking the Synthesis of Triphenylmethanol as an Example. University Chemistry, 2024, 39(3): 345-350. doi: 10.3866/PKU.DXHX202309010

    7. [7]

      Feng Han ,  Fuxian Wan ,  Ying Li ,  Congcong Zhang ,  Yuanhong Zhang ,  Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181

    8. [8]

      Liangzhen Hu ,  Li Ni ,  Ziyi Liu ,  Xiaohui Zhang ,  Bo Qin ,  Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001

    9. [9]

      Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO2 mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398

    10. [10]

      Weikang Wang , Yadong Wu , Jianjun Zhang , Kai Meng , Jinhe Li , Lele Wang , Qinqin Liu . Green H2O2 synthesis via melamine-foam supported S-scheme Cd0.5Zn0.5In2S4/S-doped carbon nitride heterojunction: synergistic interfacial charge transfer and local photothermal effect. Acta Physico-Chimica Sinica, 2025, 41(8): 100093-0. doi: 10.1016/j.actphy.2025.100093

    11. [11]

      Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036

    12. [12]

      Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350

    13. [13]

      Ling Liu ,  Haibin Wang ,  Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080

    14. [14]

      Ping Song ,  Nan Zhang ,  Jie Wang ,  Rui Yan ,  Zhiqiang Wang ,  Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087

    15. [15]

      Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026

    16. [16]

      Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028

    17. [17]

      Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Research on Cu-Based and Pt-Based Catalysts for Hydrogen Production through Methanol Steam Reforming. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-0. doi: 10.1016/j.actphy.2025.100049

    18. [18]

      Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314

    19. [19]

      Tao Cao ,  Fang Fang ,  Nianguang Li ,  Yinan Zhang ,  Qichen Zhan . Green Synthesis of p-Hydroxybenzonitrile Catalyzed by Spinach Extracts under Red-Light Irradiation: Research and Exploration of Innovative Experiments for Pharmacy Undergraduates. University Chemistry, 2024, 39(5): 63-69. doi: 10.3866/PKU.DXHX202309098

    20. [20]

      Shi-Yu Lu , Wenzhao Dou , Jun Zhang , Ling Wang , Chunjie Wu , Huan Yi , Rong Wang , Meng Jin . Amorphous-Crystalline Interfaces Coupling of CrS/CoS2 Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(8): 2308024-0. doi: 10.3866/PKU.WHXB202308024

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(488)
  • HTML views(66)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return